The ZND detonation model is a one-dimensional model for the process of

detonation Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with ...

of an

explosive An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An ex ...

. It was proposed during

World War II World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...

independently by

Yakov Zeldovich Yakov Borisovich Zeldovich (, ; 8 March 1914 – 2 December 1987), also known as YaB, was a leading Soviet people, Soviet Physics, physicist of Belarusians, Belarusian origin, who is known for his prolific contributions in physical Physical c ...

John von Neumann John von Neumann ( ; ; December 28, 1903 – February 8, 1957) was a Hungarian and American mathematician, physicist, computer scientist and engineer. Von Neumann had perhaps the widest coverage of any mathematician of his time, in ...

, and Werner Döring, hence the name. This model admits finite-rate chemical reactions and thus the process of detonation consists of the following stages. First, an

infinitesimal In mathematics, an infinitesimal number is a non-zero quantity that is closer to 0 than any non-zero real number is. The word ''infinitesimal'' comes from a 17th-century Modern Latin coinage ''infinitesimus'', which originally referred to the " ...

ly thin shock wave compresses the explosive to a high pressure called the von Neumann spike. At the von Neumann spike point the explosive still remains unreacted. The spike marks the onset of the zone of exothermic chemical reaction, which finishes at the

Chapman–Jouguet condition The Chapman–Jouguet condition holds approximately in detonation waves in high explosives. It states that the detonation propagates at a velocity at which the reacting gases just reach sonic velocity (in the frame of the leading shock wave) as t ...

. After that, the detonation products expand backward. In the reference frame in which the shock is stationary, the flow following the shock is subsonic. Because of this, energy release behind the shock is able to be transported acoustically to the shock for its support. For a self-propagating detonation, the shock relaxes to a speed given by the Chapman–Jouguet condition, which induces the material at the end of the reaction zone to have a locally sonic speed in the reference frame in which the shock is stationary. In effect, all of the chemical energy is harnessed to propagate the shock wave forward. However, in the 1960s, experiments revealed that gas-phase detonations were most often characterized by unsteady, three-dimensional structures, which can only in an averaged sense be predicted by one-dimensional steady theories. Indeed, such waves are quenched as their structure is destroyed. The Wood–Kirkwood detonation theory can correct for some of these limitations.

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Further reading