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Ostwald Ripening
Ostwald ripening is a phenomenon observed in solid solutions and liquid sols that involves the change of an inhomogeneous structure over time, in that small crystals or sol particles first dissolve and then redeposit onto larger crystals or sol particles. Dissolution of small crystals or sol particles and the redeposition of the dissolved species on the surfaces of larger crystals or sol particles was first described by Wilhelm Ostwald in 1896. For colloidal systems, Ostwald ripening is also found in water-in-oil emulsions, while flocculation is found in oil-in-water emulsions. Mechanism This thermodynamically-driven spontaneous process occurs because larger particles are more energetically favored than smaller particles. This stems from the fact that molecules on the surface of a particle are energetically less stable than the ones in the interior. Consider a cubic crystal of atoms: all the atoms inside are bonded to 6 neighbours and are quite stable, but atoms on t ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Surface Energy
In surface science, surface energy (also interfacial free energy or surface free energy) quantifies the disruption of intermolecular bonds that occurs when a surface is created. In solid-state physics, surfaces must be intrinsically less energetically favorable than the bulk of the material (that is, the atoms on the surface must have more energy than the atoms in the bulk), otherwise there would be a driving force for surfaces to be created, removing the bulk of the material by sublimation. The surface energy may therefore be defined as the excess energy at the surface of a material compared to the bulk, or it is the work required to build an area of a particular surface. Another way to view the surface energy is to relate it to the work required to cut a bulk sample, creating two surfaces. There is "excess energy" as a result of the now-incomplete, unrealized bonding between the two created surfaces. Cutting a solid body into pieces disrupts its bonds and increases the surfac ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Units Of Measurement
A unit of measurement, or unit of measure, is a definite magnitude (mathematics), magnitude of a quantity, defined and adopted by convention or by law, that is used as a standard for measurement of the same kind of quantity. Any other quantity of that kind can be expressed as a multiple of the unit of measurement. For example, a length is a physical quantity. The metre (symbol m) is a unit of length that represents a definite predetermined length. For instance, when referencing "10 metres" (or 10 m), what is actually meant is 10 times the definite predetermined length called "metre". The definition, agreement, and practical use of units of measurement have played a crucial role in human endeavour from early ages up to the present. A multitude of System of measurement, systems of units used to be very common. Now there is a global standard, the International System of Units (SI), the modern form of the metric system. In trade, weights and measures are often a su ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Reaction Rate Constant
In chemical kinetics, a reaction rate constant or reaction rate coefficient () is a proportionality constant which quantifies the rate and direction of a chemical reaction by relating it with the concentration of reactants. For a reaction between reactants A and B to form a product C, where :A and B are reactants :C is a product :''a'', ''b'', and ''c'' are stoichiometric coefficients, the reaction rate is often found to have the form: r = k mathrmm mathrm Here is the reaction rate constant that depends on temperature, and and are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the solution. (For a reaction taking place at a boundary, one would use moles of A or B per unit area instead.) The exponents ''m'' and ''n'' are called partial orders of reaction and are ''not'' generally equal to the stoichiometric coefficients ''a'' and ''b''. Instead they depend on the reacti ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Quantitatively
Quantitative research is a research strategy that focuses on quantifying the collection and analysis of data. It is formed from a deductive approach where emphasis is placed on the testing of theory, shaped by empiricist and positivist philosophies. Associated with the natural, applied, formal, and social sciences this research strategy promotes the objective empirical investigation of observable phenomena to test and understand relationships. This is done through a range of quantifying methods and techniques, reflecting on its broad utilization as a research strategy across differing academic disciplines. There are several situations where quantitative research may not be the most appropriate or effective method to use: 1. When exploring in-depth or complex topics. 2. When studying subjective experiences and personal opinions. 3. When conducting exploratory research. 4. When studying sensitive or controversial topics The objective of quantitative research is to de ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spinodal Decomposition
Spinodal decomposition is a mechanism by which a single thermodynamic Phase (matter), phase spontaneously separates into two phases (without nucleation). Decomposition occurs when there is no Thermodynamics, thermodynamic barrier to phase separation. As a result, phase separation via decomposition does not require the nucleation events resulting from thermodynamic fluctuations, which normally trigger phase separation. Spinodal decomposition is observed when mixtures of metals or polymers separate into two co-existing phases, each rich in one species and poor in the other. When the two phases emerge in approximately equal proportion (each occupying about the same volume or area), characteristic intertwined structures are formed that gradually coarsen (see animation). The dynamics of spinodal decomposition is commonly modeled using the Cahn–Hilliard equation. Spinodal decomposition is fundamentally different from nucleation and growth. When there is a nucleation barrier to the form ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Simulations
