Witherite is a

barium carbonate Barium carbonate is the inorganic compound with the formula BaCO3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of ...

mineral, Ba C O₃, in the

aragonite Aragonite is a carbonate mineral and one of the three most common naturally occurring crystal forms of calcium carbonate (), the others being calcite and vaterite. It is formed by biological and physical processes, including precipitation fr ...

group. Witherite crystallizes in the

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic Lattice (group), lattices result from stretching a cubic crystal system, cubic lattice along two of its orthogonal pairs by two different factors, res ...

system and virtually always is twinned. The mineral is colorless, milky-white, grey, pale-yellow, green, to pale-brown. The

specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...

is 4.3, which is high for a translucent mineral. It fluoresces light blue under both long- and short-wave UV light, and is phosphorescent under short-wave UV light. Witherite forms in low-temperature

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

environments. It is commonly associated with

fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...

, celestine,

galena Galena, also called lead glance, is the natural mineral form of lead(II) sulfide (PbS). It is the most important ore of lead and an important source of silver. Galena is one of the most abundant and widely distributed sulfide minerals. It crysta ...

barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

, and

. Witherite occurrences include: Cave-in-Rock, Illinois, US; Pigeon Roost Mine, Glenwood, Arkansas, US; Settlingstones Mine

Northumberland Northumberland ( ) is a ceremonial counties of England, ceremonial county in North East England, on the Anglo-Scottish border, border with Scotland. It is bordered by the North Sea to the east, Tyne and Wear and County Durham to the south, Cumb ...

; Alston Moor,

Cumbria Cumbria ( ) is a ceremonial county in North West England. It borders the Scottish council areas of Dumfries and Galloway and Scottish Borders to the north, Northumberland and County Durham to the east, North Yorkshire to the south-east, Lancash ...

;

Anglezarke Anglezarke is a sparsely populated civil parish in the Borough of Chorley in Lancashire, England. It is an agricultural area used for sheep farming and is also the site of reservoirs that were built to supply water to Liverpool. The area has a la ...

Lancashire Lancashire ( , ; abbreviated ''Lancs'') is a ceremonial county in North West England. It is bordered by Cumbria to the north, North Yorkshire and West Yorkshire to the east, Greater Manchester and Merseyside to the south, and the Irish Sea to ...

and Burnhope,

County Durham County Durham, officially simply Durham, is a ceremonial county in North East England.UK General Acts 1997 c. 23Lieutenancies Act 1997 Schedule 1(3). From legislation.gov.uk, retrieved 6 April 2022. The county borders Northumberland and Tyne an ...

England England is a Countries of the United Kingdom, country that is part of the United Kingdom. It is located on the island of Great Britain, of which it covers about 62%, and List of islands of England, more than 100 smaller adjacent islands. It ...

;

Thunder Bay Thunder Bay is a city in and the seat of Thunder Bay District, Ontario, Canada. It is the most populous municipality in Northwestern Ontario and the second most populous (after Greater Sudbury) municipality in Northern Ontario. Its population i ...

area,

Ontario Ontario is the southernmost Provinces and territories of Canada, province of Canada. Located in Central Canada, Ontario is the Population of Canada by province and territory, country's most populous province. As of the 2021 Canadian census, it ...

Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...

Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...

, and

Poland Poland, officially the Republic of Poland, is a country in Central Europe. It extends from the Baltic Sea in the north to the Sudetes and Carpathian Mountains in the south, bordered by Lithuania and Russia to the northeast, Belarus and Ukrai ...

( Tarnowskie Góry and Tajno at

Suwałki Region Suwałki Region ( ; ) is a historical region around the city of Suwałki in northeastern Poland near the border with Lithuania. It encompasses the powiats of Augustów, Suwałki, and Sejny, and roughly corresponds to the southern part of the for ...

). Witherite was named after William Withering (1741–1799) an English physician and naturalist who in 1784 published his research on the new mineral. He could show that barite and the new mineral were two different minerals.

Discovery

In 1789 the German geologist Abraham Gottlob Werner named the mineral witherite in honour of William Withering. The

Matthew Boulton Matthew Boulton ( ; 3 September 172817 August 1809) was an English businessman, inventor, mechanical engineer, and silversmith. He was a business partner of the Scottish engineer James Watt. In the final quarter of the 18th century, the par ...

mineral collection of Birmingham Museum and Art Gallery may contain one of the earliest known specimens of witherite. A label in Boulton's handwriting, records: "No.2 Terra Ponderosa Aerata, given me by Dr. Withering".

