Topic summary

Methane

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Names Preferred IUPAC name
Methane
Systematic IUPAC name
Carbane (never recommended)
Other names
  • Carbon tetrahydride
  • Carburetted hydrogen
  • Hydrogen carbide
  • Marsh gas
  • Methyl hydride
  • Natural gas
Identifiers
3D model (JSmol)
1718732 ChEBIChEMBLChemSpiderECHA InfoCard100.000.739EC Number
  • 200-812-7
59 KEGGMeSHMethaneRTECS number
  • PA1490000
UNIIUN number1971
  • InChI=1S/CH4/h1H4
    Key: VNWKTOKETHGBQD-UHFFFAOYSA-N
Properties CH4Molar mass16.043 g·mol Appearance Colorless gas OdorOdorless Density
  • 0.657 kg/m (gas, 25 °C, 1 atm)
  • 0.717 kg/m (gas, 0 °C, 1 atm)
  • 422.8 g/L (liquid, −162 °C)
Melting point−182.456 °C (−296.421 °F; 90.694 K) Boiling point−161.49 °C (−258.68 °F; 111.66 K) Critical point (T, P) 190.56 K (−82.59 °C; −116.66 °F), 4.5992 MPa (45.391 atm) 22.7 mg/L SolubilitySoluble in ethanol, diethyl ether, benzene, toluene, methanol, acetone and insoluble in waterlog P1.09 14 nmol/(Pa·kg) Conjugate acidMethaniumConjugate baseMethyl anion−17.4×10 cm/mol Structure TdTetrahedral at carbon atom 0D Thermochemistry 35.7 J/(K·mol) 186.3 J/(K·mol) −74.6 kJ/mol −50.5 kJ/mol −891 kJ/mol Hazards GHS labelling: DangerH220P210NFPA 704 (fire diamond) Flash point−188 °C (−306.4 °F; 85.1 K) 537 °C (999 °F; 810 K) Explosive limits4.4–17% Related compounds
Related alkanes
Related compounds
Supplementary data page Methane (data page)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Methane (US: , UK: ) is a chemical compound that has the chemical formulaCH4 (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The abundance of methane on Earth makes it an economically attractive fuel, although capturing and storing it is difficult because it is a gas at standard temperature and pressure. In the Earth's atmosphere methane is transparent to visible light but absorbs infrared radiation, acting as a greenhouse gas. Methane is an organichydrocarbon, and among the simplest of organic compounds.

Naturally occurring methane is found both below ground and under the seafloor and is formed by both geological and biological processes. The largest reservoir of methane is under the seafloor in the form of methane clathrates. When methane reaches the surface and the atmosphere, it is known as atmospheric methane.

Methane has also been detected on other planets, including Mars, which has implications for astrobiology research.