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Lead Nitrate
Lead(II) nitrate is an inorganic compound with the chemical formula Pb( NO3)2. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water. Known since the Middle Ages by the name plumbum dulce, the production of lead(II) nitrate from either metallic lead or lead oxide in nitric acid was small-scale, for direct use in making other lead compounds. In the nineteenth century lead(II) nitrate began to be produced commercially in Europe and the United States. Historically, the main use was as a raw material in the production of pigments for lead paints, but such paints have been superseded by less toxic paints based on titanium dioxide. Other industrial uses included heat stabilization in nylon and polyesters, and in coatings of photothermographic paper. Since around the year 2000, lead(II) nitrate has begun to be used in gold cyanidation. Lead(II) nitrate is toxic and must be handled with care to prevent inhalation, inge ...
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Inorganic Compound
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemistry''. Inorganic compounds comprise most of the Earth's crust, although the compositions of the deep mantle remain active areas of investigation. Some simple carbon compounds are often considered inorganic. Examples include the allotropes of carbon (graphite, diamond, buckminsterfullerene, etc.), carbon monoxide, carbon dioxide, carbides, and the following salts of inorganic anions: carbonates, cyanides, cyanates, and thiocyanates. Many of these are normal parts of mostly organic systems, including organisms; describing a chemical as inorganic does not necessarily mean that it does not occur within living things. History Friedrich Wöhler's conversion of ammonium cyanate into urea in 1828 is often cited as the starting point of m ...
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Polyester
Polyester is a category of polymers that contain the ester functional group in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include naturally occurring chemicals, such as in plants and insects, as well as synthetics such as polybutyrate. Natural polyesters and a few synthetic ones are biodegradable, but most synthetic polyesters are not. Synthetic polyesters are used extensively in clothing. Polyester fibers are sometimes spun together with natural fibers to produce a cloth with blended properties. Cotton-polyester blends can be strong, wrinkle- and tear-resistant, and reduce shrinking. Synthetic fibers using polyester have high water, wind and environmental resistance compared to plant-derived fibers. They are less fire-resistant and can melt when ignited. Liquid crystalline polyesters are among the first industrially used liquid crystal polymers. They are used for th ...
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Lead(II) Azide
Lead(II) azide is an inorganic compound. More so than other azides, is explosive. It is used in detonators to initiate secondary explosives. In a commercially usable form, it is a white to buff powder. Preparation and handling Lead(II) azide is prepared by the reaction of sodium azide and lead(II) nitrate in aqueous solution. Lead(II) acetate can also be used. Thickeners such as dextrin or polyvinyl alcohol are often added to the solution to stabilize the precipitated product. In fact, it is normally shipped in a dextrinated solution that lowers its sensitivity. Production history Lead azide in its pure form was first prepared by Theodor Curtius in 1891. Due to sensitivity and stability concerns, the dextrinated form of lead azide (MIL-L-3055) was developed in the 1920s and 1930s with large scale production by DuPont Co beginning in 1932. Detonator development during World War II resulted in the need for a form of lead azide with a more brisant output. RD-1333 lead azide (MIL ...
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Black Powder
Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). The sulfur and carbon act as fuels while the saltpeter is an oxidizer. Gunpowder has been widely used as a propellant in firearms, artillery, rocketry, and pyrotechnics, including use as a blasting agent for explosives in quarrying, mining, building pipelines and road building. Gunpowder is classified as a low explosive because of its relatively slow decomposition rate and consequently low brisance. Low explosives deflagrate (i.e., burn at subsonic speeds), whereas high explosives detonate, producing a supersonic shockwave. Ignition of gunpowder packed behind a projectile generates enough pressure to force the shot from the muzzle at high speed, but usually not enough force to rupture the gun barrel. It thus makes a good propellant but is ...
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Calico (textile)
Calico (; in British usage since 1505) is a heavy plain-woven textile made from unbleached, and often not fully processed, cotton. It may also contain unseparated husk parts. The fabric is far coarser than muslin, but less coarse and thick than canvas or denim. However, it is still very cheap owing to its unfinished and undyed appearance. The fabric was originally from the city of Calicut in southwestern India. It was made by the traditional weavers called cāliyans. The raw fabric was dyed and printed in bright hues, and calico prints became popular in Europe. History Origins Calico originated in Calicut, from which the name of the textile came, in South India, now Kerala, during the 11th century, where the cloth was known as "chaliyan". It was mentioned in Indian literature by the 12th century when the polymath and writer Hemachandra described calico fabric prints with a lotus design.''Encyclopædia Britannica'' (2008)"calico" Calico was woven using Gujarati cotton from S ...
