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Flexoelectricity
Flexoelectricity is a property of a dielectric material where there is coupling between electrical polarization and a strain gradient. This phenomenon is closely related to piezoelectricity, but while piezoelectricity refers to polarization due to uniform strain, flexoelectricity specifically involves polarization due to strain that varies from point to point in the material. This nonuniform strain breaks centrosymmetry, meaning that unlike in piezoelectricity, flexoelectric effects occur in both centrosymmetric and asymmetric crystal structures. This property is not the same as ferroelasticity. It plays a critical role in explaining many interesting electromechanical behaviors in hard crystalline materials and core mechanoelectric transduction phenomena in soft biomaterials. Additionally, it is a size-dependent effect that becomes more significant in nanoscale systems, such as crack tips. In common usage, flexoelectricity is the generation of polarization due to a strain gradie ...
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Triboelectric Effect
The triboelectric effect (also known as triboelectricity, triboelectric charging, triboelectrification, or tribocharging) describes electric charge transfer between two objects when they contact or slide against each other. It can occur with different materials, such as the sole of a shoe on a carpet, or between two pieces of the same material. It is ubiquitous, and occurs with differing amounts of charge transfer (tribocharge) for all solid materials. There is evidence that tribocharging can occur between combinations of solids, liquids and gases, for instance liquid flowing in a solid tube or an aircraft flying through air. Often static electricity is a consequence of the triboelectric effect when the charge stays on one or both of the objects and is not conducted away. The term triboelectricity has been used to refer to the field of study or the general phenomenon of the triboelectric effect, or to the static electricity that results from it. When there is no sliding, triboc ...
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Dielectric
In electromagnetism, a dielectric (or dielectric medium) is an Insulator (electricity), electrical insulator that can be Polarisability, polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the material as they do in an electrical conductor, because they have no loosely bound, or free, electrons that may drift through the material, but instead they shift, only slightly, from their average equilibrium positions, causing dielectric polarisation. Because of Polarisation density, dielectric polarisation, positive charges are displaced in the direction of the field and negative charges shift in the direction opposite to the field. This creates an internal electric field that reduces the overall field within the dielectric itself. If a dielectric is composed of weakly Chemical bond, bonded molecules, those molecules not only become polarised, but also reorient so that their Symmetry axis, symmetry axes a ...
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Deformation (mechanics)
In physics and continuum mechanics, deformation is the change in the shape (geometry), shape or size of an object. It has dimension (physics), dimension of length with SI unit of metre (m). It is quantified as the residual displacement (geometry), displacement of particles in a non-rigid body, from an configuration to a configuration, excluding the body's average translation (physics), translation and rotation (its rigid transformation). A ''configuration'' is a set containing the position (geometry), positions of all particles of the body. A deformation can occur because of structural load, external loads, intrinsic activity (e.g. muscle contraction), body forces (such as gravity or electromagnetic forces), or changes in temperature, moisture content, or chemical reactions, etc. In a continuous body, a ''deformation field'' results from a Stress (physics), stress field due to applied forces or because of some changes in the conditions of the body. The relation between stre ...
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Piezoelectricity
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoelectric effect results from the linear electromechanical interaction between the mechanical and electrical states in crystalline materials with no inversion symmetry. The piezoelectric effect is a reversible process: materials exhibiting the piezoelectric effect also exhibit the reverse piezoelectric effect, the internal generation of a mechanical strain resulting from an applied electric field. For example, lead zirconate titanate crystals will generate measurable piezoelectricity when their static structure is deformed by about 0.1% of the original dimension. Conversely, those same crystals will change about 0.1% of their static dimension when an external electric field is applied. The inverse piezoelectric effect is used in the pro ...
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Centrosymmetry
In crystallography, a centrosymmetric point group contains an inversion center as one of its symmetry elements. In such a point group, for every point (x, y, z) in the unit cell there is an indistinguishable point (-x, -y, -z). Such point groups are also said to have ''inversion'' symmetry. Point reflection is a similar term used in geometry. Crystals with an inversion center cannot display certain properties, such as the piezoelectric effect and the frequency doubling effect (second-harmonic generation). In addition, in such crystals, one-photon absorption (OPA) and two-photon absorption (TPA) processes are mutually exclusive, i.e., they do not occur simultaneously, and provide complementary information. The following space groups have inversion symmetry: the triclinic space group 2, the monoclinic 10-15, the orthorhombic 47-74, the tetragonal 83-88 and 123-142, the trigonal 147, 148 and 162-167, the hexagonal 175, 176 and 191-194, the cubic 200-206 and 221-230. Point gro ...
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Annual Review Of Materials Research
The ''Annual Review of Materials Research'' is a peer-reviewed journal that publishes review articles about materials science. It has been published by the nonprofit Annual Reviews since 1971, when it was first released under the title the ''Annual Review of Materials Science''. Four people have served as editors, with the current editor Ram Seshadri stepping into the position in 2024. It has an impact factor of 10.6 as of 2024. As of 2023, it is being published as open access, under the Subscribe to Open model. History The ''Annual Review of Materials Science'' was first published in 1971 by the nonprofit publisher Annual Reviews, making it their sixteenth journal. Its first editor was Robert Huggins. In 2001, its name was changed to the current form, the ''Annual Review of Materials Research''. The name change was intended "to better reflect the broad appeal that materials research has for so many diverse groups of scientists and not simply those who identify themselves w ...
