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Uranium ore deposits are economically recoverable concentrations of
uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
within
Earth's crust Earth's crust is its thick outer shell of rock, referring to less than one percent of the planet's radius and volume. It is the top component of the lithosphere, a solidified division of Earth's layers that includes the crust and the upper ...
. Uranium is one of the most common elements in Earth's crust, being 40 times more common than
silver Silver is a chemical element; it has Symbol (chemistry), symbol Ag () and atomic number 47. A soft, whitish-gray, lustrous transition metal, it exhibits the highest electrical conductivity, thermal conductivity, and reflectivity of any metal. ...
and 500 times more common than
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
. It can be found almost everywhere in rock, soil, rivers, and oceans. The challenge for commercial uranium extraction is to find those areas where the concentrations are adequate to form an economically viable deposit. The primary use for uranium obtained from mining is in fuel for
nuclear reactors A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction. They are used for commercial electricity, marine propulsion, weapons production and research. Fissile nuclei (primarily uranium-235 or plutonium-2 ...
. Globally, the distribution of uranium ore deposits is widespread on all continents, with the largest deposits found in Australia,
Kazakhstan Kazakhstan, officially the Republic of Kazakhstan, is a landlocked country primarily in Central Asia, with a European Kazakhstan, small portion in Eastern Europe. It borders Russia to the Kazakhstan–Russia border, north and west, China to th ...
, and Canada. To date, high-grade deposits are only found in the
Athabasca Basin The Athabasca Basin is a region in the Canadian Shield of northern Saskatchewan and Alberta, Canada. It is best known as the world's leading source of high-grade uranium and currently supplies about 20% of the world's uranium. The basin i ...
region of Canada. Uranium deposits are generally classified based on host rocks, structural setting, and mineralogy of the deposit. The most widely used classification scheme was developed by the
International Atomic Energy Agency The International Atomic Energy Agency (IAEA) is an intergovernmental organization that seeks to promote the peaceful use of nuclear technology, nuclear energy and to inhibit its use for any military purpose, including nuclear weapons. It was ...
and subdivides deposits into 15 categories. __TOC__


Uranium

Uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...
is a silvery-gray, weakly
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
metal A metal () is a material that, when polished or fractured, shows a lustrous appearance, and conducts electrical resistivity and conductivity, electricity and thermal conductivity, heat relatively well. These properties are all associated wit ...
lic
chemical element A chemical element is a chemical substance whose atoms all have the same number of protons. The number of protons is called the atomic number of that element. For example, oxygen has an atomic number of 8: each oxygen atom has 8 protons in its ...
. It has the
chemical symbol Chemical symbols are the abbreviations used in chemistry, mainly for chemical elements; but also for functional groups, chemical compounds, and other entities. Element symbols for chemical elements, also known as atomic symbols, normally consist ...
U and
atomic number The atomic number or nuclear charge number (symbol ''Z'') of a chemical element is the charge number of its atomic nucleus. For ordinary nuclei composed of protons and neutrons, this is equal to the proton number (''n''p) or the number of pro ...
92. The most common
isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s in
natural uranium Natural uranium (NU or Unat) is uranium with the same isotopic ratio as found in nature. It contains 0.711% uranium-235, 99.284% uranium-238, and a trace of uranium-234 by weight (0.0055%). Approximately 2.2% of its radioactivity comes from ura ...
are 238U (99.274%) and 235U (0.711%). All uranium isotopes present in natural uranium are
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
and fissionable, and 235U is
fissile In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal Nuclear chain reaction#Fission chain reaction, chain reaction can only be achieved with fissil ...
(will support a neutron-mediated chain reaction). Uranium,
thorium Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and ha ...
, and one radioactive isotope of
potassium Potassium is a chemical element; it has Symbol (chemistry), symbol K (from Neo-Latin ) and atomic number19. It is a silvery white metal that is soft enough to easily cut with a knife. Potassium metal reacts rapidly with atmospheric oxygen to ...
() as well as their decay products are the main elements contributing to natural terrestrial radioactivity. Cosmogenic radionuclides are of less importance, but unlike the aforementioned
primordial radionuclide In geochemistry, geophysics and nuclear physics, primordial nuclides, also known as primordial isotopes, are nuclides found on Earth that have existed in their current form since before Earth was formed. Primordial nuclides were present in the ...
s, which date back to the formation of the planet and have since slowly decayed away, they are replenished at roughly the same rate they decay by the bombardment of Earth with
cosmic rays Cosmic rays or astroparticles are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar ...
. Uranium has the highest
atomic weight Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a giv ...
of the naturally occurring elements and is approximately 70% denser than
lead Lead () is a chemical element; it has Chemical symbol, symbol Pb (from Latin ) and atomic number 82. It is a Heavy metal (elements), heavy metal that is density, denser than most common materials. Lead is Mohs scale, soft and Ductility, malleabl ...
, but it is not as dense as
tungsten Tungsten (also called wolfram) is a chemical element; it has symbol W and atomic number 74. It is a metal found naturally on Earth almost exclusively in compounds with other elements. It was identified as a distinct element in 1781 and first ...
,
gold Gold is a chemical element; it has chemical symbol Au (from Latin ) and atomic number 79. In its pure form, it is a brightness, bright, slightly orange-yellow, dense, soft, malleable, and ductile metal. Chemically, gold is a transition metal ...
,
platinum Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...
,
iridium Iridium is a chemical element; it has the symbol Ir and atomic number 77. This very hard, brittle, silvery-white transition metal of the platinum group, is considered the second-densest naturally occurring metal (after osmium) with a density ...
, or
osmium Osmium () is a chemical element; it has Symbol (chemistry), symbol Os and atomic number 76. It is a hard, brittle, bluish-white transition metal in the platinum group that is found as a Abundance of elements in Earth's crust, trace element in a ...
. It is always found combined with other elements. Along with all elements having atomic weights higher than that of
iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
, it is only naturally formed in
supernova A supernova (: supernovae or supernovas) is a powerful and luminous explosion of a star. A supernova occurs during the last stellar evolution, evolutionary stages of a massive star, or when a white dwarf is triggered into runaway nuclear fusion ...
explosions.


