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Bentonite
Bentonite ( ) is an Absorption (chemistry), absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite. Bentonite usually forms from the weathering of volcanic ash in seawater, or by hydrothermal circulation through the porosity of volcanic ash beds, which converts (devitrification) the volcanic glass (obsidian, rhyolite, dacite) present in the ash into clay minerals. In the mineral alteration process, a large fraction (up to 40–50 wt.%) of amorphous silica is dissolution (chemistry), dissolved and leaching (agriculture), leached away, leaving the bentonite deposit in place. Bentonite beds are white or pale blue or green (traces of redox, reduced ) in fresh exposures, turning to a cream color and then yellow, red, or brown (traces of oxidation, oxidized ) as the exposure is weathered further. As a swel ...
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Smectite
A smectite (; ; ) is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secondary minerals such as quartz and calcite. Terminology In clay mineralogy, smectite is synonym of montmorillonite (also the name of a pure clay mineral phase) to indicate a class of swelling clays. The term smectite is commonly used in Europe and in the UK while the term montmorillonite is preferred in North America, but both terms are equivalent and can be used interchangeably. For industrial and commercial applications, the term bentonite is mostly used in place of smectite or montmorillonite. Mineralogical structure The 2:1 layer (TOT) structure consists of two Silicon dioxide, silica (SiO2) Tetrahedral molecular geometry, tetrahedral (T) layers which are electrostatically cross-linked via an Al2O3 (gibbsite), or Fe2O3, Octahedral mo ...
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Montmorillonite
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm; magnification of about 25,000 times, using an electron microscope, is required to resolve individual clay particles. Members of this group include saponite, nontronite, beidellite, and hectorite. Montmorillonite is a subclass of smectite, a 2:1 phyllosilicate mineral characterized as having greater than 50% octahedral charge; its cation exchange capacity is due to isomorphous substitution of Mg for Al in the central alumina plane. The substitution of lower valence cations in such instances leaves the nearby oxygen ...
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Clay
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, ). Most pure clay minerals are white or light-coloured, but natural clays show a variety of colours from impurities, such as a reddish or brownish colour from small amounts of iron oxide. Clays develop plasticity (physics), plasticity when wet but can be hardened through Pottery#Firing, firing. Clay is the longest-known ceramic material. Prehistoric humans discovered the useful properties of clay and used it for making pottery. Some of the earliest pottery shards have been radiocarbon dating, dated to around 14,000 BCE, and Clay tablet, clay tablets were the first known writing medium. Clay is used in many modern industrial processes, such as paper making, cement production, and chemical filtration, filtering. Between one-half and two-thirds of the world's population live or work in buildings made with clay, often baked into brick, as an essenti ...
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Benstonite
Benstonite is a mineral with formula Ba6Ca6Mg(CO3)13. Discovered in 1954, the mineral was described in 1961 and named after Orlando J. Benston (1901–1966). Description and occurrence Benstonite is translucent and white, pale yellow, or pale yellow-brown in color. The mineral occurs as cleavable masses; cleavage fragments are nearly perfectly rhombohedral in shape. Cleavage faces are up to across and slightly curved. On large specimens, the faces exhibit a mosaic structure similar to that in some specimens of dolomite and siderite. Benstonite fluoresces red or yellow under x-rays and longwave and shortwave ultraviolet. The mineral also exhibits strong red phosphorescence. Benstonite is known to occur in Canada, China, India, Italy, Namibia, Russia, Sweden, and the United States. It occurs in association with alstonite, barite, barytocalcite, calcite, daqingshanite, fluorite, huntite, monazite, phlogopite, pyrite, sphalerite, strontianite, and quartz. Synthesis ...
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Drilling Mud
In geotechnical engineering, drilling fluid, also known as drilling mud, is used to aid the drilling of boreholes into the earth. Used while drilling oil well, oil and natural gas wells and on exploration drilling rigs, drilling fluids are also used for much simpler boreholes, such as water wells. The two main categories of drilling fluids are water-based muds (WBs), which can be dispersed and non-dispersed, and non-aqueous muds, usually called oil-based muds (OBs). Along with their formatives, these are used along with appropriate polymer and clay additives for drilling various oil and gas formations. Gaseous drilling fluids, typically utilizing air or natural gas, sometimes with the addition of foaming agents, can be used when downhole conditions permit. The main functions of liquid drilling fluids are to exert hydrostatic pressure to prevent formation fluids from entering into the well bore, and carrying out drill cuttings as well as suspending the drill cuttings while d ...