A simulation is an imitative representation of a process or system that could exist in the real world. In this broad sense, simulation can often be used interchangeably with model. Sometimes a clear distinction between the two terms is made, in which simulations require the use of models; the model represents the key characteristics or behaviors of the selected system or process, whereas the simulation represents the evolution of the model over time. Another way to distinguish between the terms is to define simulation as experimentation with the help of a model. This definition includes time-independent simulations. Often, computer simulation, computers are used to execute the simulation. Simulation is used in many contexts, such as simulation of technology for performance tuning or optimizing, safety engineering, testing, training, education, and video games. Simulation is also used with scientific modelling of natural systems or human systems to gain insight into their functio ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Iron Curtain
The Iron Curtain was the political and physical boundary dividing Europe into two separate areas from the end of World War II in 1945 until the end of the Cold War in 1991. On the east side of the Iron Curtain were countries connected to the Soviet Union, and on the west side those that were NATO members. Economic and military alliances developed on each side of the Iron Curtain, and it became a term for the physical barriers of razor wire, Fence, fences, Fortified wall, walls, minefields, and Watchtower, watchtowers built along it. The nations to the east of the Iron Curtain were People's Republic of Poland, Poland, East Germany, Socialist Republic of Czechoslovakia, Czechoslovakia, Hungarian People's Republic, Hungary, Socialist Republic of Romania, Romania, People's Republic of Bulgaria, Bulgaria, People's Republic of Albania, Albania, and the USSR; however, Reunification of Germany, East Germany, Breakup of Czechoslovakia, Czechoslovakia, and the Dissolution of the USSR, USS ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Carl Wagner
Carl Wilhelm Wagner (25 May 1901 – 10 December 1977) was a German physical chemist. He is best known for his pioneering work on solid-state chemistry, where his work on oxidation rate theory, counter diffusion of ions and defect chemistry led to a better understanding of how reactions take place at the atomic level. His life and achievements were honoured in a Solid State Ionics symposium commemorating his 100th birthday in 2001, where he was described as the father of solid-state chemistry. Early life Wagner was born in Leipzig, Germany; the son of Dr Julius Wagner who was the Head of Chemistry at the local institute and secretary of the German Bunsen Society of Physical Chemistry. Wagner graduated from the University of Munich and gained his PhD at the University of Leipzig in 1924 supervised by Max Le Blanc with a dissertation on the reaction rate in solutions, "Beiträge zur Kenntnis der Reaktionsgeschwindigkeit in Lösungen". Career Wagner was interested in the measu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Distribution Function (physics)
In molecular kinetic theory in physics, a system's distribution function is a function of seven variables, f(t, x,y,z, v_x,v_y,v_z), which gives the number of particles per unit volume in single-particle phase space. It is the number of particles per unit volume having approximately the velocity \mathbf = (v_x,v_y,v_z) near the position \mathbf = (x,y,z) and time t. The usual normalization of the distribution function is \begin n(\mathbf,t) &= \int f(\mathbf, \mathbf, t) \,dv_x \,dv_y \,dv_z, \\ N(t) &= \int n(\mathbf, t) \,dx \,dy \,dz, \end where is the total number of particles and is the number density of particles – the number of particles per unit volume, or the density divided by the mass of individual particles. A distribution function may be specialised with respect to a particular set of dimensions. E.g. take the quantum mechanical six-dimensional phase space, f(x,y,z;p_x,p_y,p_z) and multiply by the total space volume, to give the momentum distribution, i.e. the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nucleation
In thermodynamics, nucleation is the first step in the formation of either a new Phase (matter), thermodynamic phase or Crystal structure, structure via self-assembly or self-organization within a substance or mixture. Nucleation is typically defined to be the process that determines how long an observer has to wait before the new phase or self-organized structure appears. For example, if a volume of water is cooled (at atmospheric pressure) significantly below 0°C, it will tend to Freezing, freeze into ice, but volumes of water cooled only a few degrees below 0°C often stay completely free of ice for long periods (supercooling). At these conditions, nucleation of ice is either slow or does not occur at all. However, at lower temperatures nucleation is fast, and ice crystals appear after little or no delay. Nucleation is a common mechanism which generates first-order phase transitions, and it is the start of the process of forming a new thermodynamic phase. In contrast, new phas ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermodynamic Temperature
Thermodynamic temperature, also known as absolute temperature, is a physical quantity which measures temperature starting from absolute zero, the point at which particles have minimal thermal motion. Thermodynamic temperature is typically expressed using the Kelvin scale, where the unit of measurement is the ''kelvin'' (unit symbol: K). The Kelvin scale uses the same degree interval as the Celsius scale but is offset so that 0 K corresponds to absolute zero. For comparison, a temperature of 295 K corresponds to 21.85 °C and 71.33 °F. Another absolute scale of temperature is the Rankine scale, which is based on the Fahrenheit degree interval. Historically, thermodynamic temperature was defined by Lord Kelvin in terms of a macroscopic relation between Work (thermodynamics), thermodynamic work and Heat, heat transfer as defined in thermodynamics, but the kelvin was redefined by international agreement in 2019 in terms of phenomena that are now understood as man ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