Risk to human health

The 18th-century naturalist Dr. Leigh recorded its lethal effects after the death of a farmer's wife and child. James Watt Jnr. experimented with the mineral on animals and he recorded the same lethal properties. Until the 18th century farmers at

used the mineral as rat poison.The Mining Magazine, March 1963, Vol 108, pages 133–139

Industrial use

An experiment conducted by

Josiah Wedgwood Josiah Wedgwood (12 July 1730 – 3 January 1795) was an English potter, entrepreneur and abolitionist. Founding the Wedgwood company in 1759, he developed improved pottery bodies by systematic experimentation, and was the leader in the indu ...

, led to it being used in his ' Jasper ware'; the mineral had previously been considered as worthless. Witherite has been used for hardening steel, and for making cement, glass, enamelware, soap, dye and explosives. Witherite crystallizes in the

system. The

crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macros ...

s are invariably twinned together in groups of three, giving rise to pseudo-hexagonal forms somewhat resembling bipyramidal crystals of

quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...

, the faces are usually rough and striated horizontally. It transforms into an hexagonal phase at 1084 K that changes into a cubic phase at 1254 K. The mineral is named after William Withering, who in 1784 recognized it to be chemically distinct from

baryte Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate (Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...

s. It occurs in veins of

lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...

ore Ore is natural rock or sediment that contains one or more valuable minerals, typically including metals, concentrated above background levels, and that is economically viable to mine and process. The grade of ore refers to the concentration ...

Hexham Hexham ( ) is a market town and civil parish in Northumberland, England, on the south bank of the River Tyne, formed by the confluence of the North Tyne and the South Tyne at Warden nearby, and close to Hadrian's Wall. Hexham was the administra ...

, Alston in

, near

Chorley Chorley is a town and the administrative centre of the wider Borough of Chorley in Lancashire, England, north of Wigan, south west of Blackburn, north west of Bolton, south of Preston and north west of Manchester. The town's wealth ca ...

and a few other localities. Witherite is readily altered to barium

sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...

by the action of water containing

calcium sulfate Calcium sulfate (or calcium sulphate) is an inorganic salt with the chemical formula . It occurs in several hydrated forms; the anhydrous state (known as anhydrite) is a white crystalline solid often found in evaporite deposits. Its dihydrate ...

in solution and crystals are therefore frequently encrusted with

s. It is the chief source of barium

salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...

s and is mined in considerable amounts in Northumberland. It is used for the preparation of rat poison, in the manufacture of

glass Glass is an amorphous (non-crystalline solid, non-crystalline) solid. Because it is often transparency and translucency, transparent and chemically inert, glass has found widespread practical, technological, and decorative use in window pane ...

and

porcelain Porcelain (), also called china, is a ceramic material made by heating Industrial mineral, raw materials, generally including kaolinite, in a kiln to temperatures between . The greater strength and translucence of porcelain, relative to oth ...

, and formerly for refining

sugar Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose Glucose is a sugar with the Chemical formula#Molecular formula, molecul ...

. It is also used for controlling the chromate to

ratio in

chromium Chromium is a chemical element; it has Symbol (chemistry), symbol Cr and atomic number 24. It is the first element in Group 6 element, group 6. It is a steely-grey, Luster (mineralogy), lustrous, hard, and brittle transition metal. Chromium ...

electroplating Electroplating, also known as electrochemical deposition or electrodeposition, is a process for producing a metal coating on a solid substrate through the redox, reduction of cations of that metal by means of a direct current, direct electric cur ...

baths. Witherite-216507.jpg, Two sharp pseudohexagonal crystals of witherite on calcite from Hardin County, Illinois (size: 6.4 × 5.4 × 3.4 cm) Witherite-65711.jpg, Witherite crystal from the Cave-in-Rock Sub-District, Illinois – Kentucky Fluorspar District, Hardin County, Illinois

References

External links

{{commonscat-inline, Witherite Barium minerals Carbonate minerals Orthorhombic minerals Minerals in space group 62 Luminescent minerals Aragonite group

Discovery

Risk to human health

Industrial use

See also

References

External links