The Wobbe index (WI) or Wobbe number
is an indicator of the interchangeability of
fuel gas
Fuel gas is one of a number of fuels that under ordinary conditions are gaseous. Most fuel gases are composed of hydrocarbons (such as methane and propane), hydrogen, carbon monoxide, or mixtures thereof. Such gases are sources of energy that c ...
es such as
natural gas
Natural gas (also fossil gas, methane gas, and gas) is a naturally occurring compound of gaseous hydrocarbons, primarily methane (95%), small amounts of higher alkanes, and traces of carbon dioxide and nitrogen, hydrogen sulfide and helium ...
,
liquefied petroleum gas
Liquefied petroleum gas, also referred to as liquid petroleum gas (LPG or LP gas), is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, Butane, ''n''-butane and isobutane. It can also contain some ...
(LPG), and
town gas
Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous ...
and is frequently defined in the specifications of gas supply and transport utilities.
If
is the
higher heating value
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it.
The ''calorific value'' is the total energy release ...
, or higher
calorific value
The heating value (or energy value or calorific value) of a substance, usually a fuel or food (see food energy), is the amount of heat released during the combustion of a specified amount of it.
The ''calorific value'' is the total energy release ...
, and
is the
specific gravity
Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
, the Wobbe index,
, is defined as:
:
:
is the density of the gas at
standard conditions, the
definition
A definition is a statement of the meaning of a term (a word, phrase, or other set of symbols). Definitions can be classified into two large categories: intensional definitions (which try to give the sense of a term), and extensional definitio ...
of which changed in 1982. Published Wobbe data may be using 0 °C, 15 °C, 15.56 °C, 20 °C or 25 °C. EU directives on gas quality use 15 °C in accordance with ISO 13443 and ISO 6976.
is the
density of air
The density of air or atmospheric density, denoted '' ρ'', is the mass per unit volume of Earth's atmosphere at a given point and time. Air density, like air pressure, decreases with increasing altitude. It also changes with variations in atmosph ...
at standard conditions,
is the
molar mass
In chemistry, the molar mass () (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical substance ( element or compound) is defined as the ratio between the mass () and the amount of substance ...
of the gas and
is the molar mass of air which is about 28.96 kg/kmol.
.
The Wobbe index is used to compare the combustion energy output of different composition fuel gases in an appliance (fire, cooker etc.). If two fuels have identical Wobbe indices then for given pressure and valve settings the energy output will also be identical. Typically variations of up to 5% are allowed as these would not be noticeable to the consumer.
The Wobbe index is a critical factor to minimise the impact of the changeover when analyzing the use of ''
substitute natural gas
Substitute natural gas (SNG), or synthetic natural gas, is a fuel gas (predominantly methane, CH4) that can be produced from fossil fuels such as lignite coal, oil shale, or from biofuels (when it is named bio-SNG) or using electricity with power ...
'' (SNG) fuels such as
propane
Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
-
air
An atmosphere () is a layer of gases that envelop an astronomical object, held in place by the gravity of the object. A planet retains an atmosphere when the gravity is great and the temperature of the atmosphere is low. A stellar atmosph ...
mixtures. The Wobbe index also requires the addition of propane to some upgraded biomethane products, particularly in regions where natural gas has a high calorific value such as Sweden.
The Wobbe index has its origins in the 1920's with
Italian
Italian(s) may refer to:
* Anything of, from, or related to the people of Italy over the centuries
** Italians, a Romance ethnic group related to or simply a citizen of the Italian Republic or Italian Kingdom
** Italian language, a Romance languag ...
physicist and engineer Goffredo Wobbe.
Wobbe index of common fuel gases
Note that these Wobbe numbers below are not calculated at 15 °C and so are not correct according to ISO 13443, see
Standard temperature and pressure
Standard temperature and pressure (STP) or standard conditions for temperature and pressure are various standard sets of conditions for experimental measurements used to allow comparisons to be made between different sets of data. The most used ...
.
:Note: 1
Joule
The joule ( , or ; symbol: J) is the unit of energy in the International System of Units (SI). In terms of SI base units, one joule corresponds to one kilogram- metre squared per second squared One joule is equal to the amount of work d ...
= .
Usage
The Wobbe index is expressed in
MJ/
Nm³ (where 'Nm³' indicates'm³ in Normal conditions), or sometimes in
BTU
The British thermal unit (Btu) is a measure of heat, which is a form of energy. It was originally defined as the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit. It is also part of the United Stat ...
/
scf. In the case of natural gas (
molar mass
In chemistry, the molar mass () (sometimes called molecular weight or formula weight, but see related quantities for usage) of a chemical substance ( element or compound) is defined as the ratio between the mass () and the amount of substance ...
17 g/mol), the typical heating value is around 39 MJ/Nm³ (1,050 BTU/scf) and the specific gravity is approximately 0.59, giving a typical Wobbe index of 51 MJ/Nm³ (1,367 BTU/scf).
There are three ranges or "families" of fuel gases that have been internationally agreed based on Wobbe index. Family 1 covers manufactured gases, family 2 covers natural gases (with high and low ranges) and family 3 covers liquefied petroleum gas (
LPG). Combustion equipment is typically designed to burn a fuel gas within a particular family: hydrogen-rich town gas, natural gas or LPG.
Other flame characteristics and composition limits may determine the acceptability of the replacement gas, e.g.
flame speed, "yellow tipping" due to incomplete combustion, sulfur content,
oxygen
Oxygen is a chemical element; it has chemical symbol, symbol O and atomic number 8. It is a member of the chalcogen group (periodic table), group in the periodic table, a highly reactivity (chemistry), reactive nonmetal (chemistry), non ...
content, etc.
Limitations
In spite of its usefulness, Wobbe index alone is not a good indicator of the interchangeability of two or more gases, or mixtures of them. It is necessary to bear in mind other criteria while determining the plenty substitution of a fuel by other, different of the one used to adjust the burning system.
References
*
{{Reflist
Eponymous indices
Fuel gas
Gas technologies