Uranium minerals

The primary uranium ore
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid substance with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2011): Mi ...
is
uraninite Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium c ...
(UO2) (previously known as pitchblende). A range of other uranium minerals can be found in various deposits. These include carnotite, tyuyamunite,
torbernite Torbernite, also known as chalcolite, is a relatively common mineral with the chemical formula Cu UO2)(PO4)sub>2(H2O)12. It is a radioactive, hydrated green copper uranyl phosphate, found in granites and other uranium-bearing deposits as a s ...
and autunite.Klein, Cornelis and Cornelius S. Hurlbut, Jr., ''Manual of Mineralogy,'' Wiley, 1985, 20th ed. pp. 307–308 The davidite- brannerite- absite type uranium titanates, and the euxenite- fergusonite- samarskite group are other uranium minerals. A large variety of secondary uranium minerals are known, many of which are brilliantly coloured and fluorescent. The most common are gummite (a mixture of minerals), autunite (with
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
), saleeite (
magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...
) and
torbernite Torbernite, also known as chalcolite, is a relatively common mineral with the chemical formula Cu UO2)(PO4)sub>2(H2O)12. It is a radioactive, hydrated green copper uranyl phosphate, found in granites and other uranium-bearing deposits as a s ...
(with
copper Copper is a chemical element; it has symbol Cu (from Latin ) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orang ...
); and hydrated uranium silicates such as coffinite, uranophane (with calcium) and
sklodowskite Sklodowskite is a uranium mineral with the chemical formula: Mg(UO2)2(HSiO4)2·5H2O. It is a secondary mineral which contains magnesium and is a bright yellow colour, its crystal habit is acicular, but can form in other shapes. It has a Mohs h ...
(magnesium).


