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Alizarin
Alizarin (also known as 1,2-dihydroxyanthraquinone, Mordant Red 11, C.I. 58000, and Turkey Red) is an organic compound with formula that has been used throughout history as a prominent red dye, principally for dyeing textile fabrics. Historically it was derived from the roots of plants of the madder genus.The primary madder species from which alizarin historically has been obtained is ''Rubia tinctorum''. See also In 1869, it became the first natural dye to be produced synthetically. Alizarin is the main ingredient for the manufacture of the madder lake pigments known to painters as rose madder and alizarin crimson. Alizarin in the most common usage of the term has a deep red color, but the term is also part of the name for several related non-red dyes, such as Alizarine Cyanine Green and Alizarine Brilliant Blue. A notable use of alizarin in modern times is as a staining agent in biological research because it stains free calcium and certain calcium compounds a red or li ...
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Alizarin01
Alizarin (also known as 1,2-dihydroxyanthraquinone, Mordant Red 11, C.I. 58000, and Turkey Red) is an organic compound with formula that has been used throughout history as a prominent red dye, principally for dyeing textile fabrics. Historically it was derived from the roots of plants of the madder genus.The primary madder species from which alizarin historically has been obtained is ''Rubia tinctorum''. See also In 1869, it became the first natural dye to be produced synthetically. Alizarin is the main ingredient for the manufacture of the madder lake pigments known to painters as rose madder and alizarin crimson. Alizarin in the most common usage of the term has a deep red color, but the term is also part of the name for several related non-red dyes, such as Alizarine Cyanine Green and Alizarine Brilliant Blue. A notable use of alizarin in modern times is as a staining agent in biological research because it stains free calcium and certain calcium compounds a red or lig ...
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Alizarin Crimson (color)
Alizarin crimson is a shade of red that is biased slightly more towards purple than towards orange on the color wheel and has a blue undertone. It is named after the organic dye alizarin, found in the madder plant, and the related synthetic lake pigment alizarin crimson (PR83 in the Color Index). William Henry Perkin had co-discovered a way to synthesize the pigment alizarin, which became known as the color alizarin crimson. Its consistency and lightfastness quickly made it a favourite red pigment for artists. Alizarin crimson can create a wide range of rich, permanent purples and browns. The dye was prominently used for dyeing clothes and traces were found in Ancient Egypt, Persia and the ruins of Pompeii. By the seventh century BC, the dye had been made into a lake pigment and was used across Europe, the Middle East and Asia. By this time the use of madder dye and pigment were widespread, but they remained costly and time-consuming to produce. Alizarin crimson was a po ...
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Rose Madder
Rose madder (also known as madder) is a red paint made from the pigment madder lake, a traditional lake pigment extracted from the common madder plant ''Rubia tinctorum''. Madder lake contains two organic red dyes: alizarin and purpurin. As a paint, it has been described as a fugitive, transparent, nonstaining, mid valued, moderately dull violet red pigment in tints and medium solutions, darkening to an impermanent, dull magenta red in masstone. History Madder has been cultivated as a dyestuff since antiquity in Central Asia, South Asia, and Egypt, where it was grown as early as 1500 BC. Cloth dyed with madder root dye was found in the tomb of the Pharaoh Tutankhamun and on an Egyptian tomb painting from the Graeco-Roman period, diluted with gypsum to produce a pink color. It was also found in ancient Greece (in Corinth), and in Italy in the Baths of Titus and the ruins of Pompeii. It is referred to in the Talmud as well as mentioned in writings by Dioscoride ...
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Lake Pigment
A lake pigment is a pigment made by precipitating a dye with an inert binder, or mordant, usually a metallic salt. Unlike vermilion, ultramarine, and other pigments made from ground minerals, lake pigments are organic.K. Hunger. W. Herbst "Pigments, Organic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim, 2012. Manufacturers and suppliers to artists and industry frequently omit the ''lake'' designation in the name. Many lake pigments are fugitive because the dyes involved are not lightfast. Red lakes were particularly important in Renaissance and Baroque paintings; they were often used as translucent glazes to portray the colors of rich fabrics and draperies.David Bomford and Ashok Roy, ''A Closer Look - Colour'', National Gallery Company, p. 41. Etymology The term "lake" is derived from the term lac, the secretions of the Indian wood insect '' Kerria lacca'' (formerly ''Laccifer lacca'' or ''Coccus lacca''). It has the same root as the word ''lac ...
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Natural Dye
Natural dyes are dyes or colorants derived from plants, invertebrates, or minerals. The majority of natural dyes are vegetable dyes from plant sources—roots, berries, bark, leaves, and wood—and other biological sources such as fungi. Archaeologists have found evidence of textile dyeing dating back to the Neolithic period. In China, dyeing with plants, barks and insects has been traced back more than 5,000 years.Goodwin (1982), p. 11. The essential process of dyeing changed little over time. Typically, the dye material is put in a pot of water and heated to extract the dye compounds into solution with the water. Then the textiles to be dyed are added to the pot, and held at heat until the desired color is achieved. Textile fibre may be dyed before spinning or weaving ("dyed in the wool"), after spinning ("yarn-dyed") or after weaving ("piece-dyed"). Many natural dyes require the use of substances called mordants to bind the dye to the textile fibres. Mordants (from the Latin ...
