Compacted Oxide Layer Glaze
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Compacted Oxide Layer Glaze
Compacted oxide layer glaze describes the often shiny, wear-protective layer of oxide formed when two metals (or a metal and ceramic) are slid against each other at high temperature in an oxygen-containing atmosphere. The layer forms on either or both of the surfaces in contact and can protect against wear. Background A not often used definition of ''glaze'' is the highly sintered compacted oxide layer formed due to the sliding of either two metallic surfaces (or sometimes a metal surface and ceramic surface) at high temperatures (normally several hundred degrees Celsius) in oxidizing conditions. The sliding or tribological action generates oxide debris that can be compacted against one or both sliding surfaces and, under the correct conditions of load, sliding speed and oxide chemistry as well as (high) temperature, sinter together to form a 'glaze' layer. The 'glaze' formed in such cases is actually a crystalline oxide, with a very small crystal or grain size having been sh ...
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Oxide
An oxide () is a chemical compound that contains at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion of oxygen, an O2– (molecular) ion. with oxygen in the oxidation state of −2. Most of the Earth's crust consists of oxides. Even materials considered pure elements often develop an oxide coating. For example, aluminium foil develops a thin skin of Al2O3 (called a passivation layer) that protects the foil from further corrosion.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry of the Elements (2nd Edn.), Oxford:Butterworth-Heinemann. . Stoichiometry (the measurable relationship between reactants and chemical equations of a equation or reaction) Oxides are extraordinarily diverse in terms of stoichiometries and in terms of the structures of each stoichiometry. Most elements form oxides of more than one stoichiometry. A well known example is carbon monoxide and carbon dioxide.Greenwood, N. N.; & Earnshaw, A. (1997). Chemistry ...
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