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Gaston Charlot
Gaston Charlot (11 June 1904 – 17 April 1994) was a French chemist, founder of modern analytical chemistry in France. Charlot graduated from the École supérieure de physique et de chimie industrielles de la ville de Paris; he worked on the catalytic oxidation of organic substances in the gas phase. In 1945, he became professor of analytical chemistry at the École supérieure, and also lectured at the Faculté des sciences de Paris and at the Institut national des sciences et techniques nucléaires. Charlot generalized the Brønsted–Lowry theory of acid-base chemistry to complex chemistry. In 1943, he published ''Théories et méthodes nouvelles d'analyse qualitative'' (New theories and methods of qualitative analysis), which eliminated traditional methods such as hydrogen sulfide tests by replacing them with electrochemical or colorimetric tests, complex chemistry, and non-aqueous chemical reactions. After some reluctance from part of the chemistry community, the Charlot ...
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École Supérieure De Physique Et De Chimie Industrielles De La Ville De Paris
ESPCI Paris (officially the École supérieure de physique et de chimie industrielles de la ville de Paris, , ''The City of Paris Industrial Physics and Chemistry Higher Educational Institution'') is a grande école founded in 1882 by the city of Paris, France. It educates undergraduate and graduate students in physics, chemistry and biology and conducts high-level research in those fields. It is ranked as the first French ''École d'Ingénieurs'' in the 2017 Shanghai Ranking. ESPCI Paris is a constituent college of Université PSL and a founding member of the ParisTech (Paris Institute of Technology) alliance. Two thirds of the students enter the school following a competitive examination (concours X-ESPCI- ENS) following at least two years of Classes Préparatoires. The other students are recruited by submitting applications. The school itself is also known as Physique-Chimie or simply PC. ESPCI Paris nurtures relationships with many industrial partners such as Schlumberger ...
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Institut National Des Sciences Et Techniques Nucléaires
''L'Institut national des sciences et techniques nucléaires'' (INSTN, National Institute for Nuclear Science and Technology), is a public higher education institution administered by the CEA (French Alternative Energies and Atomic Energy Commission) under the joint authority of the Ministry of National Education, Higher Education and Research, the Ministry of the Economy, Industry and the Digital Sector and the Ministry of the Environment, Energy and Marine Affairs. It is the main centre of education for nuclear energy in France. History The establishment of INSTN goes back to 1956 with the purpose of training engineers, researchers, and technicians who were tasked with implementing the French civil nuclear development program introduced in the 1950s. Since its creation, the mission of INSTN has been to support the transfer of knowledge and know-how developed by the CEA and its industrial partners in order to support the growth of the nuclear industry worldwide. One of its main ...
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Brønsted–Lowry Acid–base Theory
The Brønsted–Lowry theory (also called proton theory of acids and bases) is an acid–base reaction theory which was developed independently in 1923 by physical chemists Johannes Nicolaus Brønsted (in Denmark) and Thomas Martin Lowry (in the United Kingdom). The basic concept of this theory is that when an acid and a base react with each other, the acid forms its conjugate base, and the base forms its conjugate acid by exchange of a proton (the hydrogen cation, or H+). This theory generalises the Arrhenius theory. Definitions of acids and bases In the Arrhenius theory, acids are defined as substances that dissociate in aqueous solutions to give H+ ( hydrogen cations or protons), while bases are defined as substances that dissociate in aqueous solutions to give OH− (hydroxide ions). In 1923, physical chemists Johannes Nicolaus Brønsted in Denmark and Thomas Martin Lowry in England both independently proposed the theory named after them. In the Brønsted–Lowry ...
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Hydrogen Sulfide
Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is toxic, corrosive, and flammable. Trace amounts in ambient atmosphere have a characteristic foul odor of rotten eggs. Swedish chemist Carl Wilhelm Scheele is credited with having discovered the chemical composition of purified hydrogen sulfide in 1777. Hydrogen sulfide is toxic to humans and most other animals by inhibiting cellular respiration in a manner similar to hydrogen cyanide. When it is inhaled or its salts are ingested in high amounts, damage to organs occurs rapidly with symptoms ranging from breathing difficulties to convulsions and death. Despite this, the human body produces small amounts of this sulfide and its mineral salts, and uses it as a signalling molecule. Hydrogen sulfide is often produced from the microbial breakdown of organic matter in the absence of oxygen, such as in swamps and sewers; this process is commonly known as anaerobic digestio ...
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Electrochemical
Electrochemistry is the branch of physical chemistry concerned with the relationship between electrical potential difference and identifiable chemical change. These reactions involve electrons moving via an electronically conducting phase (typically an external electrical circuit, but not necessarily, as in electroless plating) between electrodes separated by an ionically conducting and electronically insulating electrolyte (or ionic species in a solution). When a chemical reaction is driven by an electrical potential difference, as in electrolysis, or if a potential difference results from a chemical reaction as in an electric battery or fuel cell, it is called an ''electrochemical'' reaction. Unlike in other chemical reactions, in electrochemical reactions electrons are not transferred directly between atoms, ions, or molecules, but via the aforementioned electronically conducting circuit. This phenomenon is what distinguishes an electrochemical reaction from a conventional ...
