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Aplowite
Aplowite is a very rare mineral with the formula CoSO4•4H2O, a naturally occurring cobalt(II) sulfate Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively. The heptahydrate is a red solid that is soluble in water and ... tetrahydrate. It is the lower hydrate when compared to bieberite (heptahydrate) and moorhouseite (hexahydrate), and a higher hydrate when compared to cobaltkieserite (monohydrate). It occurs together with moorhouseite within efflorescences. References Sulfate minerals Cobalt minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Sulfate Minerals
The sulfate minerals are a class of minerals that include the sulfate ion () within their structure. The sulfate minerals occur commonly in primary evaporite depositional environments, as gangue minerals in hydrothermal veins and as secondary minerals in the oxidizing zone of sulfide mineral deposits. The chromate and manganate minerals have a similar structure and are often included with the sulfates in mineral classification systems.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, pp. 347–354 . Sulfate minerals include: *Anhydrous sulfates **Barite BaSO4 **Celestite SrSO4 ** Anglesite PbSO4 ** Anhydrite CaSO4 ** Hanksite Na22K(SO4)9(CO3)2Cl *Hydroxide and hydrous sulfates **Gypsum CaSO4·2H2O **Chalcanthite CuSO4·5H2O ** Kieserite MgSO4·H2O ** Starkeyite MgSO4·4H2O ** Hexahydrite MgSO4·6H2O ** Epsomite MgSO4·7H2O ** Meridianiite MgSO4·11H2O **Melanterite FeSO4·7H2O ** Antlerite Cu3SO4(OH)4 **Brochant ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobaltite
Cobaltite is a sulfide mineral composed of cobalt, arsenic, and sulfur, Co As S. Its impurities may contain up to 10% iron and variable amounts of nickel.Klein, Cornelus and Cornrlius Hurlbut, 1996, ''Manual of Mineralogy'', 20th ed., Wiley, p.288, Structurally, it resembles pyrite (FeS2) with one of the sulfur atoms replaced by an arsenic atom. Although rare, it is mined as a significant source of the strategically important metal cobalt. Secondary weathering incrustations of erythrite, hydrated cobalt arsenate, are common. A variety containing much iron replacing cobalt, and known as ferrocobaltite (german: link=no, Stahlkobalt), was found at Siegen in Westphalia. The name is from the German, ''Kobold'', "underground spirit" in allusion to the "refusal" of cobaltiferous ores to smelt as they are expected to, including the foul-smelling, poisonous fumes the ores gave off. Cobaltite, which contains both arsenic and sulfur, was one of these ores. It occurs in high-temperature ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt(II) Sulfate
Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydrates CoSO4.6H2O or CoSO4.7H2O, respectively. The heptahydrate is a red solid that is soluble in water and methanol. Since cobalt(II) has an odd number of electrons, its salts are paramagnetic. Preparation, and structure It forms by the reaction of metallic cobalt, its oxide, hydroxide, or carbonate with aqueous sulfuric acid: :Co + H2SO4 + 7 H2O → CoSO4(H2O)7 + H2 :CoO + H2SO4 + 6 H2O → CoSO4(H2O)7 The heptahydrate is only stable at humidity >70% at room temperature, otherwise it converts to the hexahydrate. The hexahydrate converts to the monohydrate and the anhydrous forms at 100 and 250 °C, respectively. :CoSO4(H2O)7 → CoSO4(H2O)6 + H2O :CoSO4(H2O)6 → CoSO4(H2O) + 5H2O :CoSO4(H2O) → CoSO4 + H2O The hexahydrate is a metal aquo complex consisting of octahedral o(H2O)6sup>2+ ions associated with sulfate ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Bieberite
Bieberite (CoSO4 · 7H2O) is a pinkish red colored sulfate mineral high in cobalt content. The name is derived from the type locality at the copper deposit in Bieber, Hesse, Germany. It has been described and reported as far back as the 1700s.Sage (1791) ''Le Journal de physique et le radium, Paris'', 39: 53 (as Cobalt Vitriol).Klaproth, M.H. (1797) "''Untersuchung des natürlichen Kobaltvitriols von Herrengrund, Beiträge zur chemischen Kenntniss der Mineralkörper"'', Zweiter Band, Rottmann Berlin, pp. 320.Kopp (1808) ''Allgemeines Journal der Chemie, Berlin 1798-1803 (Scherer’s Journal)'', 6: 157 (as Kobaltvitriol).Beudant, F.S. (1832) ''Trailé élémentaire de Minéralogie, second edition, 2 volumes'', 2: 481 (as Red Vitrol. Sulphate of Cobalt. Rhodhalose).Haidinger (1845) 489 (as Bieberit).Winkelblech (1845) ''Ann. Chem.'', 13: 265.Marignac (1855) ''Mém. soc. phys. nat. Genève'', 14: 245 (artificial material).Goldschmidt, V. (1913) ''Atlas der Krystallformen. 9 volumes, at ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Moorhouseite
Moorhouseite is a rare mineral with the formula CoSO4•6H2O, a naturally occurring cobalt(II) sulfate hexahydrate. It is the lower-hydrate-equivalent of bieberite (heptahydrate) and aplowite Aplowite is a very rare mineral with the formula CoSO4•4H2O, a naturally occurring cobalt(II) sulfate Cobalt(II) sulfate is any of the inorganic compounds with the formula CoSO4(H2O)x. Usually cobalt sulfate refers to the hexa- or heptahydra ... (hexahydrate). It is also hydrated equivalent of cobaltkieserite. It occurs together with moorhouseite within efflorescences found in the Magnet Cove Barium Corporation mine in Walton, Nova Scotia, Canada. Notes on chemistry Relatively high amounts of nickel and manganese were reported, with trace amounts of copper and iron. Crystal structure Analysis of synthetic analogue of moorhouseite revealed, that its structure may be described as containing:Elerman, Y., 1988. Refinement of the crystal structure of CoSO4.6H2O. Acta Crystallographica C44, ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Cobalt Minerals
Cobalt is a chemical element with the symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. The free element, produced by reductive smelting, is a hard, lustrous, silver-gray metal. Cobalt-based blue pigments (cobalt blue) have been used since ancient times for jewelry and paints, and to impart a distinctive blue tint to glass, but the color was for a long time thought to be due to the known metal bismuth. Miners had long used the name ''kobold ore'' (German for ''goblin ore'') for some of the blue-pigment-producing minerals; they were so named because they were poor in known metals, and gave poisonous arsenic-containing fumes when smelted. In 1735, such ores were found to be reducible to a new metal (the first discovered since ancient times), and this was ultimately named for the ''kobold''. Today, some cobalt is produced specifically from one of a ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Monoclinic Minerals
In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic system. They form a parallelogram prism. Hence two pairs of vectors are perpendicular (meet at right angles), while the third pair makes an angle other than 90°. Bravais lattices Two monoclinic Bravais lattices exist: the primitive monoclinic and the base-centered monoclinic. For the base-centered monoclinic lattice, the primitive cell has the shape of an oblique rhombic prism;See , row mC, column Primitive, where the cell parameters are given as a1 = a2, α = β it can be constructed because the two-dimensional centered rectangular base layer can also be described with primitive rhombic axes. Note that the length a of the primitive cell below equals \frac \sqrt of the conventional cell above. Crystal classes The table below organ ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
