
In
particle physics
Particle physics or high-energy physics is the study of Elementary particle, fundamental particles and fundamental interaction, forces that constitute matter and radiation. The field also studies combinations of elementary particles up to the s ...
, the quark model is a classification scheme for
hadron
In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced , the name is derived . They are analogous to molecules, which are held together by the electri ...
s in terms of their valence
quark
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nucleus, atomic nuclei ...
s—the quarks and antiquarks that give rise to the
quantum number
In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system.
To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantu ...
s of the hadrons. The quark model underlies
"flavor SU(3)", or the
Eightfold Way, the successful
classification scheme
In information science and ontology, a classification scheme is an arrangement of classes or groups of classes. The activity of developing the schemes bears similarity to taxonomy, but with perhaps a more theoretical bent, as a single classifica ...
organizing the large number of lighter
hadron
In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced , the name is derived . They are analogous to molecules, which are held together by the electri ...
s that were being discovered starting in the 1950s and continuing through the 1960s. It received experimental
verification beginning in the late 1960s and is a valid and effective classification of them to date. The model was independently proposed by physicists
Murray Gell-Mann
Murray Gell-Mann (; September 15, 1929 – May 24, 2019) was an American theoretical physicist who played a preeminent role in the development of the theory of elementary particles. Gell-Mann introduced the concept of quarks as the funda ...
,
[
] who dubbed them "quarks" in a concise paper, and
George Zweig
George Zweig (; born May 30, 1937) is an American physicist of Russian-Jewish origin. He was trained as a particle physicist under Richard Feynman. He introduced, independently of Murray Gell-Mann, the quark model (although he named it "aces"). ...
,
who suggested "aces" in a longer manuscript.
André Petermann also touched upon the central ideas from 1963 to 1965, without as much quantitative substantiation. Today, the model has essentially been absorbed as a component of the established
quantum field theory
In theoretical physics, quantum field theory (QFT) is a theoretical framework that combines Field theory (physics), field theory and the principle of relativity with ideas behind quantum mechanics. QFT is used in particle physics to construct phy ...
of strong and electroweak particle interactions, dubbed the
Standard Model
The Standard Model of particle physics is the Scientific theory, theory describing three of the four known fundamental forces (electromagnetism, electromagnetic, weak interaction, weak and strong interactions – excluding gravity) in the unive ...
.
Hadrons are not really "elementary", and can be regarded as bound states of their "valence quarks" and antiquarks, which give rise to the
quantum number
In quantum physics and chemistry, quantum numbers are quantities that characterize the possible states of the system.
To fully specify the state of the electron in a hydrogen atom, four quantum numbers are needed. The traditional set of quantu ...
s of the hadrons. These quantum numbers are labels identifying the hadrons, and are of two kinds. One set comes from the
Poincaré symmetry—''J''
''PC'', where ''J'', ''P'' and ''C'' stand for the
total angular momentum
In quantum mechanics, the total angular momentum quantum number parametrises the total angular momentum of a given particle, by combining its orbital angular momentum and its intrinsic angular momentum (i.e., its spin).
If s is the particle's ...
,
P-symmetry
In physics, a parity transformation (also called parity inversion) is the flip in the sign of ''one'' Three-dimensional space, spatial coordinate. In three dimensions, it can also refer to the simultaneous flip in the sign of all three spatial co ...
, and
C-symmetry
In physics, charge conjugation is a transformation that switches all particles with their corresponding antiparticles, thus changing the sign of all charges: not only electric charge but also the charges relevant to other forces. The term C-sy ...
, respectively.
The other set is the
flavor quantum numbers such as the
isospin
In nuclear physics and particle physics, isospin (''I'') is a quantum number related to the up- and down quark content of the particle.
Isospin is also known as isobaric spin or isotopic spin.
Isospin symmetry is a subset of the flavour symmetr ...
,
strangeness
In particle physics, strangeness (symbol ''S'') is a property of particles, expressed as a quantum number, for describing decay of particles in strong and electromagnetic interactions that occur in a short period of time. The strangeness of a ...
,
charm, and so on. The strong interactions binding the quarks together are insensitive to these quantum numbers, so variation of them leads to systematic mass and coupling relationships among the hadrons in the same flavor multiplet.
All quarks are assigned a
baryon number
In particle physics, the baryon number (B) is an additive quantum number of a system. It is defined as
B = \frac(n_\text - n_),
where is the number of quarks, and is the number of antiquarks. Baryons (three quarks) have B = +1, mesons (one q ...
of .
