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Constrictivity
Constrictivity is a dimensionless parameter used to describe transport processes (often molecular diffusion) in porous media. Constrictivity is viewed to depend on the ratio of the diameter of the diffusing particle to the pore diameter. The value of constrictivity is always less than 1. The constrictivity is defined not for a single pore, but as the parameter of the entire pore space considered. The resistance to transport in porous media increases because the viscosity of the fluid (which fills the pores) increases in the vicinity of the pore walls (Renkin effect;Renkin, EM (1954): ''Filtration, diffusion and molecular sieving through porous cellulose membranes.'' J. Gen. Physiologist., 38: 225-243 see also electroviscous effects). This effect is important in very narrow pores and in pore narrowing their diameter to the same size as the diameter of the diffusing particles. Constrictivity must be distinguished from the effects of Knudsen diffusion. Knudsen diffusion occurs when ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Electroviscous Effects
Electroviscous effects, in chemistry of colloids and surface chemistry, according to an IUPAC definition, are the effects of the particle surface charge on viscosity of a fluid. Viscoelectric is an effect by which an electric field near a charged interface influences the structure of the surrounding fluid and affects the viscosity of the fluid. Kinematic viscosity of a fluid, η, can be expressed as a function of electric potential gradient (electric field), \vec E, by an equation in the form: \eta=\eta_0 \left(1+ f\, \lVert \rVert^\right) where f is the viscoelectric coefficient of the fluid. The value of f for water (ambient temperature) has been estimated to be (0.5–1.0) × 10−15 V−2 m2.Robert J. Hunter and J. V. Leyendekkers, "Viscoelectric coefficient for water", J. Chem. Soc., Faraday Trans. 1, 1978, 74, 450-455. See also * Constrictivity * Electrorheological fluid * Wien effect The Wien effect is the experimentally-observed increase in ionic mobility or conduct ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transport Phenomena
In engineering, physics, and chemistry, the study of transport phenomena concerns the exchange of mass, energy, charge, momentum and angular momentum between observed and studied systems. While it draws from fields as diverse as continuum mechanics and thermodynamics, it places a heavy emphasis on the commonalities between the topics covered. Mass, momentum, and heat transport all share a very similar mathematical framework, and the parallels between them are exploited in the study of transport phenomena to draw deep mathematical connections that often provide very useful tools in the analysis of one field that are directly derived from the others. The fundamental analysis in all three subfields of mass, heat, and momentum transfer are often grounded in the simple principle that the total sum of the quantities being studied must be conserved by the system and its environment. Thus, the different phenomena that lead to transport are each considered individually with the knowledge ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Molecular Diffusion
Molecular diffusion, often simply called diffusion, is the thermal motion of all (liquid or gas) particles at temperatures above absolute zero. The rate of this movement is a function of temperature, viscosity of the fluid and the size (mass) of the particles. Diffusion explains the net flux of molecules from a region of higher concentration to one of lower concentration. Once the concentrations are equal the molecules continue to move, but since there is no concentration gradient the process of molecular diffusion has ceased and is instead governed by the process of self-diffusion, originating from the random motion of the molecules. The result of diffusion is a gradual mixing of material such that the distribution of molecules is uniform. Since the molecules are still in motion, but an equilibrium has been established, the result of molecular diffusion is called a "dynamic equilibrium". In a phase with uniform temperature, absent external net forces acting on the particles, th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Porous Medium
A porous medium or a porous material is a material containing pores (voids). The skeletal portion of the material is often called the "matrix" or "frame". The pores are typically filled with a fluid ( liquid or gas). The skeletal material is usually a solid, but structures like foams are often also usefully analyzed using concept of porous media. A porous medium is most often characterised by its porosity. Other properties of the medium (e.g. permeability, tensile strength, electrical conductivity, tortuosity) can sometimes be derived from the respective properties of its constituents (solid matrix and fluid) and the media porosity and pores structure, but such a derivation is usually complex. Even the concept of porosity is only straightforward for a poroelastic medium. Often both the solid matrix and the pore network (also known as the pore space) are continuous, so as to form two interpenetrating continua such as in a sponge. However, there is also a concept of closed poro ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Particle
In the physical sciences, a particle (or corpuscule in older texts) is a small localized object which can be described by several physical or chemical properties, such as volume, density, or mass. They vary greatly in size or quantity, from subatomic particles like the electron, to microscopic particles like atoms and molecules, to macroscopic particles like powders and other granular materials. Particles can also be used to create scientific models of even larger objects depending on their density, such as humans moving in a crowd or celestial bodies in motion. The term ''particle'' is rather general in meaning, and is refined as needed by various scientific fields. Anything that is composed of particles may be referred to as being particulate. However, the noun '' particulate'' is most frequently used to refer to pollutants in the Earth's atmosphere, which are a suspension of unconnected particles, rather than a connected particle aggregation. Conceptual properties ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Viscosity