Ore genesis

There are several themes of uranium ore deposit formation, which are caused by geological and chemical features of rocks and the element uranium. The basic themes of uranium
ore genesis Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: sour ...
are host mineralogy, reduction-oxidation potential, and
porosity Porosity or void fraction is a measure of the void (i.e. "empty") spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure ...
. Uranium is a highly soluble and radioactive heavy metal. It can be easily dissolved, transported and precipitated within
groundwater Groundwater is the water present beneath Earth's surface in rock and Pore space in soil, soil pore spaces and in the fractures of stratum, rock formations. About 30 percent of all readily available fresh water in the world is groundwater. A unit ...
by subtle changes in oxidation conditions. Uranium does not usually form very insoluble mineral species, which is a further factor in the wide variety of geological conditions and places in which uranium mineralization may accumulate. Uranium is an incompatible element within
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma (sometimes colloquially but incorrectly referred to as ''lava'') is found beneath the surface of the Earth, and evidence of magmatism has also ...
s, and as such it tends to become accumulated within highly fractionated and evolved
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
melts, particularly alkaline examples. These melts tend to become highly enriched in uranium, thorium and potassium, and may in turn create internal
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
s or hydrothermal systems into which uranium may dissolve. While it was previously assumed that biological processes played little to no role in the formation of uranium ores, more recent research posits that some ore-bodies may have been significantly influenced by metal-reducing microorganisms such as Geobacter metallireducens, Geobacter uraniireducens or Shewanella oneidensis. These species are capable of using uranium-species as a terminal
electron acceptor An electron acceptor is a chemical entity that accepts electrons transferred to it from another compound. Electron acceptors are oxidizing agents. The electron accepting power of an electron acceptor is measured by its redox potential. In the ...
.


Classification schemes


IAEA Classification (1996)

The
International Atomic Energy Agency The International Atomic Energy Agency (IAEA) is an intergovernmental organization that seeks to promote the peaceful use of nuclear technology, nuclear energy and to inhibit its use for any military purpose, including nuclear weapons. It was ...
(IAEA) assigns uranium deposits to 15 main categories of deposit types, according to their geological setting and genesis of mineralization, arranged according to their approximate economic significance. # Unconformity-related deposits # Sandstone deposits # Quartz-pebble conglomerate deposits # Breccia complex deposits # Vein deposits # Intrusive deposits (Alaskites) # Phosphorite deposits # Collapse breccia pipe deposits # Volcanic deposits # Surficial deposits # Metasomatite deposits # Metamorphic deposits #
Lignite Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered the lowest ...
# Black shale deposits # Other types of deposits


Alternate scheme

The IAEA classification scheme works well but is far from ideal, as it does not consider that similar processes may form many deposit types, yet in a different geological setting. The following table groups the above deposit types based on their environment of deposition.


Deposit types (IAEA Classification)


Unconformity-related deposits

Unconformity-type uranium deposits host high grades relative to other uranium deposits and include some of the largest and richest deposits known. They occur in close proximity to unconformities between relatively
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
-rich
sandstone Sandstone is a Clastic rock#Sedimentary clastic rocks, clastic sedimentary rock composed mainly of grain size, sand-sized (0.0625 to 2 mm) silicate mineral, silicate grains, Cementation (geology), cemented together by another mineral. Sand ...
s comprising the basal portion of relatively undeformed
sedimentary basin Sedimentary basins are region-scale depressions of the Earth's crust where subsidence has occurred and a thick sequence of sediments have accumulated to form a large three-dimensional body of sedimentary rock They form when long-term subsidence ...
s and deformed
metamorphic Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causi ...
basement rocks. These sedimentary basins are typically of
Proterozoic The Proterozoic ( ) is the third of the four geologic eons of Earth's history, spanning the time interval from 2500 to 538.8 Mya, and is the longest eon of Earth's geologic time scale. It is preceded by the Archean and followed by the Phanerozo ...
age, however some
Phanerozoic The Phanerozoic is the current and the latest of the four eon (geology), geologic eons in the Earth's geologic time scale, covering the time period from 538.8 million years ago to the present. It is the eon during which abundant animal and ...
examples exist. Phanerozoic unconformity-related deposits occur in Proterozoic metasediments below an unconformity at the base of overlying Phanerozoic sandstone. These deposits are small and low-grade (e.g., Bertholene and
Aveyron Aveyron (; ) is a Departments of France, department in the Regions of France, region of Occitania (administrative region), Occitania, Southern France. It was named after the river Aveyron (river), Aveyron. Its inhabitants are known as ''Aveyro ...
deposits in France).