Up,
charm and
top quark
The top quark, sometimes also referred to as the truth quark, (symbol: t) is the most massive of all observed elementary particles. It derives its mass from its coupling to the Higgs field. This coupling is very close to unity; in the Standard ...
s have an
electric charge
Electric charge (symbol ''q'', sometimes ''Q'') is a physical property of matter that causes it to experience a force when placed in an electromagnetic field. Electric charge can be ''positive'' or ''negative''. Like charges repel each other and ...
of +, while the
down,
strange
Strange may refer to:
Fiction
* Strange (comic book), a comic book limited series by Marvel Comics
* Strange (Marvel Comics), one of a pair of Marvel Comics characters known as The Strangers
* Adam Strange, a DC Comics superhero
* The title c ...
, and
bottom quark
The bottom quark, beauty quark, or b quark, is an elementary particle of the third generation. It is a heavy quark with a charge of − ''e''.
All quarks are described in a similar way by electroweak interaction and quantum chromodynamic ...
s have an electric charge of −. Antiquarks have the opposite quantum numbers. Quarks are
spin- particles, and thus
fermion
In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s. Each quark or antiquark obeys the Gell-Mann–Nishijima formula individually, so any additive assembly of them will as well.
Meson
In particle physics, a meson () is a type of hadronic subatomic particle composed of an equal number of quarks and antiquarks, usually one of each, bound together by the strong interaction. Because mesons are composed of quark subparticles, the ...
s are made of a valence quark–antiquark pair (thus have a baryon number of 0), while
baryon
In particle physics, a baryon is a type of composite particle, composite subatomic particle that contains an odd number of valence quarks, conventionally three. proton, Protons and neutron, neutrons are examples of baryons; because baryons are ...
s are made of three quarks (thus have a baryon number of 1). This article discusses the quark model for the up, down, and strange flavors of quark (which form an approximate flavor
SU(3) symmetry). There are generalizations to larger number of flavors.
History
Developing classification schemes for
hadron
In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced , the name is derived . They are analogous to molecules, which are held together by the electri ...
s became a timely question after new experimental techniques uncovered so many of them that it became clear that they could not all be elementary. These discoveries led
Wolfgang Pauli
Wolfgang Ernst Pauli ( ; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and a pioneer of quantum mechanics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics "for the ...
to exclaim "Had I foreseen that, I would have gone into botany." and
Enrico Fermi
Enrico Fermi (; 29 September 1901 – 28 November 1954) was an Italian and naturalized American physicist, renowned for being the creator of the world's first artificial nuclear reactor, the Chicago Pile-1, and a member of the Manhattan Project ...
to advise his student
Leon Lederman
Leon, Léon (French) or León (Spanish) may refer to:
Places
Europe
* León, Spain, capital city of the Province of León
* Province of León, Spain
* Kingdom of León, an independent state in the Iberian Peninsula from 910 to 1230 and again fro ...
: "Young man, if I could remember the names of these particles, I would have been a botanist." These new schemes earned Nobel prizes for experimental particle physicists, including
Luis Alvarez, who was at the forefront of many of these developments. Constructing hadrons as bound states of fewer constituents would thus organize the "zoo" at hand. Several early proposals, such as the ones by
Enrico Fermi
Enrico Fermi (; 29 September 1901 – 28 November 1954) was an Italian and naturalized American physicist, renowned for being the creator of the world's first artificial nuclear reactor, the Chicago Pile-1, and a member of the Manhattan Project ...
and
Chen-Ning Yang (1949), and the
Sakata model (1956), ended up satisfactorily covering the mesons, but failed with baryons, and so were unable to explain all the data.
The
Gell-Mann–Nishijima formula, developed by
Murray Gell-Mann
Murray Gell-Mann (; September 15, 1929 – May 24, 2019) was an American theoretical physicist who played a preeminent role in the development of the theory of elementary particles. Gell-Mann introduced the concept of quarks as the funda ...
and
Kazuhiko Nishijima, led to the
Eightfold Way classification, invented by Gell-Mann, with important independent contributions from
Yuval Ne'eman, in 1961. The hadrons were organized into SU(3) representation multiplets, octets and decuplets, of roughly the same mass, due to the strong interactions; and smaller mass differences linked to the flavor quantum numbers, invisible to the strong interactions. The
Gell-Mann–Okubo mass formula systematized the quantification of these small mass differences among members of a hadronic multiplet, controlled by the
explicit symmetry breaking of SU(3).
The spin-
baryon, a member of the ground-state decuplet, was a crucial prediction of that classification. After it was discovered in an experiment at
Brookhaven National Laboratory
Brookhaven National Laboratory (BNL) is a United States Department of Energy national laboratories, United States Department of Energy national laboratory located in Upton, New York, a hamlet of the Brookhaven, New York, Town of Brookhaven. It w ...