The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the internal frictional force between adjacent layers of fluid that are in relative motion. For instance, when a viscous fluid is forced through a tube, it flows more quickly near the tube's axis than near its walls. Experiments show that some stress (such as a pressure difference between the two ends of the tube) is needed to sustain the flow. This is because a force is required to overcome the friction between the layers of the fluid which are in relative motion. For a tube with a constant rate of flow, the strength of the compensating force is proportional to the fluid's viscosity. In general, viscosity depends on a fluid's state, such as its temperature, pressure, and rate of deformation. However, the dependence on some of these properties is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Knudsen Diffusion
In physics, Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved. An example of this is in a long pore with a narrow diameter (2–50 nm) because molecules frequently collide with the pore wall. Consider the diffusion of gas molecules through very small capillary pores. If the pore diameter is smaller than the mean free path of the diffusing gas molecules and the density of the gas is low, the gas molecules collide with the pore walls more frequently than with each other. This process is known as Knudsen flow or Knudsen diffusion. The Knudsen number is a good measure of the relative importance of Knudsen diffusion. A Knudsen number much greater than one indicates Knudsen diffusion is important. In practice, Knudsen diffusion applies only to gases because the mean free path for molecules in the liquid state is very small, typically nea ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Porosity
Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface (cf. closed-cell foam). There are many ways to test porosity in a substance or part, such as industrial CT scanning. The term porosity is used in multiple fields including pharmaceutics, ceramics, metallurgy, materials, manufacturing, petrophysics, hydrology, earth sciences, soil mechanics, and engineering. Void fraction in two-phase flow In gas-liquid two-phase flow, the void fraction is defined as the fraction of the flow-channel volume that is occupied by the gas phase or, alternatively, as the fraction of the cross-sectional area of the channel that is occupied by the gas phase. Void fraction usually varies from location to location in the ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Tortuosity
Tortuosity is widely used as a critical parameter to predict transport properties of porous media, such as rocks and soils. But unlike other standard microstructural properties, the concept of tortuosity is vague with multiple definitions and various evaluation methods introduced in different contexts. Hydraulic, electrical, diffusional, and thermal tortuosities are defined to describe different transport processes in porous media, while geometrical tortuosity is introduced to characterize the morphological property of porous microstructures. Tortuosity in 2-D Subjective estimation (sometimes aided by optometric grading scales) is often used. The simplest mathematical method to estimate tortuosity is the arc-chord ratio: the ratio of the length of the curve (''C'') to the distance between its ends (''L''): :\tau = \frac Arc-chord ratio equals 1 for a straight line and is infinite for a circle. Another method, proposed in 1999, is to estimate the tortuosity as the integral of ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Diffusivity (biology)
Diffusivity, mass diffusivity or diffusion coefficient is a proportionality constant between the molar flux due to molecular diffusion and the gradient in the concentration of the species (or the driving force for diffusion). Diffusivity is encountered in Fick's law and numerous other equations of physical chemistry. The diffusivity is generally prescribed for a given pair of species and pairwise for a multi-species system. The higher the diffusivity (of one substance with respect to another), the faster they diffuse into each other. Typically, a compound's diffusion coefficient is ~10,000× as great in air as in water. Carbon dioxide in air has a diffusion coefficient of 16 mm2/s, and in water its diffusion coefficient is 0.0016 mm2/s. Diffusivity has dimensions of length2 / time, or m2/s in SI units and cm2/s in CGS units. Temperature dependence of the diffusion coefficient Solids The diffusion coefficient in solids at different temperatures is generally found ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Porous Media
A porous medium or a porous material is a material containing pores (voids). The skeletal portion of the material is often called the "matrix" or "frame". The pores are typically filled with a fluid (liquid or gas). The skeletal material is usually a solid, but structures like foams are often also usefully analyzed using concept of porous media. A porous medium is most often characterised by its porosity. Other properties of the medium (e.g. permeability, tensile strength, electrical conductivity, tortuosity) can sometimes be derived from the respective properties of its constituents (solid matrix and fluid) and the media porosity and pores structure, but such a derivation is usually complex. Even the concept of porosity is only straightforward for a poroelastic medium. Often both the solid matrix and the pore network (also known as the pore space) are continuous, so as to form two interpenetrating continua such as in a sponge. However, there is also a concept of closed porosi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Transport Phenomena
In engineering, physics, and chemistry, the study of transport phenomena concerns the exchange of mass, energy, charge, momentum and angular momentum between observed and studied systems. While it draws from fields as diverse as continuum mechanics and thermodynamics, it places a heavy emphasis on the commonalities between the topics covered. Mass, momentum, and heat transport all share a very similar mathematical framework, and the parallels between them are exploited in the study of transport phenomena to draw deep mathematical connections that often provide very useful tools in the analysis of one field that are directly derived from the others. The fundamental analysis in all three subfields of mass, heat, and momentum transfer are often grounded in the simple principle that the total sum of the quantities being studied must be conserved by the system and its environment. Thus, the different phenomena that lead to transport are each considered individually with the knowledge ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