Athabasca Basin

The highest grade uranium deposits are found in the
Athabasca Basin The Athabasca Basin is a region in the Canadian Shield of northern Saskatchewan and Alberta, Canada. It is best known as the world's leading source of high-grade uranium and currently supplies about 20% of the world's uranium. The basin i ...
in Canada, including the two largest high grade uranium deposits in the world, Cigar Lake with 217 million pounds (99,000 t) U3O8 at an average grade of 18% and
McArthur River The McArthur River is a river in the Northern Territory of Australia which flows into the Gulf of Carpentaria at Port McArthur, opposite the Sir Edward Pellew Group of Islands. The river was named by Ludwig Leichhardt while he explored the a ...
with 324 million pounds (147,000 t) U3O8 at an average grade of 17%. These deposits occur below, across and immediately above the unconformity. Additionally, another high grade discovery is in the development stage at Patterson Lake (Triple R deposit) with an estimated mineral resource identified as; "Indicated Mineral Resources" estimated to total 2,291,000 tons at an average grade of 1.58% U3O8 containing of U3O8. "Inferred Mineral Resources" are estimated to total 901,000 tons at an average grade of 1.30% U3O8 containing of U3O8.


McArthur Basin

The deposits of the McArthur River basin in the East Alligator Rivers region of the
Northern Territory The Northern Territory (abbreviated as NT; known formally as the Northern Territory of Australia and informally as the Territory) is an states and territories of Australia, Australian internal territory in the central and central-northern regi ...
of Australia (including Jabiluka, Ranger, and Nabarlek) are below the unconformity and are at the low-grade end of the unconformity deposit range but are still high grade compared to most uranium deposit types. There has been very little exploration in Australia to locate deeply concealed deposits lying above the unconformity similar to those in Canada. It is possible that very high grade deposits occur in the sandstones above the unconformity in the Alligator Rivers/
Arnhem Land Arnhem Land is a historical region of the Northern Territory of Australia. It is located in the north-eastern corner of the territory and is around from the territorial capital, Darwin, Northern Territory, Darwin. In 1623, Dutch East India Compa ...
area.


Sandstone deposits

Sandstone deposits are contained within medium to coarse-grained sandstones deposited in a continental fluvial or marginal marine sedimentary environment. Impermeable
shale Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of Clay mineral, clay minerals (hydrous aluminium phyllosilicates, e.g., Kaolinite, kaolin, aluminium, Al2Silicon, Si2Oxygen, O5(hydroxide, OH)4) and tiny f ...
or
mudstone Mudstone, a type of mudrock, is a fine-grained sedimentary rock whose original constituents were clays or muds. Mudstone is distinguished from ''shale'' by its lack of fissility.Blatt, H., and R.J. Tracy, 1996, ''Petrology.'' New York, New York, ...
units are interbedded in the sedimentary sequence and often occur immediately above and below the mineralised horizon. Uranium is mobile under oxidising conditions and precipitates under reducing conditions, and thus the presence of a reducing environment is essential for the formation of uranium deposits in sandstone. Primary mineralization consists of pitchblende and coffinite, with
weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...
producing secondary mineralization. Sandstone deposits constitute about 18% of world uranium resources. Orebodies of this type are commonly low to medium grade (0.05–0.4% U3O8) and individual orebodies are small to medium in size (ranging up to a maximum of 50,000 t U3O8). Sandstone hosted uranium deposits are widespread globally and span a broad range of host rock ages. Some of the major provinces and production centers include: # Wyoming basins # Grants District of New Mexico # Central Europe # Kazakhstan Significant potential remains in most of these centers as well as in Australia, Mongolia, South America, and Africa. This model type can be further subdivided into the following sub-types: * tabular * roll front * basal channel * structurally related Many deposits represent combinations of these types.


Tabular

Tabular deposits consist of irregular tabular or elongate lenticular zones of uranium mineralisation within selectively reduced sediments. The mineralised zones are oriented parallel to the direction of groundwater flow, but on a small scale the ore zones may cut across sedimentary features of the host sandstone. Deposits of this nature commonly occur within palaeochannels cut in the underlying basement rocks. Tabular sandstone uranium deposits contain many of the highest grades of the sandstone class, however the average deposit size is very small.