, Gell-Mann received a
Nobel Prize in Physics
The Nobel Prize in Physics () is an annual award given by the Royal Swedish Academy of Sciences for those who have made the most outstanding contributions to mankind in the field of physics. It is one of the five Nobel Prizes established by the ...
for his work on the Eightfold Way, in 1969.
Finally, in 1964, Gell-Mann and
George Zweig
George Zweig (; born May 30, 1937) is an American physicist of Russian-Jewish origin. He was trained as a particle physicist under Richard Feynman. He introduced, independently of Murray Gell-Mann, the quark model (although he named it "aces"). ...
, discerned independently what the Eightfold Way picture encodes: They posited three elementary fermionic constituents—the "
up", "
down", and "
strange
Strange may refer to:
Fiction
* Strange (comic book), a comic book limited series by Marvel Comics
* Strange (Marvel Comics), one of a pair of Marvel Comics characters known as The Strangers
* Adam Strange, a DC Comics superhero
* The title c ...
" quarks—which are unobserved, and possibly unobservable in a free form. Simple pairwise or triplet combinations of these three constituents and their antiparticles underlie and elegantly encode the Eightfold Way classification, in an economical, tight structure, resulting in further simplicity. Hadronic mass differences were now linked to the different masses of the constituent quarks.
It would take about a decade for the unexpected nature—and physical reality—of these quarks to be appreciated more fully (See
Quarks
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nuclei. All commonly o ...
). Counter-intuitively, they cannot ever be observed in isolation (
color confinement
In quantum chromodynamics (QCD), color confinement, often simply called confinement, is the phenomenon that color-charged particles (such as quarks and gluons) cannot be isolated, and therefore cannot be directly observed in normal conditions b ...
), but instead always combine with other quarks to form full hadrons, which then furnish ample indirect information on the trapped quarks themselves. Conversely, the quarks serve in the definition of
quantum chromodynamics
In theoretical physics, quantum chromodynamics (QCD) is the study of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type of ...
, the fundamental theory fully describing the strong interactions; and the Eightfold Way is now understood to be a consequence of the flavor symmetry structure of the lightest three of them.
Mesons

The Eightfold Way classification is named after the following fact: If we take three flavors of quarks, then the quarks lie in the
fundamental representation, 3 (called the triplet) of
flavor SU(3)
In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1.
The matrices of the more general unitary group may have complex determinants with absolute value 1, rather than real 1 i ...
. The antiquarks lie in the complex conjugate representation . The nine states (nonet) made out of a pair can be decomposed into the
trivial representation
In the mathematical field of representation theory, a trivial representation is a representation of a group ''G'' on which all elements of ''G'' act as the identity mapping of ''V''. A trivial representation of an associative or Lie algebra is ...
, 1 (called the singlet), and the
adjoint representation, 8 (called the octet). The notation for this decomposition is
:
Figure 1 shows the application of this decomposition to the mesons. If the flavor symmetry were exact (as in the limit that only the strong interactions operate, but the electroweak interactions are notionally switched off), then all nine mesons would have the same mass. However, the physical content of the full theory includes consideration of the symmetry breaking induced by the quark mass differences, and considerations of mixing between various multiplets (such as the octet and the singlet).
N.B. Nevertheless, the mass splitting between the and the is larger than the quark model can accommodate, and this "
– puzzle" has its origin in topological peculiarities of the strong interaction vacuum, such as
instanton
An instanton (or pseudoparticle) is a notion appearing in theoretical and mathematical physics. An instanton is a classical solution to equations of motion with a finite, non-zero action, either in quantum mechanics or in quantum field theory. M ...
configurations.
Mesons are hadrons with zero
baryon number
In particle physics, the baryon number (B) is an additive quantum number of a system. It is defined as
B = \frac(n_\text - n_),
where is the number of quarks, and is the number of antiquarks. Baryons (three quarks) have B = +1, mesons (one q ...
. If the quark–antiquark pair are in an
orbital angular momentum state, and have
spin , then
* ≤ ''J'' ≤ ''L'' + ''S'', where ''S'' = 0 or 1,
* ''P'' = (−1)
''L''+1, where the 1 in the exponent arises from the
intrinsic parity
In quantum mechanics, the intrinsic parity is a phase factor that arises as an eigenvalue of the parity operation x_i \rightarrow x_i' = -x_i (a reflection about the origin). To see that the parity's eigenvalues are phase factors, we assume an ...
of the quark–antiquark pair.
