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Valleriite is an uncommon
sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide () as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenide mineral, selenides, the tell ...
(hydroxysulfide) of iron and copper with formula: or . It is an opaque, soft, bronze-yellow to brown mineral which occurs as nodules or encrustations.


Discovery and occurrence

Valleriite was first described in 1870 from an occurrence in Västmanland,
Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...
. It was named for Swedish chemist
Johan Gottschalk Wallerius Johan Gottschalk Wallerius (11 July 1709 – 16 November 1785) was a Swedish chemist and mineralogist. Biography Wallerius was born at Stora Mellösa in Närke (now Örebro County), Sweden. He was a son of provost Erik Nilsson Wallerius and h ...
(Vallerius) (1709–1785). Valleriite occurs in
dunite Dunite (), also known as olivinite (not to be confused with the mineral olivenite), is an intrusive igneous rock of ultramafic composition and with phaneritic (coarse-grained) texture. The mineral assemblage is greater than 90% olivine, wit ...
s and
chromitite Chromitite is an igneous cumulate rock composed mostly of the mineral chromite. It is found in layered intrusions such as the Bushveld Igneous Complex in South Africa, the Stillwater igneous complex in Montana and the Ring of Fire discovery in ...
s replacing
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 ...
in
Cyprus Cyprus (), officially the Republic of Cyprus, is an island country in the eastern Mediterranean Sea. Situated in West Asia, its cultural identity and geopolitical orientation are overwhelmingly Southeast European. Cyprus is the List of isl ...
. In
Phalaborwa Phalaborwa (translated to English as ''better than the south; phala'' means ''better than and borwa'' means ''south'') is a town in the Mopani District Municipality, Limpopo province, South Africa. Name The place was called "Phalaborwa" by the S ...
,
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
it occurs as replacement of
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...
in a
carbonatite Carbonatite () is a type of intrusive rock, intrusive or extrusive rock, extrusive igneous rock defined by mineralogic composition consisting of greater than 50% carbonate minerals. Carbonatites may be confused with marble and may require geoche ...
. It occurs as replacements of copper and nickel phases in
serpentinite Serpentinite is a metamorphic rock composed predominantly of serpentine group minerals formed by serpentinization of mafic or ultramafic rocks. The ancient origin of the name is uncertain; it may be from the similarity of its texture or color ...
s and other altered
ultramafic rock Ultramafic rocks (also referred to as ultrabasic rocks, although the terms are not wholly equivalent) are igneous and meta-igneous rocks with a very low silica content (less than 45%), generally >18% MgO, high FeO, low potassium, and are usua ...
s.


References

Copper minerals Iron minerals Magnesium minerals Aluminium minerals Sulfide minerals Trigonal minerals Minerals in space group 166 Minerals described in 1870 {{sulfide-mineral-stub