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Nitrogen Oxide
Nitrogen oxide may refer to a binary compound of oxygen and nitrogen, or a mixture of such compounds: Charge-neutral *Nitric oxide (NO), nitrogen(II) oxide, or nitrogen monoxide * Nitrogen dioxide (), nitrogen(IV) oxide * Nitrogen trioxide (), or nitrate radical *Nitrous oxide (), nitrogen(0,II) oxide * Dinitrogen dioxide (), nitrogen(II) oxide dimer * Dinitrogen trioxide (), nitrogen(II,IV) oxide * Dinitrogen tetroxide (), nitrogen(IV) oxide dimer *Dinitrogen pentoxide (), nitrogen(V) oxide, or nitronium nitrate * Nitrosyl azide (), nitrogen(−I,0,I,II) oxide * Nitryl azide () * Oxatetrazole () * Trinitramide ( or ), nitrogen(0,IV) oxide Anions Cations * Nitrosonium ( or ) * Nitronium ( or ) Atmospheric sciences In atmospheric chemistry: * (or NO''x'') refers to the sum of NO and . * (or NO''y'') refers to the sum of and all oxidized atmospheric odd-nitrogen species (''e.g.'' the sum of , , , etc.) * (or NO''z'') = − * Mixed Oxides of Nitrogen ("MON"): solu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Binary Compound
In materials chemistry, a binary phase or binary compound is a chemical compound containing two different elements. Some binary phase compounds are molecular, e.g. carbon tetrachloride (CCl4). More typically binary phase refers to extended solids. Famous examples zinc sulfide Zinc sulfide (or zinc sulphide) is an inorganic compound with the chemical formula of ZnS. This is the main form of zinc found in nature, where it mainly occurs as the mineral sphalerite. Although this mineral is usually black because of various i ..., which contains zinc and sulfur, and tungsten carbide, which contains tungsten and carbon. Phases with higher degrees of complexity feature more elements, e.g. three elements in ternary phases, four elements in quaternary phases. These phases exhibit a higher degree of complexity due to the interaction of these elements at different conditions. References Chemical compounds {{chem-compound-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrite
The nitrite polyatomic ion, ion has the chemical formula . Nitrite (mostly sodium nitrite) is widely used throughout chemical and pharmaceutical industries. The nitrite anion is a pervasive intermediate in the nitrogen cycle in nature. The name nitrite also refers to organic compounds having the –ONO group, which are esters of nitrous acid. Production Sodium nitrite is made industrially by passing a mixture of nitrogen oxides into aqueous sodium hydroxide or sodium carbonate solution: : : The product is purified by recrystallization. Alkali metal nitrites are thermally stable up to and beyond their melting point (441 °C for KNO2). Ammonium nitrite can be made from dinitrogen trioxide, N2O3, which is formally the anhydride of nitrous acid: :2 NH3 + H2O + N2O3 → 2 NH4NO2 Structure The nitrite ion has a symmetrical structure (C2v molecular point group, symmetry), with both N–O bonds having equal length and a bond angle of about 115°. In valence bond theory, it is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrogen Dioxide
Nitrogen dioxide is a chemical compound with the formula . One of several nitrogen oxides, nitrogen dioxide is a reddish-brown gas. It is a paramagnetic, bent molecule with C2v point group symmetry. Industrially, is an intermediate in the synthesis of nitric acid, millions of tons of which are produced each year, primarily for the production of fertilizers. Nitrogen dioxide is poisonous and can be fatal if inhaled in large quantities. Cooking with a gas stove produces nitrogen dioxide which causes poorer indoor air quality. Combustion of gas can lead to increased concentrations of nitrogen dioxide throughout the home environment which is linked to respiratory issues and diseases. The LC50 ( median lethal dose) for humans has been estimated to be 174 ppm for a 1-hour exposure. It is also included in the NOx family of atmospheric pollutants. Properties Nitrogen dioxide is a reddish-brown gas with a pungent, acrid odor above and becomes a yellowish-brown liquid below . ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitric Oxide