* ''C'' = (−1)
''L''+''S'' for mesons which have no
flavor. Flavored mesons have indefinite value of
''C''.
* For
isospin
In nuclear physics and particle physics, isospin (''I'') is a quantum number related to the up- and down quark content of the particle.
Isospin is also known as isobaric spin or isotopic spin.
Isospin symmetry is a subset of the flavour symmetr ...
and 0 states, one can define a new
multiplicative quantum number
In quantum field theory, multiplicative quantum numbers are conserved quantum numbers of a special kind. A given quantum number ''q'' is said to be additive if in a particle reaction the sum of the ''q''-values of the interacting particles is the ...
called the ''
G-parity In particle physics, G-parity is a multiplicative quantum number that results from the generalization of C-parity to multiplets of particles.
''C''-parity applies only to neutral systems; in the pion triplet, only π0 has ''C''-parity. On the ot ...
'' such that .
If ''P'' = (−1)
''J'', then it follows that ''S'' = 1, thus ''PC'' = 1. States with these quantum numbers are called ''natural parity states''; while all other quantum numbers are thus called ''exotic'' (for example, the state ).
Baryons

Since quarks are
fermion
In particle physics, a fermion is a subatomic particle that follows Fermi–Dirac statistics. Fermions have a half-integer spin (spin 1/2, spin , Spin (physics)#Higher spins, spin , etc.) and obey the Pauli exclusion principle. These particles i ...
s, the
spin–statistics theorem implies that the
wavefunction
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter) ...
of a baryon must be antisymmetric under the exchange of any two quarks. This antisymmetric wavefunction is obtained by making it fully antisymmetric in color, discussed below, and symmetric in flavor, spin and space put together. With three flavors, the decomposition in flavor is
The decuplet is symmetric in flavor, the singlet antisymmetric and the two octets have mixed symmetry. The space and spin parts of the states are thereby fixed once the orbital angular momentum is given.
It is sometimes useful to think of the
basis states of quarks as the six states of three flavors and two spins per flavor. This approximate symmetry is called spin-flavor
SU(6). In terms of this, the decomposition is
The 56 states with symmetric combination of spin and flavour decompose under flavor
SU(3)
In mathematics, the special unitary group of degree , denoted , is the Lie group of unitary matrices with determinant 1.
The matrices of the more general unitary group may have complex determinants with absolute value 1, rather than real 1 i ...
into
where the superscript denotes the spin, ''S'', of the baryon. Since these states are symmetric in spin and flavor, they should also be symmetric in space—a condition that is easily satisfied by making the orbital angular momentum . These are the ground-state baryons.
The octet baryons are the two
nucleon
In physics and chemistry, a nucleon is either a proton or a neutron, considered in its role as a component of an atomic nucleus. The number of nucleons in a nucleus defines the atom's mass number.
Until the 1960s, nucleons were thought to be ele ...
s (, ), the three
Sigmas (, , ), the two
Xis (, ), and the
Lambda
Lambda (; uppercase , lowercase ; , ''lám(b)da'') is the eleventh letter of the Greek alphabet, representing the voiced alveolar lateral approximant . In the system of Greek numerals, lambda has a value of 30. Lambda is derived from the Phoen ...
(). The decuplet baryons are the four
Deltas
A river delta is a landform, wikt:archetype#Noun, archetypically triangular, created by the deposition (geology), deposition of the sediments that are carried by the waters of a river, where the river merges with a body of slow-moving water or ...
(, , , ), three
Sigmas (, , ), two
Xis (, ), and the
Omega
Omega (, ; uppercase Ω, lowercase ω; Ancient Greek ὦ, later ὦ μέγα, Modern Greek ωμέγα) is the twenty-fourth and last letter in the Greek alphabet. In the Greek numerals, Greek numeric system/isopsephy (gematria), it has a value ...
().
For example, the constituent quark model wavefunction for the proton is
Mixing of baryons, mass splittings within and between multiplets, and magnetic moments are some of the other quantities that the model predicts successfully.
The group theory approach described above assumes that the quarks are eight components of a single particle, so the anti-symmetrization applies to all the quarks. A simpler approach is to consider the eight flavored quarks as eight separate, distinguishable, non-identical particles. Then the anti-symmetrization applies only to two identical quarks (like uu, for instance).
Then, the proton wavefunction can be written in a simpler form:
:
and the
:
If quark–quark interactions are limited to two-body interactions, then all the successful quark model predictions, including sum rules for baryon masses and magnetic moments, can be derived.
