sulfide minerals
The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...
with the general formula , where
*A represents a metal such as copper, lead, silver, iron, and rarely
mercury
Mercury commonly refers to:
* Mercury (planet), the nearest planet to the Sun
* Mercury (element), a metallic chemical element with the symbol Hg
* Mercury (mythology), a Roman god
Mercury or The Mercury may also refer to:
Companies
* Merc ...
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
germanium
Germanium is a chemical element with the symbol Ge and atomic number 32. It is lustrous, hard-brittle, grayish-white and similar in appearance to silicon. It is a metalloid in the carbon group that is chemically similar to its group neighbors s ...
vanadium
Vanadium is a chemical element with the symbol V and atomic number 23. It is a hard, silvery-grey, malleable transition metal. The elemental metal is rarely found in nature, but once isolated artificially, the formation of an oxide layer ( pas ...
*X is
sulfur
Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
or rarely selenium and/or tellurium.
The Strunz classification includes the sulfosalts in a ''sulfides and sulfosalts'' superclass. A group which have similar appearing formulas are the
sulfarsenide The sulfarsenide minerals are a subgroup of the sulfide minerals which include arsenic replacing sulfur as an anion in the formula.Klein, Cornelis and Cornelius S. Hurlbut, 1985, ''Manual of Mineralogy,'' 20th ed., John Wiley and Sons, New York, p. ...
s (for example cobaltite (Co,Fe)AsS). In sulfarsenides the arsenic substitutes for
sulfide
Sulfide (British English also sulphide) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to chemical compounds lar ...
anions whereas in the sulfosalts the arsenic substitutes for a metal
cation
An ion () is an atom or molecule with a net electrical charge.
The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
.Klein, Cornelis and Cornelius S. Hurlbut (1985). ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York .
About 200 sulfosalt minerals are known. Examples include:
File:Proustite (long prismatic crystal) - Chanarcillo, Copiapo Province, Atacama Region, Chile.jpg, As illustrated by this specimen of proustite, sulfosalt minerals are often deeply colored.
* type
** Pyrargyrite
** Proustite
**
Tetrahedrite
Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, ...
Geocronite
Geocronite is a mineral, a mixed sulfosalt containing lead, antimony, and arsenic with a formula of Pb14(Sb, As)6S23. Geocronite is the antimony-rich endmember of a solid solution series. The arsenic-rich endmember is named jordanite. It occurs a ...
**
Gratonite
Gratonite is a lead-arsenic sulfosalt mineral, with the chemical composition Pb9As4S15. Gratonite was discovered in 1939 at the Excelsior Mine, Cerro de Pasco, Peru
, image_flag = Flag of Peru.svg
, image_coat = E ...
Seligmannite
Seligmanite is a rare mineral, with the chemical formula PbCuAsS3. Originally described from the Lengenbach Quarry, Valais, Valais Canton, Switzerland; it has also been found in the Raura district, Lima Region, Peru; at Tsumeb, Oshikoto Region, Na ...
Chalcostibite
Chalcostibite is a copper antimony sulfide mineral.
Příbramite is related, having selenium instead of sulfur. Emplectite contains bismuth instead of antimony.
Occurrences
* Argentina
** Salta Province
*** Los Andes department
**** San Ant ...
Andorite
Andorite is a sulfosalt minerals, sulfosalt mineral with the chemical formula PbAgSb3S6.
It was first described in 1892 for an occurrence in the Baia Sprie mine, Baia Sprie, in what is now Maramureș County, Romania, and named for Hungarian amate ...
Berthierite
Berthierite is a mineral, a sulfide of iron and antimony with formula FeSb2S4. It is steel grey in colour with a metallic lustre which can be covered by an iridescent tarnish. Because of its appearance it is often mistaken for stibnite.
It was ...
mindat.org
Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogy, mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collecting, mi ...
, 10 ed, pending publication).
*Abbreviations:
**"*" - discredited (IMA/CNMNC status).
**"?" - questionable/doubtful (IMA/CNMNC status).
**"REE" - Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu)
**"PGE" - Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt)
**03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V,6/sup> Vanadates), 09 Silicates:
***Neso: insular (from Greek νῆσος ''nēsos'', island)
***Soro: grouping (from Greek σωρός ''sōros'', heap, mound (especially of corn))
***Cyclo: ring (from Greek κύκλος ''kyklos'', wheel, ring, round)
***Ino: chain (from Greek ἴς enitive: ἰνός ''inos'' fibre)
***Phyllo: sheet (from Greek φύλλον ''phyllon'', leaf)
***Tekto: three-dimensional framework (from Greek stem τεκτ- ''tekt-'' in words having to do with carpentry)
*Nickel–Strunz code scheme: NN.XY.##x
**NN: Nickel–Strunz mineral class number
**X: Nickel–Strunz mineral division letter
**Y: Nickel–Strunz mineral family letter
**##x: Nickel–Strunz mineral/group number, x add-on letter
Aktashite
Aktashite is a rare arsenic sulfosalt mineral with formula Cu6Hg3As4S12. It is a copper Mercury (element), mercury-bearing sulfosalt and is the only sulfosalt mineral with essential Cu and Hg yet known. It is of hydrothermal origin. It was publish ...
