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Fatty Nitrile
In chemistry, a fatty amine is loosely defined as any amine possessing a mostly linear hydrocarbon chain of eight or more carbon atoms. They are typically prepared from the more abundant fatty acids, with vegetable or seed-oils being the ultimate starting material. As such they are often mixtures of chain lengths, ranging up to about C22. They can be classified as oleochemicals. Commercially important members include coco amine, oleylamine, tallow amine, and soya amine. These compounds and their derivatives are used as fabric softeners, froth flotation agents (purification of ores), corrosion inhibitors, lubricants and friction modifiers. They are also the basis for a variety of cosmetic formulations. Production and reactions Fatty amines are commonly prepared from fatty acids; which are themselves obtained from natural sources, typically seed-oils. The overall reaction is sometimes referred to as the Nitrile Process and begins with a reaction between the fatty acid and ammonia at ...
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Copper Chromite
Copper chromite often refers to inorganic compounds with the formula . They are black solids. is a well-defined material. The other copper chromite often is described as . It is used to catalyze reactions in organic chemistry. History Copper chromite was first described in 1908. The catalyst was further developed by Homer Burton Adkins and Wilbur Arthur Lazier, partly based on interrogation of German chemists after World War II in relation to the Fischer–Tropsch process. For this reason it is sometimes referred to as the Adkins catalyst or the Lazier catalyst. Adkins was the first to incorporate barium into the structure, which prevents the catalyst from being reduced to an inactive form during hydrogenation reactions. Chemical structures The stoichiometry of the Laziar or Adkins catalyst is not well defined, thus the structure of their material is not defined either. The oxidation states for the constituent metals in Cu2Cr2O4 are Cu(II) and Cr(III). A variety of compo ...
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Lauryldimethylamine Oxide
Lauryldimethylamine oxide (LDAO), also known as dodecyldimethylamine oxide (DDAO), is an amine oxide–based zwitterionic surfactant, with a C12 (dodecyl) alkyl tail. It is one of the most frequently-used surfactants of this type. Like other amine oxide–based surfactants it is antimicrobial, being effective against common bacteria such as '' S. aureus'' and ''E. coli'', however, it is also non-denaturing and can thus be used for protein purification. At high concentrations, LDAO forms liquid crystalline phases. Despite having only one polar atom that is able to interact with water – the oxygen atom (the quaternary nitrogen atom is hidden from intermolecular interactions), DDAO is a strongly amphiphilic surfactant: it forms normal micelle A micelle () or micella () ( or micellae, respectively) is an aggregate (or supramolecular assembly) of surfactant amphipathic lipid molecules dispersed in a liquid, forming a colloidal suspension (also known as associated colloidal sy ...
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Asphalt Concrete
Asphalt concrete (commonly called asphalt, blacktop, or pavement in North America, and Tarmacadam, tarmac or bitumen macadam in the United Kingdom and the Republic of Ireland) is a composite material commonly used to surface road surface, roads, parking lots, airports, and the core of embankment dams. Asphalt mixtures have been used in pavement construction since the nineteenth century. It consists of Construction aggregate, mineral aggregate Binder (material), bound together with bitumen (a substance also independently known as asphalt, Pitch (resin), pitch, or tar), laid in layers, and compacted. The American English terms ''asphalt'' (or ''asphaltic'') ''concrete'', ''bituminous asphalt concrete'', and ''bituminous mixture'' are typically used only in engineering and construction documents, which define concrete as any composite material composed of mineral aggregate adhered with a binder. The abbreviation, ''AC'', is sometimes used for ''asphalt concrete'' but can also denot ...
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Behentrimonium Chloride
Behentrimonium chloride, also known as docosyltrimethylammonium chloride or BTAC-228, is a yellow waxlike organic compound with chemical formula , used as an antistatic agent and, sometimes, a disinfectant. It is commonly found in cosmetics such as conditioners, hair dye, and mousse, and also in detergents. Laboratory tests have indicated that it does readily biodegrade. See also * Cetrimonium bromide – a C19 structural analogue * Cetrimonium chloride Cetrimonium chloride, or cetyltrimethylammonium chloride (CTAC), is a topical antiseptic and surfactant. Long-chain quaternary ammonium surfactants, such as cetyltrimethylammonium chloride (CTAC), are generally combined with long-chain fatty alc ... – a C19 structural analogue References External links Behentrimonium chloride at the Household Products Database Cosmetics chemicals Disinfectants Water treatment Antistatic agents Chlorides Cationic surfactants Quaternary ammonium compounds {{Carbohydrate-stub ...
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Hair Conditioner
Hair conditioner is a hair care cosmetic product used to improve the feel, texture, appearance and manageability of hair. Its main purpose is to reduce friction between strands of hair to allow smoother brushing or combing, which might otherwise cause damage to the scalp. Various other benefits are often advertised, such as hair repair, strengthening, or a reduction in split ends. Conditioners are available in a wide range of forms, including viscous liquids, gels and creams, as well as thinner lotions and sprays. Hair conditioner is usually used after the hair has been washed with shampoo. It is applied and worked into the hair and may either be rinsed out a short time later or left in. History For centuries, natural oils have been used to condition human hair. A conditioner popular with men in the late Victorian era was Macassar oil, but this product was quite greasy and necessitated the pinning of a small cloth, known as an antimacassar, to the headrests of chairs and sofa ...