Discovery of color
Color quantum numbers are the characteristic charges of the strong force, and are completely uninvolved in electroweak interactions. They were discovered as a consequence of the quark model classification, when it was appreciated that the spin baryon, the , required three up quarks with parallel spins and vanishing orbital angular momentum. Therefore, it could not have an antisymmetric wavefunction, (required by the
Pauli exclusion principle).
Oscar Greenberg noted this problem in 1964, suggesting that quarks should be
para-fermions.
Instead, six months later,
Moo-Young Han and
Yoichiro Nambu
was a Japanese-American physicist and professor at the University of Chicago.
Known for his groundbreaking contributions to theoretical physics, Nambu was the originator of the theory of spontaneous symmetry breaking, a concept that revoluti ...
suggested the existence of a hidden degree of freedom, they labeled as the group SU(3)' (but later called 'color). This led to three triplets of quarks whose wavefunction was anti-symmetric in the color degree of freedom.
Flavor and color were intertwined in that model: they did not commute.
The modern concept of color completely commuting with all other charges and providing the strong force charge was articulated in 1973, by
William Bardeen,
Harald Fritzsch, and
Murray Gell-Mann
Murray Gell-Mann (; September 15, 1929 – May 24, 2019) was an American theoretical physicist who played a preeminent role in the development of the theory of elementary particles. Gell-Mann introduced the concept of quarks as the funda ...
.
States outside the quark model
While the quark model is derivable from the theory of
quantum chromodynamics
In theoretical physics, quantum chromodynamics (QCD) is the study of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type of ...
, the structure of hadrons is more complicated than this model allows. The full
quantum mechanical
Quantum mechanics is the fundamental physical theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is the foundation of a ...
wavefunction
In quantum physics, a wave function (or wavefunction) is a mathematical description of the quantum state of an isolated quantum system. The most common symbols for a wave function are the Greek letters and (lower-case and capital psi (letter) ...
of any hadron must include virtual quark pairs as well as virtual
gluon
A gluon ( ) is a type of Massless particle, massless elementary particle that mediates the strong interaction between quarks, acting as the exchange particle for the interaction. Gluons are massless vector bosons, thereby having a Spin (physi ...
s, and allows for a variety of mixings. There may be hadrons which lie outside the quark model. Among these are the ''
glueballs'' (which contain only valence gluons), ''hybrids'' (which contain valence quarks as well as gluons) and ''
exotic hadrons'' (such as
tetraquarks or
pentaquark
A pentaquark is a human-made subatomic particle, consisting of four quarks and one antiquark bound together; they are not known to occur naturally, or exist outside of experiments specifically carried out to create them.
As quarks have a bar ...
s).
See also
*
Subatomic particles
In physics, a subatomic particle is a particle smaller than an atom. According to the Standard Model of particle physics, a subatomic particle can be either a composite particle, which is composed of other particles (for example, a baryon, like ...
*
Hadron
In particle physics, a hadron is a composite subatomic particle made of two or more quarks held together by the strong nuclear force. Pronounced , the name is derived . They are analogous to molecules, which are held together by the electri ...
s,
baryon
In particle physics, a baryon is a type of composite particle, composite subatomic particle that contains an odd number of valence quarks, conventionally three. proton, Protons and neutron, neutrons are examples of baryons; because baryons are ...
s,
meson
In particle physics, a meson () is a type of hadronic subatomic particle composed of an equal number of quarks and antiquarks, usually one of each, bound together by the strong interaction. Because mesons are composed of quark subparticles, the ...
s and
quark
A quark () is a type of elementary particle and a fundamental constituent of matter. Quarks combine to form composite particles called hadrons, the most stable of which are protons and neutrons, the components of atomic nucleus, atomic nuclei ...
s
*
Exotic hadrons:
exotic meson
In particle physics, exotic mesons are mesons that have quantum numbers not possible in the quark model; some proposals for non-standard quark model mesons could be:
;glueballs or gluonium: Glueballs have no valence quarks at all.
;tetraquarks: ...
s and
exotic baryon
In particle physics, exotic baryons are a type of hadron (bound states of quarks and gluons) with half-integer spin, but with a quark content different from the three quarks (''qqq'') present in conventional baryons. An example would be pentaq ...
s
*
Quantum chromodynamics
In theoretical physics, quantum chromodynamics (QCD) is the study of the strong interaction between quarks mediated by gluons. Quarks are fundamental particles that make up composite hadrons such as the proton, neutron and pion. QCD is a type of ...
,
flavor, the
QCD vacuum
Notes
References
*
*
* Thomson, M A (2011)
Lecture notes*
{{Standard model of physics
Hadrons
Quarks
Particle physics
Concepts in physics
Standard Model
Murray Gell-Mann