Nitric oxide (nitrogen oxide, nitrogen monooxide, or nitrogen monoxide) is a colorless gas with the formula . It is one of the principal oxides of nitrogen. Nitric oxide is a free radical: it has an unpaired electron, which is sometimes denoted by a dot in its chemical formula (•N=O or •NO). Nitric oxide is also a heteronuclear diatomic molecule, a class of molecules whose study spawned early modern theories of chemical bonding. An important intermediate in industrial chemistry, nitric oxide forms in combustion systems and can be generated by lightning in thunderstorms. In mammals, including humans, nitric oxide is a signaling molecule in many physiological and pathological processes. It was proclaimed the " Molecule of the Year" in 1992. The 1998 Nobel Prize in Physiology or Medicine was awarded for discovering nitric oxide's role as a cardiovascular signalling molecule. Its impact extends beyond biology, with applications in medicine, such as the development of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Atmospheric Chemistry
Atmospheric chemistry is a branch of atmospheric science that studies the chemistry of the Earth's atmosphere and that of other planets. This multidisciplinary approach of research draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology, climatology and other disciplines to understand both natural and human-induced changes in atmospheric composition. Key areas of research include the behavior of trace gasses, the formation of pollutants, and the role of aerosols and greenhouse gasses. Through a combination of observations, laboratory experiments, and computer modeling, atmospheric chemists investigate the causes and consequences of atmospheric changes. Atmospheric composition The composition and chemistry of the Earth's atmosphere is important for several reasons, but primarily because of the interactions between the atmosphere and living organisms. Natural processes such as volcano emissions, lightning and bombardme ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitronium Ion
The nitronium ion, , is a cation. It is an onium ion because its nitrogen atom has +1 charge, similar to ammonium ion . It is created by the removal of an electron from the paramagnetic nitrogen dioxide molecule , or the protonation of nitric acid (with removal of ). It is stable enough to exist in normal conditions, but it is generally reactive and used extensively as an electrophile in the nitration of other substances. The ion is generated '' in situ'' for this purpose by mixing concentrated sulfuric acid and concentrated nitric acid according to the equilibrium: : Structure The nitronium ion is isoelectronic with carbon dioxide and has the same linear structure and bond angle of 180°. For this reason it has a similar vibrational spectrum to carbon dioxide. Historically, the nitronium ion was detected by Raman spectroscopy, because its symmetric stretch is Raman-active but infrared-inactive. The Raman-active symmetrical stretch was first used to identify the ion ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrosonium
The nitrosonium ion is , in which the nitrogen atom is bonded to an oxygen atom with a bond order of 3, and the overall diatomic species bears a positive charge. It can be viewed as nitric oxide with one electron removed. This ion is usually obtained as the following salts: , ( nitrosylsulfuric acid, more descriptively written ) and . The and salts are slightly soluble in acetonitrile . NOBF4 can be purified by sublimation at 200–250 °C and . Synthesis and spectroscopy is isoelectronic with CO, and . It arises via protonation of nitrous acid: :HONO + H+ NO+ + H2O In its infrared spectrum of its salts, νNO is a strong peak in the range 2150-2400 cm−1. Chemical properties Hydrolysis reacts readily with water to form nitrous acid: : For this reason, nitrosonium compounds must be protected from water or even moist air. With base, the reaction generates nitrite: : As a diazotizing agent reacts with aryl amines, , to give diazonium salts, . The resu ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Ammonium Dinitramide
Ammonium dinitramide (ADN) is an inorganic compound with the chemical formula . It is the ammonium salt (chemistry), salt of dinitraminic acid . It consists of ammonium cations and dinitramide anions . ADN decomposes under heat to leave only nitrogen, oxygen, and water. It makes an excellent solid rocket oxidizer with a slightly higher specific impulse than ammonium perchlorate and, more importantly, does not leave corrosive hydrogen chloride fumes. This property is also of military interest because halogen-free smoke is harder to detect. It decomposes into low-molecular-mass gases, which contributes to higher performance without creating excessive temperatures if used in gun or rocket propellants. However, the dinitramide salt is more prone to detonation under high temperatures and shock compared with the perchlorate. The Eurenco Bofors company produced LMP-103S as a 1-to-1 substitute for hydrazine by dissolving 65% ammonium dinitramide, , in 35% water solution of methanol and a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitroxylate
Nitroxylic acid or hydronitrous acid is an unstable reduced oxonitrogen acid. It has formula H4N2O4 containing nitrogen in the +2 oxidation state. It consists of a central pair of bonded nitrogen atoms with four hydroxyl groups around them, giving rise to hydrazine-1,1,2,2-tetrol as an alternate chemical name. The corresponding anion called nitroxylate is ; its empirical formula is the basis for the original names of some of its salts. The first clue that nitroxylic acid exists was when Edward Bedford Maxted electrolysed sodium nitrite dissolved in liquid ammonia. A bright yellow substance deposited on the cathode. He called this ''disodium nitrite''. The disodium nitrite could also be made by mixing ammonia solutions of sodium and sodium nitrite in the complete absence of water. Disodium nitrite reacts with water to form sodium nitrite, sodium hydroxide and hydrogen. Other ways to make the disodium nitrite include reacting sodium with ammonium nitrate or electrolysing sodium n ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Trioxodinitrate
Angeli's salt, sodium trioxodinitrate, is the inorganic compound with the formula Na2 2O3 It contains nitrogen in an unusual reduced state. It is a colorless, water-soluble solid, hence a salt. In research, this salt is used as a source of the metastable nitroxyl (HNO), which is a signalling molecule in nature. It is also known by the name sodium trioxodinitrate(II) monohydrate. Preparation and properties As first reported by Angelo Angeli in 1896, the salt is prepared by combining hydroxylamine and an organic nitrate, as a source of nitronium (): :NH2OH + RONO2 + 2 NaOR′ → ROH + 2 R′OH + Na2N2O3 The structure of the hydrate has been confirmed by X-ray crystallography. The anion is planar. Starting from the ONN end, the bond distances are 1.35 Å (N–O), 1.26 Å (N–N), 1.31 Å (N–O''trans''), and 1.32 Å (N–O''cis''). The negative charge is on the oxygen atoms at opposite ends of the molecule. The angles are 112.9° (Osingl ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hyponitrite
In chemistry, hyponitrite may refer to the anion ( N=NOsup>2−), or to any ionic compound that contains it. In organic chemistry, it may also refer to the group −O−N=N−O−, or any organic compound with the generic formula R1−O−N=N−O−R2, where R1 and R2 are organic groups. Such compounds can be viewed as salts and esters of hyponitrous acid. An acid hyponitrite is an ionic compound with the anion ( ON=NOsup>−). Hyponitrite ion Hyponitrite exhibits cis–trans isomerism.Egon Wiberg, Arnold Frederick Holleman (2001) ''Inorganic Chemistry'', Elsevier The ''trans'' (''E'') form is generally found in hyponitrite salts such as sodium hyponitrite () and silver(I) hyponitrite (). The ''cis'' (''Z'') form of sodium hyponitrite can be obtained too, but it is more reactive than the ''trans'' form. The ''cis'' hyponitrite anion is nearly planar and almost symmetric, with lengths of about 140 pm for N−O bond and 120 pm for the N−N bond, and O−N� ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Orthonitrate
Orthonitrate is a tetrahedral anion of nitrogen with the formula . It was first identified in 1977 and is currently known in only two compounds, sodium orthonitrate (Na3NO4) and potassium orthonitrate (K3NO4). The corresponding oxoacid, orthonitric acid (H3NO4), is hypothetical and has never been observed. Sodium and potassium orthonitrate can be prepared by fusion of the nitrate and metal oxide under high temperatures and ideally high pressures (several GPa). : (300 °C for 3 days) The resulting orthonitrates are white solids which are extremely sensitive to moisture and CO2, decomposing within minutes to hydroxides, carbonates, and nitrates upon exposure to air. : : The orthonitrate ion is tetrahedral with N–O bond lengths of 139 pm, which is unexpectedly short, indicating that polar interactions are shortening the bond. This short bond length parallels that of hypervalent oxyanions containing third-row elements like and , for which pπ–dπ bonding was pre ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