Roll front

Roll-front uranium deposits are generally hosted within permeable and porous sandstones or conglomerates. The mechanism for deposit formation is dissolution of uranium from the formation or nearby
strata In geology and related fields, a stratum (: strata) is a layer of Rock (geology), rock or sediment characterized by certain Lithology, lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by v ...
and the transport of this soluble uranium into the host unit. When the fluids change
redox Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is t ...
state, generally in contact with
carbon Carbon () is a chemical element; it has chemical symbol, symbol C and atomic number 6. It is nonmetallic and tetravalence, tetravalent—meaning that its atoms are able to form up to four covalent bonds due to its valence shell exhibiting 4 ...
-rich organic matter, uranium precipitates to form a 'front'. The roll front subtype deposits typically represent the largest of the sandstone-hosted uranium deposits and one of the largest uranium deposit types with an average of 21 million lb (9,500 t) U3O8. Included in this class are the Inkai deposit in Kazakhstan and the Smith Ranch deposit in Wyoming. Probably more significant than their larger size, roll front deposits have the advantage of being amenable to low cost
in situ leach In-situ leaching (ISL), also called in-situ recovery (ISR) or solution mining, is a mining process used to recover minerals such as copper and uranium through boreholes drilled into a deposit, '' in situ''. In-situ leach works by artificially di ...
recovery. Typical characteristics: *roll-front deposits are crescent-shaped bodies that transect the host
lithology The lithology of a rock unit is a description of its physical characteristics visible at outcrop, in hand or core samples, or with low magnification microscopy. Physical characteristics include colour, texture, grain size, and composition. Lit ...
*typically the convex side points down the hydraulic gradient. *the limbs or tails tend to be peneconcordant with the lithology. *most ore-bodies consist of several interconnected rolls. *individual roll-front deposits are quite small but collectively can extend for considerable distances.


Basal channel (palaeochannel)

Basal channel deposits are often grouped with tabular or roll front deposits, depending on their unique characteristics. The model for formation of palaeochannel deposits is similar to that for roll front deposits except that the source of uranium may be in the watershed leading into a stream or in the
bed load The term bed load or bedload describes particles in a flowing fluid (usually water) that are transported along the stream bed. Bed load is complementary to suspended load and wash load. Bed load moves by rolling, sliding, and/or Saltation (geolo ...
of the palaeochannel. This uranium is transported through groundwater and is deposited either at a reduced boundary or in ephemeral drainage systems such as those in deserts of Namibia and Australia; it is deposited in calcretised evaporation sites or even in saline lakes as the water evaporates. Some particularly rich uranium deposits are formed in palaeochannels which are filled in the lower parts by
lignite Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered the lowest ...
or brown
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal i ...
, which acts as a particularly efficient reductive trap for uranium. Sometimes, elements such as
scandium Scandium is a chemical element; it has Symbol (chemistry), symbol Sc and atomic number 21. It is a silvery-white metallic d-block, d-block element. Historically, it has been classified as a rare-earth element, together with yttrium and the lantha ...
, gold and silver may be concentrated within these lignite-hosted uranium deposits. The Frome Embayment in
South Australia South Australia (commonly abbreviated as SA) is a States and territories of Australia, state in the southern central part of Australia. With a total land area of , it is the fourth-largest of Australia's states and territories by area, which in ...
hosts several deposits of this type including
Honeymoon A honeymoon is a vacation taken by newlyweds after their wedding to celebrate their marriage. Today, honeymoons are often celebrated in destinations considered exotic or romantic. In a similar context, it may also refer to the phase in a couple ...
, Oban, Beverley and Four-Mile (which is the largest deposit of this class). These deposits are hosted in palaeochannels filled with
Cenozoic The Cenozoic Era ( ; ) is Earth's current geological era, representing the last 66million years of Earth's history. It is characterized by the dominance of mammals, insects, birds and angiosperms (flowering plants). It is the latest of three g ...
sediments and sourced their uranium from uranium-rich
Paleoproterozoic The Paleoproterozoic Era (also spelled Palaeoproterozoic) is the first of the three sub-divisions ( eras) of the Proterozoic eon, and also the longest era of the Earth's geological history, spanning from (2.5–1.6  Ga). It is further sub ...
to
Mesoproterozoic The Mesoproterozoic Era is a geologic era that occurred from . The Mesoproterozoic was the first era of Earth's history for which a fairly definitive geological record survives. Continents existed during the preceding era (the Paleoproterozoic ...
rocks of the Mount Painter Inlier and the Olary Domain of the Curnamona Province.


Structurally related

Tectonic-lithologic controlled uranium deposits occur in sandstones adjacent to a permeable fault zone which cuts the sandstone/mudstone sequence. Mineralisation forms tongue-shaped ore zones along the permeable sandstone layers adjacent to the fault. Often there are mineralised zones 'stacked' vertically on top of each other within sandstone units adjacent to the fault zone.


