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Perovskite
Perovskite (pronunciation: ) is a calcium titanium oxide mineral composed of calcium titanate (chemical formula ). Its name is also applied to the class of compounds which have the same type of crystal structure as , known as the perovskite (structure), perovskite structure, which has a general chemical formula . Many different cations can be embedded in this structure, allowing the development of diverse engineered materials. History The mineral was discovered in the Ural Mountains of Russia by Gustav Rose in 1839 and is named after Russian mineralogist Lev Perovski (1792–1856). Perovskite's notable crystal structure was first described by Victor Goldschmidt in 1926 in his work on tolerance factors. The crystal structure was later published in 1945 from X-ray diffraction data on barium titanate by Helen Dick Megaw. Occurrence Found in the Earth's Mantle (geology), mantle, perovskite's occurrence at Khibiny Mountains, Khibina Massif is restricted to the silica under-saturat ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Perovskite (structure)
A perovskite is a crystalline material of formula ABX3 with a crystal structure similar to that of the mineral perovskite, this latter consisting of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). In addition to being one of the most abundant structural families, perovskites have wide-ranging properties and applications. Structure Perovskite structures are adopted by many compounds that have the chemical formula ABX3. 'A' and 'B' are positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite for ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Calcium Titanate
Calcium titanate is an inorganic compound with the chemical formula Ca Ti O3. As a mineral, it is called perovskite, named after Russian mineralogist, Lev Perovski (1792–1856). It is a colourless, diamagnetic solid, although the mineral is often coloured owing to impurities. Synthesis CaTiO3 can be prepared by the combination of CaO and TiO2 at temperatures >1300 °C. Sol-gel processes has been used to make a more pure substance, as well as lowering the synthesis temperature. These compounds synthesized are more compressible due to the powders from the sol-gel process as well and bring it closer to its calculated density (~4.04 g/ml). Structure Calcium titanate is obtained as orthorhombic crystals, more specifically perovskite structure. In this motif, the Ti(IV) centers are octahedral and the Ca2+ centers occupy a cage of 12 oxygen centres. Many useful materials adopt related structures, e.g. barium titanate or variations of the structure, e.g. yttrium barium cop ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Helen Dick Megaw
Helen Dick Megaw (1 June 1907 – 26 February 2002) was an Irish crystallographer who was a pioneer in X-ray crystallography. She made measurements of the cell dimensions of ice and established the Perovskite crystal structure. Education and career Megaw was born in Dublin to mathematics teacher Annie McElderry (1874-1968) and judge Robert Megaw, two graduates of Queen's University Belfast who were both originally from Ballymoney, Antrim. She was educated at first at Alexandra College in Dublin, and then briefly at Methodist College in Belfast after the family (including younger brother John, later a leading judge) moved back there in 1921, and finally at the Roedean School in England. While still at school, Megaw read Bragg's ''X-rays and Crystal Structure.'' She spent a year at Queen's University, Belfast before moving to Girton College, Cambridge to study Natural Sciences in 1926. She graduated in 1930 and was a research student in crystallography under J. D. Bernal. Megaw ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Barium Titanate
Barium titanate (BTO) is an inorganic compound with chemical formula BaTiO3. It is the barium salt of metatitanic acid. Barium titanate appears white as a powder and is transparent when prepared as large crystals. It is a Ferroelectricity, ferroelectric, Pyroelectricity, pyroelectric, and Piezoelectricity, piezoelectric ceramic material that exhibits the photorefractive effect. It is used in capacitors, electromechanical transducers and nonlinear optics. Structure The solid exists in one of four polymorphs depending on temperature. From high to low temperature, these crystal symmetries of the four polymorphs are Cubic crystal system, cubic, Tetragonal crystal system, tetragonal, Orthorhombic crystal system, orthorhombic and Trigonal crystal system, rhombohedral crystal structure. All of these phases exhibit the ferroelectric effect apart from the cubic phase. The high temperature cubic phase is easiest to describe, as it consists of regular corner-sharing octahedral TiO6 units ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gustav Rose
Prof Gustavus ("Gustav") Rose Royal Society of London, FRSFor HFRSE (18 March 1798 – 15 July 1873) was a German mineralogist who was a native of Berlin. He was President of the German Geological Society from 1863 to 1873. Life He was born in Berlin the son of pharmacologist Valentin Rose (pharmacologist), Valentin Rose. Rose was a graduate of the University of Berlin, where he was a student of mineralogist Christian Samuel Weiss (1780–1856). He also studied under Swedish people, Swedish Physical chemistry, physical chemist Jöns Jakob Berzelius (1779–1848) in Stockholm. While studying with Berzelius, Rose met German chemist Eilhard Mitscherlich (1794–1863), with whom he maintained a lifelong friendship. Rose provided assistance to Mitscherlich's development of the law of Isomorphism (crystallography), isomorphism. In 1826 he became an associate professor of mineralogy in Berlin. In 1829, with German natural history, naturalists Alexander von Humboldt (1769–1859) and Chri ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Minerals
