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Cement Kiln
Cement kilns are used for the pyroprocessing stage of manufacture of portland and other types of hydraulic cement, in which calcium carbonate reacts with silica-bearing minerals to form a mixture of calcium silicates. Over a billion tonnes of cement are made per year, and cement kilns are the heart of this production process: their capacity usually defines the capacity of the cement plant. As the main energy-consuming and greenhouse-gas–emitting stage of cement manufacture, improvement of kiln efficiency has been the central concern of cement manufacturing technology. Emissions from cement kilns are a major source of greenhouse gas emissions, accounting for around 2.5% of non-natural carbon emissions worldwide. The manufacture of cement clinker A typical process of manufacture consists of three stages: * grinding a mixture of limestone and clay or shale to make a fine "rawmix" (see Rawmill); * heating the rawmix to sintering temperature (up to 1450 °C) in a cement k ...
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Fuel
A fuel is any material that can be made to react with other substances so that it releases energy as thermal energy or to be used for work. The concept was originally applied solely to those materials capable of releasing chemical energy but has since also been applied to other sources of heat energy, such as nuclear energy (via nuclear fission and nuclear fusion). The heat energy released by reactions of fuels can be converted into mechanical energy via a heat engine. Other times, the heat itself is valued for warmth, cooking, or industrial processes, as well as the illumination that accompanies combustion. Fuels are also used in the cells of organisms in a process known as cellular respiration, where organic molecules are oxidized to release usable energy. Hydrocarbons and related organic molecules are by far the most common source of fuel used by humans, but other substances, including radioactive metals, are also utilized. Fuels are contrasted with other substance ...
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Frederick Ransome
Frederick Ransome (1818–1893) was a British inventor and industrialist, creator of Ransome's artificial stone. Frederick was the son of James Ransome, 1782–1849, a member of the Ransomes steel and agricultural equipment-making family of Ipswich. In 1844 Frederick invented an artificial sandstone, using sand and powdered flint in an alkaline solution. By heating it in an enclosed high temperature steam boiler the siliceous particles were bound together and could be moulded or worked. With properties equivalent to natural stone, it found applications as filtering slabs, vases, tombstones, decorative architectural work, emery wheels and grindstones. Ransome founded the Patent Siliceous Stone Company in 1852 in order to produce and sell the stone, with an illustrious group of backers that included Charles Darwin, and the Patent Concrete Stone Company in 1865. However, the stone fell out of use, in favour of Portland cement-based concrete, which could be more simply cast on-sit ...
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Pennsylvania
Pennsylvania (; ( Pennsylvania Dutch: )), officially the Commonwealth of Pennsylvania, is a state spanning the Mid-Atlantic, Northeastern, Appalachian, and Great Lakes regions of the United States. It borders Delaware to its southeast, Maryland to its south, West Virginia to its southwest, Ohio to its west, Lake Erie and the Canadian province of Ontario to its northwest, New York to its north, and the Delaware River and New Jersey to its east. Pennsylvania is the fifth-most populous state in the nation with over 13 million residents as of 2020. It is the 33rd-largest state by area and ranks ninth among all states in population density. The southeastern Delaware Valley metropolitan area comprises and surrounds Philadelphia, the state's largest and nation's sixth most populous city. Another 2.37 million reside in Greater Pittsburgh in the southwest, centered around Pittsburgh, the state's second-largest and Western Pennsylvania's largest city. The state's sub ...
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Petroleum
Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude oil and petroleum products that consist of refined crude oil. A fossil fuel, petroleum is formed when large quantities of dead organisms, mostly zooplankton and algae, are buried underneath sedimentary rock and subjected to both prolonged heat and pressure. Petroleum is primarily recovered by oil drilling. Drilling is carried out after studies of structural geology, sedimentary basin analysis, and reservoir characterisation. Recent developments in technologies have also led to exploitation of other unconventional reserves such as oil sands and oil shale. Once extracted, oil is refined and separated, most easily by distillation, into innumerable products for direct use or use in manufacturing. Products include fuels such as gasol ...