Quartz conglomerate deposits

Quartz pebble conglomerate hosted uranium deposits are of historical significance as the major source of primary production for several decades after
World War II World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
. This type of deposit has been identified in eight localities around the world. The most significant deposits are in the Huronian Supergroup in
Elliot Lake Elliot Lake is a city in Algoma District, Ontario, Canada. It is north of Lake Huron, midway between the cities of Greater Sudbury, Sudbury and Sault Ste. Marie, Ontario, Sault Ste. Marie in the Northern Ontario region. Once dubbed the "uranium ca ...
,
Ontario Ontario is the southernmost Provinces and territories of Canada, province of Canada. Located in Central Canada, Ontario is the Population of Canada by province and territory, country's most populous province. As of the 2021 Canadian census, it ...
, Canada and in the Witwatersrand Supergroup of
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
. These deposits make up approximately 13% of the world's uranium resources. Quartz pebble conglomerate hosted uranium deposits formed from the transport and deposition of uraninite in a fluvial sedimentary environment and are defined as stratiform and stratabound
placer deposit In geology, a placer deposit or placer is an accumulation of valuable minerals formed by gravity separation from a specific source rock during sedimentary processes. The name is from the Spanish language, Spanish word ''placer'', meaning "alluviu ...
s. Host rocks are typically submature to supermature, polymictic conglomerates and sandstones deposited in
alluvial fan An alluvial fan is an accumulation of sediments that fans outwards from a concentrated source of sediments, such as a narrow canyon emerging from an escarpment. They are characteristic of mountainous terrain in arid to Semi-arid climate, semiar ...
and braided stream environments. The host conglomerates of the Huronian deposits are situated at the base of the sequence, whereas the mineralized horizons at Witwatersand are arguably along tectonized intraformational unconformities. Uranium minerals were derived from uraniferous pegmatites in the sediment source areas. These deposits are restricted to the
Archean The Archean ( , also spelled Archaean or Archæan), in older sources sometimes called the Archaeozoic, is the second of the four geologic eons of Earth's history of Earth, history, preceded by the Hadean Eon and followed by the Proterozoic and t ...
and early Paleoproterozoic and do not occur in sediments younger than about 2,200 million years when oxygen levels in the atmosphere reached a critical level, making simple uranium oxides no longer stable in near-surface environments. Quartz pebble conglomerate uranium deposits are typically low grade but characterized by high tonnages. The Huronian deposits generally contain higher grades (0.15% U3O8) and greater resources (as shown by the Denison and Quirke mines), however some of the Witwatersand gold deposits also contain sizeable low grade (0.01% U3O8) uranium resources.


Witwatersrand

In the Witwatersrand deposits, ores are found along unconformities, shale and siltstone beds, and carbonaceous seams. The West Rand Group of sediments tend to host the most uranium within the Witwatersrand Supergroup. The uranium rich Dominion Reef is located at the base of the West Rand Supergroup. The Vaal Reef is the most uranium rich reef of the Central Rand Group of sediments. Structural controls on the regional scale are normal faults while on the deposit scale are bedding parallel shears and thrusts. Textural evidence indicates that the uranium and gold have been remobilized to their current sites; however the debate continues if the original deposition was detrital or was entirely hydrothermal, or alternatively related to high grade
diagenesis Diagenesis () is the process of physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a role as sedi ...
. Uranium minerals are typically uraninite with lesser uranothorite, brannerite, and coffinite. The uranium is especially concentrated along thin carbonaceous seams or carbon leaders. Strong regional scale alteration consists of pyrophyllite, chloritoid,
muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula KAl2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavage y ...
,
chlorite The chlorite ion, or chlorine dioxide anion, is the halite (oxyanion), halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as s ...
, quartz,
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at vis ...
, and
pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...
. The main elements associated with the uranium are gold and silver. Gold contents are much higher than in the Elliot Lake type with U:Au ranging between 5:1 and 500:1, which indicates that these gold-rich ores are essentially very low grade uranium deposits with gold.