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Colorimetric
Colorimetry is "the science and technology used to quantify and describe physically the human color perception". It is similar to spectrophotometry, but is distinguished by its interest in reducing spectra to the physical correlates of color perception, most often the CIE 1931 XYZ color space tristimulus values and related quantities. History The Duboscq colorimeter was invented by Jules Duboscq in 1870. Instruments Colorimetric equipment is similar to that used in spectrophotometry. Some related equipment is also mentioned for completeness. * A tristimulus colorimeter measures the tristimulus values of a color. * A spectroradiometer measures the absolute spectral radiance (intensity) or irradiance of a light source. * A spectrophotometer measures the spectral reflectance, transmittance, or relative irradiance of a color sample. * A ''spectrocolorimeter'' is a spectrophotometer that can ''calculate'' tristimulus values. * A densitometer measures the degree of lig ...
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Utrecht (city)
Utrecht ( ; ; ) is the List of cities in the Netherlands by province, fourth-largest city of the Netherlands, as well as the capital and the most populous city of the Provinces of the Netherlands, province of Utrecht (province), Utrecht. The municipality of Utrecht is located in the eastern part of the Randstad conurbation, in the very centre of mainland Netherlands, and includes Haarzuilens, Vleuten and De Meern. It has a population of 376,435 as of . Utrecht's ancient city centre features many buildings and structures, several dating as far back as the High Middle Ages. It has been the religious centre of the Netherlands since the 8th century. In 1579, the Union of Utrecht was signed in the city to lay the foundations for the Dutch Republic. Utrecht was the most important city in the Netherlands until the Dutch Golden Age, when it was surpassed by Amsterdam as the country's cultural centre and most populous city. Utrecht is home to Utrecht University, the largest university ...
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French Academy Of Sciences
The French Academy of Sciences (, ) is a learned society, founded in 1666 by Louis XIV at the suggestion of Jean-Baptiste Colbert, to encourage and protect the spirit of French Scientific method, scientific research. It was at the forefront of scientific developments in Europe in the 17th and 18th centuries, and is one of the earliest Academy of Sciences, Academies of Sciences. Currently headed by Patrick Flandrin (President of the academy), it is one of the five Academies of the . __TOC__ History The Academy of Sciences traces its origin to Colbert's plan to create a general academy. He chose a small group of scholars who met on 22 December 1666 in the King's library, near the present-day Bibliothèque nationale de France, Bibliothèque Nationale, and thereafter held twice-weekly working meetings there in the two rooms assigned to the group. The first 30 years of the academy's existence were relatively informal, since no statutes had as yet been laid down for the ins ...
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Légion D'honneur
The National Order of the Legion of Honour ( ), formerly the Imperial Order of the Legion of Honour (), is the highest and most prestigious French national order of merit, both military and Civil society, civil. Currently consisting of five classes, it was originally established in 1802 by Napoleon, Napoleon Bonaparte, and it has been retained (with occasional slight alterations) by all later French governments and regimes. The order's motto is ' ("Honour and Fatherland"); its Seat (legal entity), seat is the Palais de la Légion d'Honneur next to the Musée d'Orsay, on the left bank of the Seine in Paris. Since 1 February 2023, the Order's grand chancellor has been retired General François Lecointre, who succeeded fellow retired General Benoît Puga in office. The order is divided into five degrees of increasing distinction: ' (Knight), ' (Officer), ' (Commander (order), Commander), ' (Grand Officer) and ' (Grand Cross). History Consulate During the French Revolution, all ...
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Charlot Equation
The Charlot equation, named after Gaston Charlot, is used in analytical chemistry to relate the hydrogen ion concentration, and therefore the pH, with the formal analytical concentration of an acid and its conjugate base. It can be used for computing the pH of buffer solutions when the approximations of the Henderson–Hasselbalch equation break down. The Henderson–Hasselbalch equation assumes that the autoionization of water is negligible and that the dissociation or hydrolysis of the acid and the base in solution are negligible (in other words, that the formal concentration is the same as the equilibrium concentration). For an acid-base equilibrium such as HA H+ + A−, the Charlot equation may be written as :\mathrm = K_a \frac where +is the equilibrium concentration of H+, ''K''a is the acid dissociation constant, ''C''a and ''C''b are the analytical concentrations of the acid and its conjugate base, respectively, and Δ = +− H− The equation can be solved for +by us ...
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Members Of The French Academy Of Sciences
Member may refer to: * Military jury, referred to as "Members" in military jargon * Element (mathematics), an object that belongs to a mathematical set * In object-oriented programming, a member of a class ** Field (computer science) In data hierarchy, a field (data field) is a Variable (computer science), variable in a record (computer science), record. A record, also known as a data structure, allows logically related data to be identified by a single name. Identifying relate ..., entries in a database ** Member variable, a variable that is associated with a specific object * Limb (anatomy), an appendage of the human or animal body ** Euphemism for penis * Structural component of a truss, connected by nodes * User (computing), a person making use of a computing service, especially on the Internet * Member (geology), a component of a geological formation * Member of parliament * The Members, a British punk rock band * Meronymy, a semantic relationship in linguistics * C ...
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