Volumetric Flask
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A volumetric flask (measuring flask or graduated flask) is a piece of laboratory apparatus, a type of
laboratory flask Laboratory flasks are vessels or containers that fall into the category of laboratory equipment known as glassware. In laboratory and other scientific settings, they are usually referred to simply as flasks. Flasks come in a number of shapes an ...
, calibrated to contain a precise volume at a certain temperature. Volumetric flasks are used for precise dilutions and preparation of
standard solution In analytical chemistry, a standard solution (titrant or titrator) is a solution containing an accurately known concentration. Standard solutions are generally prepared by dissolving a solute of known mass into a solvent to a precise volume, or by ...
s. These flasks are usually pear-shaped, with a flat bottom, and made of glass or plastic. The flask's mouth is either furnished with a plastic snap/screw cap or fitted with a
joint A joint or articulation (or articular surface) is the connection made between bones, ossicles, or other hard structures in the body which link an animal's skeletal system into a functional whole.Saladin, Ken. Anatomy & Physiology. 7th ed. McGraw- ...
to accommodate a
PTFE Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene, and has numerous applications because it is chemically inert. The commonly known brand name of PTFE-based composition is Teflon by Chemours, a spin-off fro ...
or glass stopper. The neck of volumetric flasks is elongated and narrow with an etched ring
graduation A graduation is the awarding of a diploma by an educational institution. It may also refer to the ceremony that is associated with it, which can also be called Commencement speech, commencement, Congregation (university), congregation, Convocat ...
marking. The marking indicates the volume of liquid contained when filled up to that point. The marking is typically
calibrated In measurement technology and metrology, calibration is the comparison of measurement values delivered by a device under test with those of a calibration standard of known accuracy. Such a standard could be another measurement device of known ...
"to contain" (marked "TC" or "IN") at 20 °C and indicated correspondingly on a label. The flask's label also indicates the nominal
volume Volume is a measure of regions in three-dimensional space. It is often quantified numerically using SI derived units (such as the cubic metre and litre) or by various imperial or US customary units (such as the gallon, quart, cubic inch) ...
, tolerance, precision class, relevant manufacturing standard and the manufacturer's logo. Volumetric flasks are of various sizes, containing from a fraction of a milliliter to hundreds of liters of liquid.


Classes

Calibration and toleration standards for volumetric flasks are defined in the following standard specifications and practices:
ASTM ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and s ...
E288, E542, E694,
ISO The International Organization for Standardization (ISO ; ; ) is an independent, non-governmental, international standard development organization composed of representatives from the national standards organizations of member countries. Me ...
1042, and
GOST GOST () refers to a set of international technical standards maintained by the Euro-Asian Council for Standardization, Metrology and Certification (EASC), a regional standards organization operating under the auspices of the Commonwealth of I ...
1770-74. According to these specifications, volumetric flasks come in two different classes. The higher standard flasks (Class A, Class 1, USP or equivalent depending on the country) are made with a more accurately placed graduation mark, and have a unique serial number for traceability. Where this is not required, a lower standard (Class B or equivalent) is used for qualitative or educational work.


Modifications

Volumetric flasks are generally colourless but may be amber-coloured for the handling of light-sensitive compounds such as
silver nitrate Silver nitrate is an inorganic compound with chemical formula . It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called ''lunar causti ...
or
vitamin A Vitamin A is a fat-soluble vitamin that is an essential nutrient. The term "vitamin A" encompasses a group of chemically related organic compounds that includes retinol, retinyl esters, and several provitamin (precursor) carotenoids, most not ...
. A modification of the volumetric flask exists for dealing with large quantities of solids that are to be transferred into a volumetric vessel for dissolution. Such a flask has a wide mouth and is known as a ''Kohlrausch volumetric flask''. This kind of volumetric flask is commonly used in analysis of the sugar content in
sugar beet A sugar beet is a plant whose root contains a high concentration of sucrose and that is grown commercially for sugar production. In plant breeding, it is known as the Altissima cultivar group of the common beet (''Beta vulgaris''). Together with ...
s. While conventional volumetric flasks have a single mark, industrial volumetric tests in
analytical chemistry Analytical skill, Analytical chemistry studies and uses instruments and methods to Separation process, separate, identify, and Quantification (science), quantify matter. In practice, separation, identification or quantification may constitute t ...
and
food chemistry Food chemistry is the study of chemical processes and interactions of all biological and non-biological components of foods. The biological substances include such items as meat, poultry, lettuce, beer, milk as examples. It is similar to biochemi ...
may employ specialized volumetric flasks with multiple marks to combine several accurately measured volumes. A highly specialized kind of the volumetric flask is the ''Le Chatelier flask'' for use with the volumetric procedure in
specific gravity Relative density, also called specific gravity, is a dimensionless quantity defined as the ratio of the density (mass of a unit volume) of a substance to the density of a given reference material. Specific gravity for solids and liquids is nea ...
determination.


See also

* Graduated cylinder * Babcock bottle *
Burette A burette (also spelled buret) is a graduated glass tube with a tap at one end, for delivering known volumes of a liquid, especially in titrations. It is a long, graduated glass tube, with a stopcock at its lower end and a tapered capillary tub ...


References


Further reading

* * * {{DEFAULTSORT:Volumetric Flask Laboratory glassware Volumetric instruments