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Volatilization is the process whereby a dissolved sample is
vaporised Vaporization (or vaporisation) of an element or compound is a phase transition from the liquid phase to vapor. There are two types of vaporization: evaporation and boiling. Evaporation is a surface phenomenon, whereas boiling is a bulk phenomenon. ...
. In atomic spectroscopy this is usually a two-step process. The analyte is turned into small droplets in a nebuliser which are entrained in a gas flow which is in turn volatilised in a high temperature flame in the case of AAS or volatilised in a
gas plasma torch Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
in the case of
ICP spectroscopy ICP may refer to: Business * ICP srl, Italian manufacturer of automotive equipment and kit aircraft *Ideal customer profile: see Qualified prospect * International Comfort Products Corporation, US air conditioning and heating company * Indonesian ...
.


Herbicide volatilisation

Herbicide volatilisation refers to
evaporation Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidi ...
or
sublimation Sublimation or sublimate may refer to: * ''Sublimation'' (album), by Canvas Solaris, 2004 * Sublimation (phase transition), directly from the solid to the gas phase * Sublimation (psychology), a mature type of defense mechanism * Sublimate of mer ...
of a volatile
herbicide Herbicides (, ), also commonly known as weedkillers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page fo ...
. The effect of gaseous chemical is lost at its intended place of application and may move downwind and affect other plants not intended to be affected causing crop damage. Herbicides vary in their susceptibility to volatilisation. Prompt incorporation of the herbicide into the soil may reduce or prevent volatilisation. Wind, temperature, and humidity also affect the rate of volatilisation with humidity reducing in. 2,4-D and dicamba are commonly used chemicals that are known to be subject to volatilisation but there are many others. Application of herbicides later in the season to protect herbicide-resistant genetically modified plants increases the risk of volatilisation as the temperature is higher and incorporation into the soil impractical., Herbicide applied as a powder or a mist can also drift in the wind in solid form as dust or liquid form as tiny drops. However, a transformation of known herbicides, such as glyphosate, dicamba or MCPA, into the form of
herbicidal ionic liquids Herbicides (, ), also commonly known as weedkillers, are substances used to control undesired plants, also known as weeds.EPA. February 201Pesticides Industry. Sales and Usage 2006 and 2007: Market Estimates. Summary in press releasMain page fo ...
proved to be a solution to this particular problem since herbicidal ionic systems express lower susceptibility to volatilisation.


Notes

Analytical chemistry {{Chemistry-stub