Xitieshanite
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Xitieshanite is a hydrous
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
chloride The term chloride refers to a compound or molecule that contains either a chlorine anion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). The pr ...
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
with chemical formula: Fe3+(SO4)Cl·6(H2O). It was discovered in 1983 and named for the discovery location of Xitieshan
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
/
zinc Zinc is a chemical element; it has symbol Zn and atomic number 30. It is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodic tabl ...
ore deposit Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...
in the
Qinghai Province Qinghai is an inland province in Northwestern China. It is the largest province of China (excluding autonomous regions) by area and has the third smallest population. Its capital and largest city is Xining. Qinghai borders Gansu on the nort ...
,
China China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
. It was approved by the IMA in the year of its discovery. The mineral has also been reported in 2005 from
acid mine drainage Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines and coal mines. Acid rock drainage occurs naturally within some environments as part of the rock weatherin ...
from a
coal mine Coal mining is the process of resource extraction, extracting coal from the ground or from a mine. Coal is valued for its Energy value of coal, energy content and since the 1880s has been widely used to Electricity generation, generate electr ...
in Green Valley, Vigo County, Indiana.Melchiorre, Erik, et al., ''A new occurrence of xitieshanite e3+(SO4)Cl·6H2Ocrystals in acid-mine seepways, Green Valley, Vigo County, Indiana, U.S.A.,'' American Mineralogist, v. 90 no. 10 p. 1518-1521, 2005


Properties

Xitieshanite mainly consists of oxygen (56.14%) and iron (17.82%), but otherwise contains chlorine (11.31%), sulphur (10.23%) and hydrogen (4.50%). This mineral grown in lead-zinc mines, in the oxidation zone of it. Xitieshanite is a pleochroic mineral, which is an optical phenomenon, meaning the mineral appears as if it's changing colors depending on the axis it is being inspected at. On the X axis it appears as it's colorless, while it looks pale yellow if viewed on the Y axis, and light greenish yellow on the Z axis. It doesn't show any radioactive properties whatsoever.


References

Iron(III) minerals Sulfate minerals Halide minerals Monoclinic minerals Minerals in space group 14 {{sulfate-mineral-stub