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Volcanic Ash
Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, produced during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer to all explosive eruption products (correctly referred to as '' tephra''), including particles larger than 2 mm. Volcanic ash is formed during explosive volcanic eruptions when dissolved gases in magma expand and escape violently into the atmosphere. The force of the gases shatters the magma and propels it into the atmosphere where it solidifies into fragments of volcanic rock and glass. Ash is also produced when magma comes into contact with water during phreatomagmatic eruptions, causing the water to explosively flash to steam leading to shattering of magma. Once in the air, ash is transported by wind up to thousands of kilometres away. Due to its wide dispersal, ash can have a number of impacts on society, including animal a ...
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Pottery
Pottery is the process and the products of forming vessels and other objects with clay and other raw materials, which are fired at high temperatures to give them a hard and durable form. The place where such wares are made by a ''potter'' is also called a ''pottery'' (plural ''potteries''). The definition of ''pottery'', used by the ASTM International, is "all fired ceramic wares that contain clay when formed, except technical, structural, and refractory products". End applications include tableware, ceramic art, decorative ware, toilet, sanitary ware, and in technology and industry such as Insulator (electricity), electrical insulators and laboratory ware. In art history and archaeology, especially of ancient and prehistoric periods, pottery often means only vessels, and sculpture, sculpted figurines of the same material are called terracottas. Pottery is one of the Timeline of historic inventions, oldest human inventions, originating before the Neolithic, Neolithic period, w ...
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Absorption (chemistry)
Absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter the liquid or solid bulk phase of a material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface (as in the case for adsorption). A more common definition is that "Absorption is a chemical or physical phenomenon in which the molecules, atoms and ions of the substance getting absorbed enter into the bulk phase (gas, liquid or solid) of the material in which it is taken up." A more general term is '' sorption'', which covers absorption, adsorption, and ion exchange. Absorption is a condition in which something takes in another substance. In many processes important in technology, the chemical absorption is used in place of the physical process, e.g., absorption of carbon dioxide by sodium hydroxide – such acid-base processes do not follow the Nernst partition law (see: solubility). For some examp ...
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Dissolution (chemistry)
Solvations describes the interaction of a solvent with dissolved molecules. Both ionized and uncharged molecules interact strongly with a solvent, and the strength and nature of this interaction influence many properties of the solute, including solubility, reactivity, and color, as well as influencing the properties of the solvent such as its viscosity and density. If the attractive forces between the solvent and solute particles are greater than the attractive forces holding the solute particles together, the solvent particles pull the solute particles apart and surround them. The surrounded solute particles then move away from the solid solute and out into the solution. Ions are surrounded by a concentric shell of solvent. Solvation is the process of reorganizing solvent and solute molecules into solvation complexes and involves bond formation, hydrogen bonding, and van der Waals forces. Solvation of a solute by water is called hydration. Solubility of solid compounds de ...
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Kaolinite
Kaolinite ( ; also called kaolin) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahedral sheet of alumina (). Kaolinite is a soft, earthy, usually white, mineral (dioctahedral phyllosilicate clay), produced by the chemical weathering of aluminium silicate minerals like feldspar. It has a low shrink–swell capacity and a low cation-exchange capacity (1–15 meq/100 g). Rocks that are rich in kaolinite, and halloysite, are known as kaolin () or china clay. In many parts of the world kaolin is colored pink-orange-red by iron oxide, giving it a distinct rust hue. Lower concentrations of iron oxide yield the white, yellow, or light orange colors of kaolin. Alternating lighter and darker layers are sometimes found, as at Providence Canyon State Park in Georgia, United States. Kaolin is an important raw material in many industries and app ...
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Binder (material)
A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion. More narrowly, binders are liquid or dough-like substances that harden by a chemical or physical process and bind fibres, filler powder and other particles added into it. Examples include glue, adhesive and thickening. Examples of mechanical binders are bond stones in masonry and tie beams in timber framing. Classification Binders are loosely classified as organic ( bitums, animal and plant glues, polymers) and inorganic ( lime, cement, gypsum, liquid glass, etc.). These can be either metallic or ceramic as well as polymeric depending on the nature of the main material. For example, in the compound WC-Co (Tungsten Carbide used in cutting tools) Co constitutes the binding agent for the WC particles. Based on their chemical resistance, binders are classified by the field of use: non-hydrau ...
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Adsorbent
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a fluid (the ''absorbate'') is dissolved by or permeates a liquid or solid (the ''absorbent''). While adsorption does often precede absorption, which involves the transfer of the absorbate into the volume of the absorbent material, alternatively, adsorption is distinctly a surface phenomenon, wherein the adsorbate does not penetrate through the material surface and into the bulk of the adsorbent. The term '' sorption'' encompasses both adsorption and absorption, and ''desorption'' is the reverse of sorption. Like surface tension, adsorption is a consequence of surface energy. In a bulk material, all the bonding requirements (be they ionic, covalent or metallic) of the constituent atoms of the material are fulfilled by other atoms in ...
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