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Bio-oil
Pyrolysis oil, sometimes also known as biocrude or bio-oil, is a synthetic fuel with few industrial applications and under investigation as substitute for petroleum. It is obtained by heating dried biomass without oxygen in a reactor at a temperature of about with subsequent cooling, separation from the aqueous phase and other processes. Pyrolysis oil is a kind of tar and normally contains levels of oxygen too high to be considered a pure hydrocarbon. This high oxygen content results in non-volatility, corrosiveness, partial miscibility with fossil fuels, thermal instability, and a tendency to polymerize when exposed to air. As such, it is distinctly different from petroleum products. Removing oxygen from bio-oil or nitrogen from algal bio-oil is known as upgrading. Standards There are few standards for pyrolysis oil because of few efforts to produce it. One is from ASTM. Feedstock decomposition Pyrolysis is a well established technique for decomposition of organic material ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Hydrothermal Liquefaction
Hydrothermal liquefaction (HTL) is a thermal depolymerization process used to convert wet biomass, and other macromolecules, into crude-like oil under moderate temperature and high pressure. The crude-like oil has high energy density with a lower heating value of 33.8-36.9 MJ/kg and 5-20 wt% oxygen and renewable chemicals. The process has also been called hydrous pyrolysis. The reaction usually involves homogeneous and/or heterogeneous catalysts to improve the quality of products and yields. Carbon and hydrogen of an organic material, such as biomass, peat or low-ranked coals (lignite) are thermo-chemically converted into hydrophobic compounds with low viscosity and high solubility. Depending on the processing conditions, the fuel can be used as produced for heavy engines, including marine and rail or upgraded to transportation fuels, such as diesel, gasoline or jet-fuels. The process may be significant in the creation of fossil fuels. Simple heating without water, anhydrous pyrol ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Biochar
Biochar is a form of charcoal, sometimes modified, that is intended for organic use, as in soil. It is the lightweight black remnants remaining after the pyrolysis of biomass, consisting of carbon and ashes. Despite its name, biochar is sterile immediately after production and only gains biological life following assisted or incidental exposure to biota. Biochar is defined by the International Biochar Initiative as the "solid material obtained from the thermochemical conversion of biomass in an oxygen-limited environment". Biochar is mainly used in soils to increase soil aeration, reduce soil emissions of greenhouse gases, reduce nutrient leaching, reduce soil acidity, and potentially increase the water content of coarse soils. Biochar application may increase soil fertility and agricultural productivity. However, when applied excessively or made from feedstock unsuitable for the soil type, biochar soil amendments also have the potential for negative effects, including harm ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Synthetic Fuel
Synthetic fuel or synfuel is a liquid fuel, or sometimes Fuel gas, gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas. Common ways for refining synthetic fuels include the Fischer–Tropsch process, Fischer–Tropsch conversion, Gas to liquids, methanol to gasoline conversion, or direct coal liquefaction. Classification and principles There is a range of meanings for the terms 'synthetic fuel' or 'synfuel'. * The most traditional view restricts the input material (feedstock) to coal (commonly via syngas) and the output to liquid hydrocarbons. Some authors additionally allow natural gas as input. * Newer understandings (such as Energy Information Administration, EIA 2006) allow coal, natural gas, or biomass as feedstock. The output can be synthetic crude or synthetic liquid products. Industrial and municipal waste can also be a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Second-generation Biofuels
Second-generation biofuels, also known as advanced biofuels, are fuels that can be manufactured from various types of non-food biomass. Biomass in this context means plant materials and animal waste used especially as a source of fuel. First-generation biofuels are made from sugar-starch feedstocks (e.g., sugarcane and corn) and edible oil feedstocks (e.g., rapeseed and soybean oil), which are generally converted into bioethanol and biodiesel, respectively. Second-generation biofuels are made from different feedstocks and therefore may require different technology to extract useful energy from them. Second generation feedstocks include lignocellulosic biomass or woody crops, agricultural residues or waste, as well as dedicated non-food energy crops grown on marginal land unsuitable for food production. The term second-generation biofuels is used loosely to describe both the 'advanced' technology used to process feedstocks into biofuel, but also the use of non-food crops, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Pyrolysis
Pyrolysis is a process involving the Bond cleavage, separation of covalent bonds in organic matter by thermal decomposition within an Chemically inert, inert environment without oxygen. Etymology The word ''pyrolysis'' is coined from the Greek language, Greek-derived morpheme, elements ''pyro-'' (from Ancient Greek : - "fire, heat, fever") and ''lysis'' ( : - "separation, loosening"). Applications Pyrolysis is most commonly used in the treatment of organic compound, organic materials. It is one of the processes involved in the charring of wood or pyrolysis of biomass. In general, pyrolysis of organic substances produces volatile products and leaves Char (chemistry), char, a carbon-rich solid residue. Extreme pyrolysis, which leaves mostly carbon as the residue, is called carbonization. Pyrolysis is considered one of the steps in the processes of gasification or combustion. Laypeople often confuse pyrolysis gas with syngas. Pyrolysis gas has a high percentage of heavy tar ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Thermal Depolymerization