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Dyeing
Dyeing is the application of dyes or pigments on textile materials such as fibers, yarns, and fabrics with the goal of achieving color with desired color fastness. Dyeing is normally done in a special solution containing dyes and particular chemical material. Dye molecules are fixed to the fiber by absorption, diffusion, or bonding with temperature and time being key controlling factors. The bond between dye molecule and fiber may be strong or weak, depending on the dye used. Dyeing and printing are different applications; in printing, color is applied to a localized area with desired patterns. In dyeing, it is applied to the entire textile. The primary source of dye, historically, has been nature, with the dyes being extracted from animals or plants. Since the mid-19th century, however, humans have produced artificial dyes to achieve a broader range of colors and to render the dyes more stable to washing and general use. Different classes of dyes are used for different types ...
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Chrome Orange
Chrome orange is a mixed oxide with the chemical formula Pb2CrO5. It can be made by treating a lead(II) salt with an alkaline solution of a chromate or by treating chrome yellow (PbCrO4) with strongly basic solution.. Synthesis and nanoparticles Pb2CrO5 can be synthesized with a gas-liquid precipitation process. Changing the pH controls whether PbCrO4 or Pb2CrO5 is created. Orthorhombic nanocrystals can be selectively synthesized in a facile room temperature solution for Pb2CrO5. Using a microwave-assisted ionic liquid (MAIL) method, bundle and rod-like nanocrystals of Pb2CrO5 were formed. The bundles look like bundles of straw, secured in the middle. In basic solution, single-crystalline Pb2CrO5 could be formed by heating lead acetate and potassium dichromate with microwave radiation for only 10 minutes at 90 celsius. The MAIL process is simple, fast, and does not employ surfactants. The presence of hydroxide changes the phase that is formed. Using NaOH, monoclinic Pb2CrO ...
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Chrome Yellow
__NOTOC__ Chrome yellow is a yellow pigment in paints using monoclinic lead(II) chromate (PbCrO4). It occurs naturally as the mineral crocoite but the mineral ore itself was never used as a pigment for paint. After the French chemist Louis Vauquelin discovered the new element chromium in 1797 lead chromate was synthesized in the laboratory and used as a pigment beginning in the second decade of the nineteenth century. Chrome yellow had been commonly made by mixing solutions of lead nitrate and potassium chromate and filtering off the lead chromate precipitate. The pigment tends to react with hydrogen sulfide and darken on exposure to air over time, forming lead sulfide, and it contains the toxic heavy metal lead plus the toxic, carcinogenic chromate. For these reasons, it was replaced by another pigment, cadmium yellow (mixed with enough cadmium orange to produce a color equivalent to chrome yellow). Darkening may also occur from reduction by sulfur dioxide. Good quality ...
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Andreas Libavius
Andreas Libavius or Andrew Libavius was born in Halle, Germany c. 1550 and died in July 1616. Libavius was a renaissance man who spent time as a professor at the University of Jena teaching history and poetry. After which he became a physician at the Gymnasium in Rothenburg and later founded the Gymnasium at Coburg. Libavius was most known for practicing alchemy and writing a book called ''Alchemia'', one of the first chemistry textbooks ever written. Life Libavius was born in Halle, Germany, as Andreas Libau, the son of Johann Libau. His father, only a linen worker, could not give Libavius an education because in this time period only the wealthy were able to get a higher education. Showing great intelligence as a child Livavius overcame his personal status and attended the University of Whittenburg at the age of eighteen in 1578. In 1579 he entered the University of Jena where he studied philosophy, history and medicine. In 1581 he obtained the academic degree of ''magister ...
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Alchemy
Alchemy (from Arabic: ''al-kīmiyā''; from Ancient Greek: χυμεία, ''khumeía'') is an ancient branch of natural philosophy, a philosophical and protoscientific tradition that was historically practiced in China, India, the Muslim world, and Europe. In its Western form, alchemy is first attested in a number of pseudepigraphical texts written in Greco-Roman Egypt during the first few centuries AD.Principe, Lawrence M. The secrets of alchemy'. University of Chicago Press, 2012, pp. 9–14. Alchemists attempted to purify, mature, and perfect certain materials. Common aims were chrysopoeia, the transmutation of "base metals" (e.g., lead) into "noble metals" (particularly gold); the creation of an elixir of immortality; and the creation of panaceas able to cure any disease. The perfection of the human body and soul was thought to result from the alchemical ''magnum opus'' ("Great Work"). The concept of creating the philosophers' stone was variously connected with all of ...
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Hazard
A hazard is a potential source of harm. Substances, events, or circumstances can constitute hazards when their nature would allow them, even just theoretically, to cause damage to health, life, property, or any other interest of value. The probability of that harm being realized in a specific ''incident'', combined with the magnitude of potential harm, make up its risk, a term often used synonymously in colloquial speech. Hazards can be classified in several ways; they can be classified as natural, anthropogenic, technological, or any combination, such as in the case of the natural phenomenon of wildfire becoming more common due to human-made climate change or more harmful due to changes in building practices. A common theme across many forms of hazards in the presence of stored energy that, when released, can cause damage. The stored energy can occur in many forms: chemical, mechanical, thermal hazards and by the populations that may be affected and the severity of the associa ...
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