Uranous
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Uranous is the
chemical A chemical substance is a unique form of matter with constant chemical composition and characteristic properties. Chemical substances may take the form of a single element or chemical compounds. If two or more chemical substances can be combin ...
term for the
reduced Reduction, reduced, or reduce may refer to: Science and technology Chemistry * Reduction (chemistry), part of a reduction-oxidation (redox) reaction in which atoms have their oxidation state changed. ** Organic redox reaction, a redox reacti ...
tetrapositive
cation An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
of
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
that exhibits the valence U4+. It is one of the two common ionic states of uranium found in nature, the other being the
oxidised Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
hexapositive ion called
uranyl The uranyl ion with the chemical formula has a linear structure with short U–O bonds, indicative of the presence of multiple bonds between uranium and oxygen, with uranium in the oxidation state +6. Four or more ligands may be bound to the u ...
. Uranous compounds are usually unstable; they revert to the oxidised form on exposure to air. Examples of these compounds include salts such as
uranium tetrachloride Uranium tetrachloride is an inorganic compound, a salt of uranium and chlorine, with the formula UCl4. It is a hygroscopic olive-green solid. It was used in the electromagnetic isotope separation (EMIS) process of uranium enrichment. It is one ...
() and
uranium tetrafluoride Uranium tetrafluoride is the inorganic compound with the formula UF4. It is a green solid with an insignificant vapor pressure and low solubility in water. Uranium in its tetravalent ( uranous) state is important in various technological process ...
(), which are important in
molten salt reactor A molten-salt reactor (MSR) is a class of nuclear fission reactor in which the primary nuclear reactor coolant and/or the fuel is a mixture of molten salt with a fissile material. Two research MSRs operated in the United States in the mid-20th ...
applications, and
uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reac ...
(), a common form of
nuclear fuel Nuclear fuel refers to any substance, typically fissile material, which is used by nuclear power stations or other atomic nucleus, nuclear devices to generate energy. Oxide fuel For fission reactors, the fuel (typically based on uranium) is ...
. The solvated ion is normally not present in water. Most of the compounds like are better described with the
covalent bond A covalent bond is a chemical bond that involves the sharing of electrons to form electron pairs between atoms. These electron pairs are known as shared pairs or bonding pairs. The stable balance of attractive and repulsive forces between atom ...
than an
ionic bond Ionic bonding is a type of chemical bond A chemical bond is the association of atoms or ions to form molecules, crystals, and other structures. The bond may result from the electrostatic force between oppositely charged ions as in ionic ...
. Minerals containing the uranous
ion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...
are more subdued in colour, typically brown or black, and occur in reducing environments. Common uranous minerals include
uraninite Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium c ...
and
coffinite Coffinite is a uranium-bearing silicate mineral with formula: U(SiO4)1−x(OH)4x. It occurs as black incrustations, dark to pale-brown in thin section. It has a grayish-black streak. It has a brittle to conchoidal fracture. The hardness of coffin ...
.


References

{{Uranium compounds Cations Uranium(IV) compounds Uranium compounds