Yttrium(III) Iodide
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Yttrium iodide is a binary
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
, a salt of
yttrium Yttrium is a chemical element; it has Symbol (chemistry), symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost a ...
and
hydroiodic acid Hydroiodic acid (or hydriodic acid) is a colorless liquid. It is an aqueous solution of hydrogen iodide with the chemical formula . It is a strong acid, in which hydrogen iodide is ionized completely in an aqueous solution. Concentrated aqueous ...
with the formula . The compound forms colorless crystals, soluble in water.


Synthesis

1. Heating yttrium and iodine in an inert atmosphere: : 2. Heating
yttrium oxide Yttrium oxide may refer to: * Yttrium(II) oxide Yttrium(II) oxide or yttrium monoxide is a chemical compound with the formula YO. This chemical compound was first created in its solid form by pulsed laser deposition, using yttrium(III) oxide as ...
with
ammonium iodide Ammonium iodide is the inorganic compound with the formula NH4I. A white solid. It is an ionic compound, although impure samples appear yellow. This salt consists of ammonium cation and an iodide anion.Holleman, A. F.; Wiberg, E. ''Inorganic Chemis ...
: : It can also be obtained by reacting yttrium oxide or yttrium hydroxide with hydroiodic acid.


Physical properties

Yttrium iodide forms colorless flaky crystals. The crystal structure is that of the structure type. It dissolves well in water and
ethanol Ethanol (also called ethyl alcohol, grain alcohol, drinking alcohol, or simply alcohol) is an organic compound with the chemical formula . It is an Alcohol (chemistry), alcohol, with its formula also written as , or EtOH, where Et is the ps ...
. Does not dissolve in
diethyl ether Diethyl ether, or simply ether, is an organic compound with the chemical formula , sometimes abbreviated as . It is a colourless, highly Volatility (chemistry), volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It belongs ...
. It also occurs as a tri- and hexahydrate.


Applications

A precursor for
YBCO Yttrium barium copper oxide (YBCO) is a family of crystalline chemical compounds that display high-temperature superconductivity; it includes the first material ever discovered to become superconductivity, superconducting above the boiling point o ...
superconducting Superconductivity is a set of physical properties observed in superconductors: materials where electrical resistance vanishes and magnetic fields are expelled from the material. Unlike an ordinary metallic conductor, whose resistance decreases g ...
materials in a lower temperature preparation.


References

{{Yttrium compounds Yttrium compounds Iodides Metal halides