Routhierite
Routhierite is a rare thallium sulfosalt mineral with formula .
It was first described in 1974 for an occurrence in the Jas Roux deposit in the French Alps. It was named after French geologist Pierre Routhier (1916–2008).Erniggliite; 50
Seligmannite
Seligmanite is a rare mineral, with the chemical formula PbCuAsS3. Originally described from the Lengenbach Quarry, Valais, Valais Canton, Switzerland; it has also been found in the Raura district, Lima Region, Peru; at Tsumeb, Oshikoto Region, Na ...
Freibergite
Freibergite is a complex sulfosalt mineral of silver, copper, iron, antimony and arsenic with formula . It has cubic crystals and is formed in hydrothermal deposits. It forms one solid solution series with tetrahedrite and another with argentoten ...
Tetrahedrite
Tetrahedrite is a copper antimony sulfosalt mineral with formula: . It is the antimony endmember of the continuous solid solution series with arsenic-bearing tennantite. Pure endmembers of the series are seldom if ever seen in nature. Of the two, ...
Polybasite
Polybasite is a sulfosalt mineral of silver, copper, antimony and arsenic. Its chemical formula is .
It forms black monoclinic crystals (thin, tabular, with six corners) which can show dark red internal reflections. It has a Mohs hardness of 2.5 ...
Aleksite
Aleksite ( IMA symbol: Alk) is a rare lead bismuth tellurium sulfosalt mineral
Sulfosalt minerals are sulfide minerals with the general formula , where
*A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanad ...
Chalcostibite
Chalcostibite is a copper antimony sulfide mineral.
Příbramite is related, having selenium instead of sulfur. Emplectite contains bismuth instead of antimony.
Occurrences
* Argentina
** Salta Province
*** Los Andes department
**** San Ant ...
; 10
Miargyrite
Miargyrite is a mineral, a sulfide of silver and antimony with the formula Ag Sb S2. It is a dimorph of cuboargyrite. Originally discovered in the Freiberg district of Germany in 1824, it has subsequently been found in many places where silver i ...
, 15
Livingstonite
Livingstonite is a mercury antimony sulfosalt mineral. It occurs in low-temperature hydrothermal veins associated with cinnabar, stibnite, sulfur and gypsum.
It was first described in 1874 for an occurrence in Huitzuco de los Figueroa, Guerrer ...
; 20
Berthierite
Berthierite is a mineral, a sulfide of iron and antimony with formula FeSb2S4. It is steel grey in colour with a metallic lustre which can be covered by an iridescent tarnish. Because of its appearance it is often mistaken for stibnite.
It was ...
Salzburgite
Salzburgite has a general empirical formula of Pb2Cu2Bi7S12 and an orthorhombic crystal structure.Ralph, Joylon, and Ida ChauSalzburgite Joylon Ralph, 1993-2010. Web. 14 September 2010. This mineral is very similar to paarite in that they both ...
, 05b
Meneghinite
Meneghinite is a sulfosalt mineral with the chemical formula CuPb13 Sb7S24.
In the orthorhombic crystal system, meneghinite has a Mohs hardness of , one perfect cleavage and a conchoidal fracture. It is a blackish lead-grey in colour and gives a ...
Kobellite
Kobellite is a gray, fibrous, metallic mineral with the chemical formula . It is also a sulfide mineral consisting of antimony, bismuth, and lead. It is a member of the izoklakeite – berryite series with silver and iron substituting in the coppe ...
Berryite
Berryite is a mineral with the formula . It occurs as gray to blue-gray monoclinic prisms. It is opaque and has a metallic Lustre (mineralogy), luster. It has a Mohs hardness of 3.5 and a specific gravity of 6.7.
It was first identified in 1965 u ...
Guettardite
Guettardite is a rare arsenic-antimony lead sulfosalt mineral with the chemical formula . It forms gray black metallic prismatic to acicular crystals with monoclinic symmetry. It is a dimorph of the triclinic twinnite.
Discovery and occurrence
...
, 05b
Baumhauerite
Baumhauerite (Pb3As4S9) is a rare lead sulfosalt mineral. It crystallizes in the triclinic system, is gray-black to blue-gray and its lustre is metallic to dull. Baumhauerite has a hardness of 3.
Baumhauerite occurs as small crystals embedded in ...
Rayite
Rayite, a monoclinic mineral containing Lead-Silver-Thallium-Antimony, was found during microscopic and electron microprobe study of specimens from the complex, polymetallic sulphide-native metal sulpho-salt paragenesis of Rajpura- Dariba, Rajast ...