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Ferroelasticity
Ferroelasticity is a phenomenon in which a material may exhibit a spontaneous strain, and is the mechanical equivalent of ferroelectricity and ferromagnetism in the field of ferroics. A ferroelastic crystal has two or more stable orientational states in the absence of mechanical stress or electric field, i.e. remanent states, and can be reproducibly switched between the states by applying a stress or an electric field greater than some critical value. The application of opposite fields leads to Hysteresis as the system crosses back and forth across an energy barrier. This transition dissipates an energy equal to the area enclosed by the hysteresis loop. The transition of the crystal's parent structure to one of its stable ferroelastic strains is typically accompanied by a reduction in the crystal symmetry. The spontaneous change in strain and crystal structure can be associated with a spontaneous change in other observable properties, such as birefringence, optical absorption, and p ...
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Nano Lett
''Nano Letters'' is a monthly peer-reviewed scientific journal published by the American Chemical Society. It was established in January 2001. The editor-in-chief is Teri W. Odom (Northwestern University). The journal covers all aspects of nanoscience and nanotechnology and their subdisciplines. Abstracting and indexing The journal is currently abstracted and indexed in Chemical Abstracts Service, Scopus, EBSCOhost, Index Medicus/MEDLINE/PubMed, Science Citation Index, and Current Contents ''Current Contents'' is a rapid alerting service database from Clarivate, formerly the Institute for Scientific Information and Thomson Reuters. It is published online and in several different printed subject sections. History ''Current Contents .../Physical, Chemical & Earth Sciences. References External links * {{American Chemical Society Journals American Chemical Society academic journals Nanotechnology journals Academic journals established in 2001 Monthly journals Engli ...
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Strain (chemistry)
In chemistry, a molecule experiences strain when its chemical structure undergoes some Stress (mechanics), stress which raises its internal energy in comparison to a strain-free reference Chemical compound, compound. The internal energy of a molecule consists of all the energy stored within it. A strained molecule has an additional amount of internal energy which an unstrained molecule does not. This extra internal energy, or strain energy, can be likened to a compression (physics), compressed spring (device), spring.Anslyn and Dougherty, ''Modern Physical Organic Chemistry'', University Science Books, 2006, Much like a compressed spring must be held in place to prevent release of its potential energy, a molecule can be held in an energetically unfavorable conformation by the Chemical bond, bonds within that molecule. Without the bonds holding the conformation in place, the strain energy would be released. Summary Thermodynamics The Chemical equilibrium, equilibrium of two c ...
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Piezoelectricity
Piezoelectricity (, ) is the electric charge that accumulates in certain solid materials—such as crystals, certain ceramics, and biological matter such as bone, DNA, and various proteins—in response to applied mechanical stress. The piezoelectric effect results from the linear electromechanical interaction between the mechanical and electrical states in crystalline materials with no inversion symmetry. The piezoelectric effect is a reversible process: materials exhibiting the piezoelectric effect also exhibit the reverse piezoelectric effect, the internal generation of a mechanical strain resulting from an applied electric field. For example, lead zirconate titanate crystals will generate measurable piezoelectricity when their static structure is deformed by about 0.1% of the original dimension. Conversely, those same crystals will change about 0.1% of their static dimension when an external electric field is applied. The inverse piezoelectric effect is used in the pro ...
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Ferroelectricity
In physics and materials science, ferroelectricity is a characteristic of certain materials that have a spontaneous electric polarization that can be reversed by the application of an external electric field. All ferroelectrics are also piezoelectric and pyroelectric, with the additional property that their natural electrical polarization is reversible. The term is used in analogy to ferromagnetism, in which a material exhibits a permanent magnetic moment. Ferromagnetism was already known when ferroelectricity was discovered in 1920 in Rochelle salt by American physicist Joseph Valasek.See and Thus, the prefix ''ferro'', meaning iron, was used to describe the property despite the fact that most ferroelectric materials do not contain iron. Materials that are both ferroelectric ''and'' ferromagnetic are known as multiferroics. Polarization When most materials are electrically polarized, the polarization induced, ''P'', is almost exactly proportional to the applied extern ...
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Ferroelasticity
Ferroelasticity is a phenomenon in which a material may exhibit a spontaneous strain, and is the mechanical equivalent of ferroelectricity and ferromagnetism in the field of ferroics. A ferroelastic crystal has two or more stable orientational states in the absence of mechanical stress or electric field, i.e. remanent states, and can be reproducibly switched between the states by applying a stress or an electric field greater than some critical value. The application of opposite fields leads to Hysteresis as the system crosses back and forth across an energy barrier. This transition dissipates an energy equal to the area enclosed by the hysteresis loop. The transition of the crystal's parent structure to one of its stable ferroelastic strains is typically accompanied by a reduction in the crystal symmetry. The spontaneous change in strain and crystal structure can be associated with a spontaneous change in other observable properties, such as birefringence, optical absorption, and p ...
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