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Quaternary Ammonium Salt
In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure , where R is an alkyl group, an aryl group or organyl group. Unlike the ammonium ion () and the primary, secondary, or tertiary ammonium cations, the quaternary ammonium cations are permanently charged, independent of the pH of their solution. Quaternary ammonium salts or quaternary ammonium compounds (called quaternary amines in oilfield parlance) are salts of quaternary ammonium cations. Polyquats are a variety of engineered polymer forms which provide multiple quat molecules within a larger molecule. Quats are used in consumer applications including as antimicrobials (such as detergents and disinfectants), fabric softeners, and hair conditioners. As an antimicrobial, they are able to inactivate enveloped viruses (such as SARS-CoV-2). Quats tend to be gentler on surfaces than bleach-based disinfectants, and are generally fabric-safe. Synthes ...
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Formic Acid
Formic acid (), systematically named methanoic acid, is the simplest carboxylic acid. It has the chemical formula HCOOH and structure . This acid is an important intermediate in chemical synthesis and occurs naturally, most notably in some ants. Esters, salts, and the anion derived from formic acid are called formates. Industrially, formic acid is produced from methanol. Natural occurrence Formic acid, which has a pungent, penetrating odor, is found naturally in insects, weeds, fruits and vegetables, and forest emissions. It appears in most ants and in stingless bees of the genus '' Oxytrigona''. Wood ants from the genus ''Formica'' can spray formic acid on their prey or to defend the nest. The puss moth caterpillar (''Cerura vinula'') will spray it as well when threatened by predators. It is also found in the trichomes of stinging nettle (''Urtica dioica''). Apart from that, this acid is incorporated in many fruits such as pineapple (0.21 mg per 100 g), apple (2 mg per ...
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Formaldehyde
Formaldehyde ( , ) (systematic name methanal) is an organic compound with the chemical formula and structure , more precisely . The compound is a pungent, colourless gas that polymerises spontaneously into paraformaldehyde. It is stored as aqueous solutions (formalin), which consists mainly of the hydrate CH2(OH)2. It is the simplest of the aldehydes (). As a precursor to many other materials and chemical compounds, in 2006 the global production of formaldehyde was estimated at 12 million tons per year. It is mainly used in the production of industrial resins, e.g., for particle board and coatings. Formaldehyde also occurs naturally. It is derived from the degradation of serine, dimethylglycine, and lipids. Demethylases act by converting N-methyl groups to formaldehyde. Formaldehyde is classified as a group 1 carcinogen and can cause respiratory and skin irritation upon exposure. Forms Formaldehyde is more complicated than many simple carbon compounds in that i ...
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Leuckart Reaction
The Leuckart reaction is the chemical reaction that converts aldehydes or ketones to amines. The reaction is an example of reductive amination. The reaction, named after Rudolf Leuckart (chemist), Rudolf Leuckart, uses either ammonium formate or formamide as the nitrogen donor and reducing agent. It requires high temperatures, usually between 120 and 130 °C; for the formamide variant, the temperature can be greater than 165 °C. History The Leuckart reaction is named in honor of its developer, the German chemist Rudolf Leuckart (chemist), Rudolf Leuckart (1854–1899). He discovered that heating benzaldehyde with formamide does not produce benzylidenediformamide as anticipated, but benzylamine. In 1891, a colleague of Leuckart at the University of Göttingen, Otto Wallach, performed further reactions using alicyclic and terpenoid ketones as well as aldehydes, demonstrating the general application. Over the course of the past century, chemists have discovered severa ...
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Phase Transfer Catalyst
In chemistry, a phase-transfer catalyst or PTC is a catalyst that facilitates the transition of a reactant from one phase into another phase where reaction occurs. Phase-transfer catalysis is a special form of catalysis and can act through homogeneous catalysis or heterogeneous catalysis methods depending on the catalyst used. Ionic reactants are often soluble in an aqueous phase but insoluble in an organic phase in the absence of the phase-transfer catalyst. The catalyst functions like a detergent for solubilizing the salts into the organic phase. Phase-transfer catalysis refers to the acceleration of the reaction upon the addition of the phase-transfer catalyst. PTC is widely exploited industrially.Marc Halpern "Phase-Transfer Catalysis" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim. Polyesters for example are prepared from acyl chlorides and bisphenol-A. Phosphothioate-based pesticides are generated by PTC-catalyzed alkylation of phosphothioates ...
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Quaternary Ammonium Salts
In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure , where R is an alkyl group, an aryl group or organyl group. Unlike the ammonium ion () and the primary, secondary, or tertiary ammonium cations, the quaternary ammonium cations are permanently charged, independent of the pH of their solution. Quaternary ammonium salts or quaternary ammonium compounds (called quaternary amines in oilfield parlance) are salts of quaternary ammonium cations. Polyquats are a variety of engineered polymer forms which provide multiple quat molecules within a larger molecule. Quats are used in consumer applications including as antimicrobials (such as detergents and disinfectants), fabric softeners, and hair conditioners. As an antimicrobial, they are able to inactivate enveloped viruses (such as SARS-CoV-2). Quats tend to be gentler on surfaces than bleach-based disinfectants, and are generally fabric-safe. Synthesis Q ...
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