Plumosite
Plumosite is a questionable mineral. Most of the time, it can refer to any feather ore, i.e. any ore that forms fine capillaries within the surrounding rock.
Older specimens could be either boulangerite, jamesonite or zinkenite
Zinkenite is ...
Gabrielite
Gabrielite is a rare thallium sulfosalt mineral with a chemical formula of or .
It was first reported in 2002 for its occurrence in the Lengenbach quarry, Binntal, Valais, Switzerland, and named after Walter Gabriel (born 1943), a Swiss min ...
** 02.HE With alkalies, : 05 Gerstleyite
** 02.HF With SnS and PbS archetype structure units: 20 Vrbaite; 25a
Abramovite
Abramovite is a very rare mineral from the sulfides and sulfosalt categories. It has the chemical formula Pb2 Sn In Bi S7. It occurs as tiny elongated lamellar-shaped crystals, up 1 mm × 0.2 mm in size, and is characterized by its no ...
Franckeite
Franckeite, chemical formula Pb5Sn3Sb2S14, belongs to a family of complex sulfide minerals. Franckeite is a sulfosalt. It is closely related to cylindrite.
It was first described in 1893 for an occurrence in Chocaya, Potosí Department, Bolivia. ...
Marrite
Marrite (mar'-ite) is a mineral with the chemical formula PbAgAsS3. It is the arsenic equivalent of freieslebenite (PbAgSbS3), but also displays close polyhedral characteristics with sicherite and diaphorite.Berlepsch, P., Makovicky E., and Ar ...
Jordanite
Jordanite is a sulfosalt mineral with chemical formula in the monoclinic crystal system, named after the German scientist H. Jordan (1808–1887) who discovered it in 1864.
Lead-grey in colour (frequently displaying an iridescent tarnish), its ...
, 30a
Geocronite
Geocronite is a mineral, a mixed sulfosalt containing lead, antimony, and arsenic with a formula of Pb14(Sb, As)6S23. Geocronite is the antimony-rich endmember of a solid solution series. The arsenic-rich endmember is named jordanite. It occurs a ...
Bursaite
Bursaite is a sulfosalt of the lillianite family. It has the formula Pb5Bi4S11 and orthorhombic structure. Bursaite is named after Bursa Province, Turkey, where it was discovered.Rasit, T. (1954-55A study on the concentration tests and beneficiati ...
Xilingolite
Xilingolite is a lead sulfide mineral with formula Pb3Bi2S6. It has a hardness of 3, a metallic luster, and usually exhibits a lead-grey color. It is a dimorph of lillianite, exhibiting increased Pb-Bi order and decreased symmetry.
Its crystal s ...
Andorite
Andorite is a sulfosalt minerals, sulfosalt mineral with the chemical formula PbAgSb3S6.
It was first described in 1892 for an occurrence in the Baia Sprie mine, Baia Sprie, in what is now Maramureș County, Romania, and named for Hungarian amate ...
Gratonite
Gratonite is a lead-arsenic sulfosalt mineral, with the chemical composition Pb9As4S15. Gratonite was discovered in 1939 at the Excelsior Mine, Cerro de Pasco, Peru
, image_flag = Flag of Peru.svg
, image_coat = E ...
Briartite
Briartite is an opaque iron-grey metallic sulfide mineral, with traces of Ga and Sn, found as inclusions in other germanium- gallium-bearing sulfides.
It was discovered at the Prince Léopold Mine, Kipushi, Shaba, Congo (Léopoldville) in 1965 ...
Fangite
Fangite is a sulfosalt first discovered in the Mercur gold deposit located in Tooele County Utah. The specimen was found in a boulder in the southern Oquirrh Mountains. The only available specimens of fangite are located in the National Museum ...
Playfairite
Playfairite is a rare sulfosalt mineral with chemical formula Pb16Sb18S43 in the monoclinic crystal system, named after the Scottish scientist and mathematician John Playfair. It was discovered in 1966 by the Canadian mineralogist John Leslie Jam ...
Sarabauite
Sarabauite (sar-a-bau'-ite) is a red monoclinic sulfide mineral with the chemical formula: CaSb10O10S6.
Origin of name and type locality
Sarabauite was first described in 1977 and named for its type locality, the Sarabau Mine (Lucky Hill mi ...
Many sulfosalts can be prepared in the laboratory, including many that do not occur in nature.Sheldrick, William S.; Wachhold, Michael "Chalcogenidometalates of the heavier Group 14 and 15 elements" Coordination Chemistry Reviews 1998, vol. 176, 211-322.
References
* Mozgova N.N. (2000). ''Sulfosalt mineralogy today''. In: ''Modern Approaches to Ore and Environmental Mineralogy'', MSF Mini-Symposium Espoo Finland, June 11–17, 2000, https://web.archive.org/web/20050907172937/http://www.igem.ru/igem/mine/sulfosalts.htm Retrieved July 22, 2005.
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