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Firebrick
A fire brick, firebrick, or refractory is a block of ceramic material used in lining furnaces, kilns, fireboxes, and fireplaces. A refractory brick is built primarily to withstand high temperature, but will also usually have a low thermal conductivity for greater energy efficiency. Usually dense firebricks are used in applications with extreme mechanical, chemical, or thermal stresses, such as the inside of a wood-fired kiln or a furnace, which is subject to abrasion from wood, fluxing from ash or slag, and high temperatures. In other, less harsh situations, such as in an electric- or natural gas-fired kiln, more porous bricks, commonly known as "kiln bricks", are a better choice. They are weaker, but they are much lighter and easier to form and insulate far better than dense bricks. In any case, firebricks should not spall, and their strength should hold up well during rapid temperature changes. Manufacture In the making of firebrick, fireclay is fired in the kiln until it ...
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Rotary Kiln
A rotary kiln is a pyroprocessing device used to raise materials to a high temperature (calcination) in a continuous process. Materials produced using rotary kilns include: * Cement * Lime * Refractories * Metakaolin * Titanium dioxide * Alumina * Vermiculite * Iron ore pellets They are also used for roasting a wide variety of sulfide ores prior to metal extraction. Principle of operation The kiln is a cylindrical vessel, inclined slightly from the horizontal, which is rotated slowly about its longitudinal axis. The process feedstock is fed into the upper end of the cylinder. As the kiln rotates, material gradually moves down toward the lower end, and may undergo a certain amount of stirring and mixing. Hot gases pass along the kiln, sometimes in the same direction as the process material (co-current), but usually in the opposite direction (counter-current). The hot gases may be generated in an external furnace, or may be generated by a flame inside the kiln. Su ...
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Lime Kiln
A lime kiln is a kiln used for the calcination of limestone ( calcium carbonate) to produce the form of lime called quicklime (calcium oxide). The chemical equation for this reaction is : CaCO3 + heat → CaO + CO2 This reaction can take place at anywhere above 840 °C (1544 °F), but is generally considered to occur at 900 °C(1655 °F) (at which temperature the partial pressure of CO2 is 1 atmosphere), but a temperature around 1000 °C (1832 °F) (at which temperature the partial pressure of CO2 is 3.8 atmospheres) is usually used to make the reaction proceed quickly.Parkes, G.D. and Mellor, J.W. (1939). ''Mellor's Modern Inorganic Chemistry'' London: Longmans, Green and Co. Excessive temperature is avoided because it produces unreactive, "dead-burned" lime. Slaked lime (calcium hydroxide) can be formed by mixing quicklime with water. Early lime use Because it is so readily made by heating limestone, lime must have been known from the earlies ...
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Alite
Alite is an impure form of tricalcium silicate, , sometimes formulated as ( in cement chemist notation), typically with 3-4% of substituent oxides. It is the major, and characteristic, phase in Portland cement. The name was given by Törnebohm in 1897 to a crystal identified in microscopic investigation of Portland cement. Hatrurite is the name of a mineral that is substituted . Composition and structure The alite found in Portland cement differs in composition from simple tricalcium silicate. It is a solid solution and contains minor amounts of other oxides besides CaO and . A typical composition is: Based on this, the formula can be expressed as . In practice, the composition varies with the bulk composition of the clinker, subject to certain limits. Substitution of calcium ions or orthosilicate ions requires that electric charges be kept in balance. For instance, a limited number of orthosilicate () ions can be replaced with sulfate () ions, provided that for each su ...
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Calcium Oxide
Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "'' lime''" connotes calcium-containing inorganic materials, in which carbonates, oxides and hydroxides of calcium, silicon, magnesium, aluminium, and iron predominate. By contrast, ''quicklime'' specifically applies to the single chemical compound calcium oxide. Calcium oxide that survives processing without reacting in building products such as cement is called free lime. Quicklime is relatively inexpensive. Both it and a chemical derivative ( calcium hydroxide, of which quicklime is the base anhydride) are important commodity chemicals. Preparation Calcium oxide is usually made by the thermal decomposition of materials, such as limestone or seashells, that contain calcium carbonate (CaCO3; mineral calcite) in a lime kiln. This is accomplished by heating the material to above ,Me ...
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