A whiteschist is an uncommon

metamorphic rock Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock ( protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...

formed at high to ultra-high pressures. It has the characteristic mineral assemblage of

kyanite Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure Polymorphism (materials science), polymorph of andalusite and sillimanite, and the presence of kyani ...

talc Talc, or talcum, is a clay mineral composed of hydrated magnesium silicate, with the chemical formula . Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent and lubricant ...

, responsible for its white colour. The name was introduced in 1973 by German mineralogist and petrologist

Werner Schreyer Werner Schreyer (14 November 1930 in Nuremberg; 12 February 2006 in Bochum) was a German mineralogist and experimental metamorphic petrologist. Schreyer completed his undergraduate work in geology and petrology at the University of Erlangen-Nuremb ...

. This rock is associated with the

metamorphism Metamorphism is the transformation of existing Rock (geology), rock (the protolith) to rock with a different mineral composition or Texture (geology), texture. Metamorphism takes place at temperatures in excess of , and often also at elevated ...

of some

pelite A pelite () or metapelite is a metamorphism, metamorphosed fine-grained sedimentary rock, i.e. mudstone or siltstone. The term was earlier used by geologists to describe a clay-rich, fine-grained clastic sediment or sedimentary rock, i.e. mud or ...

evaporite An evaporite () is a water- soluble sedimentary mineral deposit that results from concentration and crystallization by evaporation from an aqueous solution. There are two types of evaporite deposits: marine, which can also be described as oce ...

sequences or altered

basalt Basalt (; ) is an aphanite, aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the planetary surface, surface of a terrestrial ...

ic or

felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...

intrusion In geology, an igneous intrusion (or intrusive body or simply intrusion) is a body of intrusive igneous rock that forms by crystallization of magma slowly cooling below the surface of the Earth. Intrusions have a wide variety of forms and com ...

s. Whiteschists form in the MgO–––– (MFASH) system. Rocks of this primary chemistry are extremely uncommon and they are in most cases thought to be the result of

metasomatic Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...

alteration, with the removal of various mobile elements.

Occurrence

Whiteschists occur as lenses or tectonic slices on a metre to kilometre scale within nine

orogenic belt An orogenic belt, orogen, or mobile belt, is a zone of Earth's crust affected by orogeny. An orogenic belt develops when a continental plate crumples and is uplifted to form one or more mountain ranges; this involves a series of geological proc ...

s around the world. There are two occurrences in Central Africa, one in

Tasmania Tasmania (; palawa kani: ''Lutruwita'') is an island States and territories of Australia, state of Australia. It is located to the south of the Mainland Australia, Australian mainland, and is separated from it by the Bass Strait. The sta ...

, one in the Norwegian Caledonides, two in the Alps and three in Asia. One of the most extensive outcrops of whiteschist occurs within the

Lufilian Arc The Lufilian Arc (or Lufilian Belt) is part of a system of orogenic belts in southern Africa formed during the Pan-African orogeny, a stage in the formation of the Gondwana supercontinent. It extends across eastern Angola, the Katanga Province of ...

- Zambezi Belt

orogen An orogenic belt, orogen, or mobile belt, is a zone of Earth's crust affected by orogeny. An orogenic belt develops when a continental plate crumples and is uplifted to form one or more mountain ranges; this involves a series of geological proc ...

. This northwest-southeast trending zone extends for about 700 km. The whiteschist is found with rocks bearing the assemblages

anthophyllite Anthophyllite is an orthorhombic amphibole mineral: ☐Mg2Mg5Si8O22(OH)2 (☐ is for a vacancy, a point defect in the crystal structure), magnesium iron inosilicate hydroxide. Anthophyllite is polymorphic with cummingtonite. Some forms of anth ...

–

cordierite Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present, and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: to . A high-tempera ...

–

and

garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...

–

staurolite Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc ...

–

. Most occurrences were originally described from

metasediment In geology, metasedimentary rock is a type of metamorphic rock. Such a rock was first formed through the deposition and solidification of sediment Sediment is a solid material that is transported to a new location where it is deposited. It occu ...

ary sequences, and thought to represent either evaporite or

bentonite Bentonite ( ) is an Absorption (chemistry), absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelli ...

layers. However, whiteschists have now been described with

protolith A protolith () is the original, unmetamorphosed rock from which a given metamorphic rock is formed. For example, the protolith of a slate is a shale or mudstone. Metamorphic rocks can be derived from any other kind of non-metamorphic rock and ...

s ranging from metabasalt to granite.

Formation

Whiteschists have a chemistry that only very rarely occurs as the primary composition of rocks. This implies that they can only form under conditions where other chemical components have been removed by large scale metasomatism, strongly altering the original rock composition. The mobile components that may be removed include , CaO, , MnO, , Rb, Ba, Th. Another feature of whiteschists is that iron and manganese only occur in their highest

oxidation state In chemistry, the oxidation state, or oxidation number, is the hypothetical Electrical charge, charge of an atom if all of its Chemical bond, bonds to other atoms are fully Ionic bond, ionic. It describes the degree of oxidation (loss of electrons ...

, indicating that the fluid responsible for the metasomatism was characterised by a high oxygen

fugacity In thermodynamics, the fugacity of a real gas is an effective partial pressure which replaces the mechanical partial pressure in an accurate computation of chemical equilibrium. It is equal to the pressure of an ideal gas which has the same tempe ...

. The main reaction involved in their formation is Mg-

chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...

+ quartz → talc + kyanite, which has been used to define the stability of the whiteschist assemblage. In at least one example however, the overall reaction

phlogopite Phlogopite is a yellow, greenish, or reddish-brown member of the mica family of phyllosilicates. It is also known as magnesium mica. Phlogopite is the magnesium endmember of the biotite solid solution series, with the chemical formula KMg3AlSi3 ...

+ amphibole +

plagioclase Plagioclase ( ) is a series of Silicate minerals#Tectosilicates, tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continu ...

→ kyanite + talc + quartz + Fe(

hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...

) + Na, Ca, K, Mn (fluid) has been described from an altered

amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose ...

, suggesting that the original reaction may be insufficient to describe the full stability range of the kyanite + talc assemblage under high oxygen fugacity conditions.

References

{{Rock type Metamorphic petrology Schist