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George Field (chemist)
George Field (1777?–1854), was an English chemist. He was born in or about 1777 at Berkhamsted, Hertfordshire, of a family long settled in that town, and was educated at St. Peter's school there. When about eighteen years of age he came to London to seek a profession. He thought he saw an opening in the careful application of chemistry to pigments and dyes. War on the continent, by stopping the supply of madder from Holland, threatened to impede his progress. This obstacle, however, led him to consider the nature of its cultivation, and with a well-devised project he waited on Sir Joseph Banks for his advice, and, as he hoped, his co-operation. Sir Joseph, after unsuccessfully attempting to cultivate madder in Essex, had made up his mind that it could not be done in England. Horticulture and inventions Field then commenced the cultivation in his own garden, and from roots of his own growth produced beautiful specimens of colouring matter. A contrivance, both mechanical and chemi ...
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Cochineal
The cochineal ( , ; ''Dactylopius coccus'') is a scale insect in the suborder Sternorrhyncha, from which the natural dye carmine is derived. A primarily sessile parasite native to tropical and subtropical South America through North America (Mexico and the Southwest United States), this insect lives on cacti in the genus ''Opuntia'', feeding on plant moisture and nutrients. The insects are found on the pads of prickly pear cacti, collected by brushing them off the plants, and dried. The insect produces carminic acid that deters predation by other insects. Carminic acid, typically 17–24% of dried insects' weight, can be extracted from the body and eggs, then mixed with aluminium or calcium salts to make carmine dye, also known as cochineal. Today, carmine is primarily used as a colorant in food and in lipstick (E120 or Natural Red 4). Carmine dye was used in the Americas for coloring fabrics and became an important export good in the 16th century during the colon ...
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Red Coat (British Army)
Red coat, also referred to as redcoat or scarlet tunic, was a military garment which was widely (though not exclusively) used by the infantry units of the British military, including the British Army and Royal Marines, from the 16th to 19th centuries. The garment was also widely used by the British Colonial Auxiliary Forces and the British Indian Army during the 18th and 19th centuries. Though by the 20th centuries the red coat was abandoned for practical duties in favour of khaki by all British and Commonwealth military units, it continues to be used for ceremonial full dress and mess dress uniforms. The usage of red coats by English soldiers dates back to the Tudor period, when the Yeomen of the Guard and the Yeomen Warders were both equipped in the royal colours of the House of Tudor, red and gold. During the Tudor conquest of Ireland and the Wars of the Three Kingdoms, units of English soldiers were equipped in red coats, most notably the New Model Army, which fought o ...
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Mordant
A mordant or dye fixative is a substance used to set (i.e. bind) dyes on fabrics by forming a coordination complex with the dye, which then attaches to the fabric (or tissue). It may be used for dyeing fabrics or for intensifying stains in cell or tissue preparations. Although mordants are still used, especially by small batch dyers, it has been largely displaced in industry by directs.} The term mordant comes from the Latin ''mordere'', "to bite". In the past, it was thought that a mordant helped the dye bite onto the fiber so that it would hold fast during washing. A mordant is often a polyvalent metal ion, and one example is chromium (III). The resulting coordination complex of dye and ion is colloidal and can be either acidic or alkaline. Common dye mordants Mordants include tannic acid, oxalic acid, alum, chrome alum, sodium chloride, and certain salts of aluminium, chromium, copper, iron, iodine, potassium, sodium, tungsten, and tin. Iodine is often referred to as ...
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Anthraquinone
Anthraquinone, also called anthracenedione or dioxoanthracene, is an aromatic organic compound with formula . Isomers include various quinone derivatives. The term anthraquinone however refers to the isomer, 9,10-anthraquinone (IUPAC: 9,10-dioxoanthracene) wherein the keto groups are located on the central ring. It is a building block of many dyes and is used in bleaching pulp for papermaking. It is a yellow, highly crystalline solid, poorly soluble in water but soluble in hot organic solvents. It is almost completely insoluble in ethanol near room temperature but 2.25 g will dissolve in 100 g of boiling ethanol. It is found in nature as the rare mineral hoelite. Synthesis There are several current industrial methods to produce 9,10-anthraquinone: # The oxidation of anthracene. Chromium(VI) is the typical oxidant. # The Friedel-Crafts reaction of benzene and phthalic anhydride in presence of AlCl3. o-Benzoylbenzoic acid is an intermediate. This reaction is useful for produci ...
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Alum
An alum () is a type of chemical compound, usually a hydrated double sulfate salt of aluminium with the general formula , where is a monovalent cation such as potassium or ammonium. By itself, "alum" often refers to potassium alum, with the formula . Other alums are named after the monovalent ion, such as sodium alum and ammonium alum. The name "alum" is also used, more generally, for salts with the same formula and structure, except that aluminium is replaced by another trivalent metal ion like chromium, and/or sulfur is replaced by another chalcogen like selenium. The most common of these analogs is chrome alum . In most industries, the name "alum" (or "papermaker's alum") is used to refer to aluminium sulfate, , which is used for most industrial flocculation (the variable is an integer whose size depends on the amount of water absorbed into the alum). In medicine, "alum" may also refer to aluminium hydroxide gel used as a vaccine adjuvant. History Alum found at a ...
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Charlemagne
Charlemagne ( , ) or Charles the Great ( la, Carolus Magnus; german: Karl der Große; 2 April 747 – 28 January 814), a member of the Carolingian dynasty, was King of the Franks from 768, King of the Lombards from 774, and the first Emperor of the Romans from 800. Charlemagne succeeded in uniting the majority of western and central Europe and was the first recognized emperor to rule from western Europe after the fall of the Western Roman Empire around three centuries earlier. The expanded Frankish state that Charlemagne founded was the Carolingian Empire. He was canonized by Antipope Paschal III—an act later treated as invalid—and he is now regarded by some as beatified (which is a step on the path to sainthood) in the Catholic Church. Charlemagne was the eldest son of Pepin the Short and Bertrada of Laon. He was born before their canonical marriage. He became king of the Franks in 768 following his father's death, and was initially co-ruler with his brother ...
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