Elliot Lake

Sedimentological controls on the Huronian deposits appear to be much stronger than in the Witwatersrand deposits. Ores grade from uranium through
thorium Thorium is a chemical element; it has symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive grey when it is exposed to air, forming thorium dioxide; it is moderately soft, malleable, and ha ...
to
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
-rich with decreasing pebble size and increasing distance from their source. While evidence of post- diagenetic remobilization has been identified, these effects appear far subordinate to the sedimentological controls. Ore consists of uraninite with lesser brannerite and thucholite. These occur in thin beds exhibiting graded bedding reminiscent of placer sorting. Alteration is nonexistent to very weak at best, and the weak chlorite and
sericite Sericite is the name given to very fine, ragged grains and Aggregate (geology), aggregates of white (colourless) micas, typically made of muscovite, illite, or paragonite. Sericite is produced by the alteration of orthoclase or plagioclase feldsp ...
are believed to be mainly post-ore effects. Other post-depositional alteration includes pyritization, silicification, and alteration of titanium minerals. The most prominent geochemical associations with the uranium are thorium and titanium. This schematic model represents the original depositional setting. The Huronian underwent mild post-depositional folding during the Penokean orogeny around 1.9 billion years. The main regional structure is the Quirke syncline along the margins of which the majority of the known deposits are situated. Ore bodies range from subhorizontal to steeply dipping.


Breccia complex deposits

Only one iron oxide copper gold ore deposit is known to contain economically significant quantities of uranium. Olympic Dam in South Australia is the world's largest resource of low-grade uranium and accounts for about 66% of Australia's reserves plus resources. Uranium occurs with copper, gold, silver, and rare-earth elements in a large
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
-rich granite
breccia Breccia ( , ; ) is a rock composed of large angular broken fragments of minerals or Rock (geology), rocks cementation (geology), cemented together by a fine-grained matrix (geology), matrix. The word has its origins in the Italian language ...
complex in the Gawler craton overlain by approximately 300 metres of flat-lying sedimentary rocks of the Stuart Shelf geological province. Another example for the breccia type is the Mount Gee area in the Mount Painter Inlier, South Australia. Uranium mineralised quartz-hematite breccia is related to Palaeoproterozoic granites with uranium contents of up to 100 ppm. Hydrothermal processes at about 300 million years ago remobilised uranium from these granites and enriched them in the quartz-hematite breccias. The breccias in the area host a low grade resource of about 31,400 t U3O8 at 615 ppm in average.