Thermal depolymerization (TDP) is the process of converting a polymer into a monomer or a mixture of monomers, by predominantly thermal means. It may be catalyzed or un-catalyzed and is distinct from other forms of depolymerization which may rely on the use of chemicals or biological action. This process is associated with an increase in entropy. For most polymers, thermal depolymerization is chaotic process, giving a mixture of volatile compounds. Materials may be depolymerized in this way during waste management, with the volatile components produced being burnt as a form of synthetic fuel in a waste-to-energy process. For other polymers, thermal depolymerization is an ordered process giving a single product, or limited range of products; these transformations are usually more valuable and form the basis of some plastic recycling technologies. Disordered depolymerization For most polymeric materials, thermal depolymerization proceeds in a disordered manner, with random chain ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Heat Of Combustion
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it. The ''calorific value'' is the total energy released as heat when a substance undergoes complete combustion with oxygen under standard conditions. The chemical reaction is typically a hydrocarbon or other organic molecule reacting with oxygen to form carbon dioxide and water and release heat. It may be expressed with the quantities: * energy/ mole of fuel * energy/mass of fuel * energy/volume of the fuel There are two kinds of enthalpy of combustion, called high(er) and low(er) heat(ing) value, depending on how much the products are allowed to cool and whether compounds like are allowed to condense. The high heat values are conventionally measured with a bomb calorimeter. Low heat values are calculated from high heat value test data. They may also be calculated as the difference be ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coal-oil
Coal oil is a shale oil obtained from the destructive distillation of cannel coal, mineral wax, or bituminous shale, once used widely for illumination. Chemically similar to the more refined, petroleum-derived kerosene, it consists mainly of several hydrocarbons of the alkane series, with 10 to 16 carbon atoms in each molecule, with a boiling point of , higher than gasoline or the petroleum ethers, and lower than the oils. Because kerosene was first derived from cannel coal, classified as terrestrial type of oil shale, it continued to be popularly referred to as "coal oil" even after production shifted to petroleum as a feedstock. Refined hydrocarbons of the alkane series with 10 to 16 carbon atoms are the same thing whether taken from coal or petroleum. History The term was in use by the late 18th century for oil produced as a by-product of the production of coal gas and coal tar. In the early 19th century, it was discovered that coal oil distilled from cannel coal could ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Coal-tar
Coal tar is a thick dark liquid which is a by-product of the production of coke and coal gas from coal. It is a type of creosote. It has both medical and industrial uses. Medicinally it is a topical medication applied to skin to treat psoriasis and seborrheic dermatitis (dandruff). It may be used in combination with ultraviolet light therapy. Industrially it is a railroad tie preservative and used in the surfacing of roads. Coal tar was listed as a known human carcinogen in the first Report on Carcinogens from the U.S. Federal Government, issued in 1980. Coal tar was discovered circa 1665 and used for medical purposes as early as the 1800s. Circa 1850, the discovery that it could be used as the main raw material for the synthesis of dyes engendered an entire industry. It is on the World Health Organization's List of Essential Medicines. Coal tar is available as a generic medication and over the counter. Side effects include skin irritation, sun sensitivity, allergic react ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
New Zealand Science Review
The New Zealand Association of Scientists is an independent association for scientists in New Zealand. It was founded in 1941 as the New Zealand Association of Scientific Workers, and renamed in 1954.Gregory, G., 2013. Not to be forgotten: New Zealand Association of Scientific Workers. New Zealand Science Review, 70(1), pp.10-19. It differs from the Royal Society of New Zealand in being an independent non-profit incorporated society and registered charity, rather than being constituted by an Act of Parliament. While not being entirely non-political, the Association focuses on policy, social and economic responsibility aspects of science. History The history of the Association is documented in a sequence of articles in the NZ Science Review (NZSR) written by Geoff Gregory.Gregory, G., 2013. The mechanism of prosperity: New Zealand Association of Scientists 1954–73. New Zealand Science Review, 70(4), pp.61-72.Gregory, G., 2014. Tackling issues and initiating public debate: ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Char (chemistry)
Char is the solid material that remains after light gases (e.g. coal gas) and tar have been driven out or released from a carbonaceous material during the initial stage of combustion, which is known as carbonization, charring, devolatilization or pyrolysis. Further stages of efficient combustion (with or without char deposits) are known as gasification reactions, ending quickly when the reversible gas phase of the water gas shift reaction is reached. See also * Biochar * Charcoal * Coke (fuel) * Petroleum coke Petroleum coke, abbreviated coke, pet coke or petcoke, is a final carbon-rich solid material that derives from oil refinery, oil refining, and is one type of the group of fuels referred to as Coke (fuel), cokes. Petcoke is the coke that, in parti ... * Shale oil extraction * Spent shale References Oil shale Coal {{hydrocarbon-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