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the Silicate mineral, silicates, Sulfate mineral, sulfates, carbonate mineral, carbonates and Phosphate mineral, phosphates are classed separately. Simple oxides *XO form **Periclase group ***Periclase ***Manganosite **Zincite group ***Zincite ***Bromellite ***Tenorite ***Litharge * form **Cuprite **Ice * form **Hematite group ***Corundum ***Hematite ***Ilmenite * form **Rutile group ***Rutile ***Pyrolusite ***Cassiterite **Baddeleyite **Uraninite **Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite ***Franklinite ***Chromite **Chrysoberyl **Columbite *Hydroxide subgroup: **Brucite **Manganite **Romanèchite **Goethite group: ***Diaspore ***Goethite Nickel–Strunz class 4: oxides Internationa ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Crystal Structure
In crystallography, crystal structure is a description of ordered arrangement of atoms, ions, or molecules in a crystalline material. Ordered structures occur from intrinsic nature of constituent particles to form symmetric patterns that repeat along the principal directions of three-dimensional space in matter. The smallest group of particles in a material that constitutes this repeating pattern is the unit cell of the structure. The unit cell completely reflects the symmetry and structure of the entire crystal, which is built up by repetitive translation of the unit cell along its principal axes. The translation vectors define the nodes of the Bravais lattice. The lengths of principal axes/edges, of the unit cell and angles between them are lattice constants, also called ''lattice parameters'' or ''cell parameters''. The symmetry properties of a crystal are described by the concept of space groups. All possible symmetric arrangements of particles in three-dimensional space ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Oxide Mineral
The oxide mineral class includes those minerals in which the oxide anion (O2−) is bonded to one or more metal alloys. The hydroxide-bearing minerals are typically included in the oxide class. Minerals with complex anion groups such as the silicates, sulfates, carbonates and phosphates are classed separately. Simple oxides *XO form **Periclase group *** Periclase *** Manganosite **Zincite group *** Zincite *** Bromellite *** Tenorite *** Litharge * form ** Cuprite **Ice * form **Hematite group ***Corundum ***Hematite *** Ilmenite * form **Rutile group ***Rutile *** Pyrolusite *** Cassiterite ** Baddeleyite ** Uraninite ** Thorianite * form **Spinel group ***Spinel ***Gahnite ***Magnetite *** Franklinite ***Chromite ** Chrysoberyl ** Columbite *Hydroxide subgroup: **Brucite ** Manganite ** Romanèchite **Goethite group: *** Diaspore ***Goethite Nickel–Strunz class 4: oxides IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 20 ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Foidolite
Foidolite () is a rare phaneritic (coarse-grained) intrusive igneous rock in which more than 60% (by volume) of light-coloured minerals are feldspathoids. Crystals of alkali feldspar, plagioclase, biotite, amphibole, pyroxene, and/or olivine may be present within the rock. The volcanic equivalents are termed foidite and ''phonolitic or tephritic foidites''. Some foidolites are a potential source of aluminium. See also *QAPF diagram A QAPF diagram is a doubled-triangle plot diagram used to classify igneous rocks based on their mineralogy. The acronym QAPF stands for "quartz, alkali feldspar, plagioclase, feldspathoid (foid)", which are the four mineral groups used for clas ... References External linksFoidolite(at University of Manitoba) - Retrieved 2009-05-15 Igneous rocks {{igneous-rock-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Mount Vesuvius
Mount Vesuvius ( ) is a Somma volcano, somma–stratovolcano located on the Gulf of Naples in Campania, Italy, about east of Naples and a short distance from the shore. It is one of several volcanoes forming the Campanian volcanic arc. Vesuvius consists of a large volcanic cone, cone partially encircled by the steep rim of a summit caldera, resulting from the collapse of an earlier, much higher structure. The eruption of Mount Vesuvius in 79 AD destroyed the Roman Empire, Roman cities of Pompeii, Herculaneum, Oplontis, Stabiae and other settlements. The eruption ejected a cloud of Volcanic rock, stones, Volcanic ash, ash and volcanic gases to a height of , Volcanic eruption, erupting Lava, molten rock and pulverized pumice at the rate of per second. More than 1,000 people are thought to have died in the eruption, though the exact toll is unknown. The only surviving witness account consists of two letters by Pliny the Younger to the historian Tacitus. Vesuvius has erupted ma ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Limestone
Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science), crystal forms of calcium carbonate . Limestone forms when these minerals Precipitation (chemistry), precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life. About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly Dolomite (rock), dolomite, a closely related rock, which contains a high percentage of the mineral Dolomite (mine ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Arkansas
Arkansas ( ) is a landlocked state in the West South Central region of the Southern United States. It borders Missouri to the north, Tennessee and Mississippi to the east, Louisiana to the south, Texas to the southwest, and Oklahoma to the west. Its name derives from the Osage language, and refers to their relatives, the Quapaw people. The state's diverse geography ranges from the mountainous regions of the Ozark and Ouachita Mountains, which make up the U.S. Interior Highlands, to the densely forested land in the south known as the Arkansas Timberlands, to the eastern lowlands along the Mississippi River and the Arkansas Delta. Previously part of French Louisiana and the Louisiana Purchase, the Territory of Arkansas was admitted to the Union as the 25th state on June 15, 1836. Much of the Delta had been developed for cotton plantations, and landowners there largely depended on enslaved African Americans' labor. In 1861, Arkansas seceded from the United St ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