Vein deposits

Vein Veins () are blood vessels in the circulatory system of humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are those of the pulmonary and feta ...
deposits play a special role in the history of uranium: the term "pitchblende" ("''pechblende''") originates from German vein deposits when they were mined for silver in the 16th century. Franz Ernst Brückmann made the first mineralogical description of the mineral in 1727, and the vein deposit
Jáchymov Jáchymov (; or ''Joachimsthal'') is a spa town in Karlovy Vary District in the Karlovy Vary Region of the Czech Republic. It has about 2,300 inhabitants. Jáchymov has a long mining tradition, thanks to which it used to be the second most popu ...
in the
Czech Republic The Czech Republic, also known as Czechia, and historically known as Bohemia, is a landlocked country in Central Europe. The country is bordered by Austria to the south, Germany to the west, Poland to the northeast, and Slovakia to the south ...
became the type locality for uraninite. In 1789 German chemist
Martin Heinrich Klaproth Martin Heinrich Klaproth (1 December 1743 – 1 January 1817) was a German chemist. He trained and worked for much of his life as an apothecary, moving in later life to the university. His shop became the second-largest apothecary in Berlin, and ...
discovered the element uranium in a sample of pitchblende from the Johanngeorgenstadt vein deposit. The first industrial production of uranium was made from the Jáchymov deposit, and Marie and
Pierre Curie Pierre Curie ( ; ; 15 May 1859 – 19 April 1906) was a French physicist, Radiochemistry, radiochemist, and a pioneer in crystallography, magnetism, piezoelectricity, and radioactivity. He shared the 1903 Nobel Prize in Physics with his wife, ...
used the
tailings In mining, tailings or tails are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different from overburden, which is the waste rock or other material ...
of the mine for their discovery of
polonium Polonium is a chemical element; it has symbol Po and atomic number 84. A rare and highly radioactive metal (although sometimes classified as a metalloid) with no stable isotopes, polonium is a chalcogen and chemically similar to selenium and tel ...
and
radium Radium is a chemical element; it has chemical symbol, symbol Ra and atomic number 88. It is the sixth element in alkaline earth metal, group 2 of the periodic table, also known as the alkaline earth metals. Pure radium is silvery-white, ...
. Vein deposits consist of uranium minerals filling in cavities such as cracks, veins, fractures, breccias, and stockworks associated with steeply dipping fault systems. There are three major subtypes of vein style uranium mineralisation: *intragranitic veins (Central Massif, France) *veins in metasedimentary rocks in exocontacts of granites **quartz-carbonate uranium veins (
Ore Mountains The Ore Mountains (, or ; ) lie along the Czech–German border, separating the historical regions of Bohemia in the Czech Republic and Saxony in Germany. The highest peaks are the Klínovec in the Czech Republic (German: ''Keilberg'') at ab ...
, Germany/Czech Republic;
Bohemian Massif The Bohemian Massif ( or ''Český masiv'', or ''Böhmisches Massiv'') is a geomorphological province in Central Europe. It is a large massif stretching over most of the Czech Republic, eastern Germany, southern Poland and northern Austria. Th ...
, Czech Republic) **uranium-polymetal veins (Ore Mountains; Saskatchewan) *mineralised fault and shear zones (Central Africa; Bohemian Massif) Intragranitic veins form in the late phase of magmatic activity when hot fluids derived from the magma precipitate uranium on cracks within the newly formed granite. Such mineralisation contributed much to the uranium production of France. Veins hosted by metasedimentary units in the exocontact of granites are the most important sources of uranium mineralisation in central Europe including the world class deposits Schneeberg-Schlema-Alberoda in Germany (96,000 t uranium content) as well as Příbram (50,000 t uranium content) and
Jáchymov Jáchymov (; or ''Joachimsthal'') is a spa town in Karlovy Vary District in the Karlovy Vary Region of the Czech Republic. It has about 2,300 inhabitants. Jáchymov has a long mining tradition, thanks to which it used to be the second most popu ...
(~10,000 t uranium content) in the Czech Republic. Also they are closely related to the granites, the mineralization is much younger with a time gap between granite formation and mineralisation of 20 million years. The initial uranium mineralisation consists of quartz,
carbonate A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
,
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
and pitchblende. Remobilisation of uranium occurred at later stages producing polymetal veins containing silver,
cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...
,
nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...
,
arsenic Arsenic is a chemical element; it has Symbol (chemistry), symbol As and atomic number 33. It is a metalloid and one of the pnictogens, and therefore shares many properties with its group 15 neighbors phosphorus and antimony. Arsenic is not ...
and other elements. Large deposits of this type can contain more than 1,000 individual mineralized veins. However, only 5 to 12% of the vein areas carry mineralization and although massive lenses of pitchblende can occur, the overall ore grade is only about 0.1% uranium. The Bohemian Massif contains shear zone hosted uranium deposits with the most important one being Rozna-Olsi in Moravia northwest of
Brno Brno ( , ; ) is a Statutory city (Czech Republic), city in the South Moravian Region of the Czech Republic. Located at the confluence of the Svitava (river), Svitava and Svratka (river), Svratka rivers, Brno has about 403,000 inhabitants, making ...
. Rozna is currently the only operating uranium mine in central Europe with a total uranium content of 23,000 t and an average grade of 0.24%. The formation of this mineralisation occurred in several stages. After the Variscan orogeny, extension took place and hydrothermal fluids overprinted fine grained materials in shear zones with a sulfide-chlorite alteration. Fluids from the overlying sediments entered the basement mobilising uranium and while uprising on the shear zone, the chlorite-pyrite material caused precipitation of uranium minerals in form of coffinite, pitchblende and U-Zr-silicates. This initial mineralisation event took place at about 277 million to 264 million years. During the Triassic a further mineralisation event took place relocating uranium into quartz-carbonate-uranium veins. Another example of this mineralisation style is the
Shinkolobwe Shinkolobwe, or Kasolo, or Chinkolobew, or Shainkolobwe, was a radium and uranium mine in the Haut-Katanga Province of the Democratic Republic of the Congo (DRC), located west of Likasi (formerly Jadotville), south of Kambove, and about northwe ...
deposit in Congo containing about 30,000 t of uranium.


Intrusive associated deposits

Intrusive deposits make up a large proportion of the world's uranium resources. Included in this type are those associated with intrusive rocks including alaskite,
granite Granite ( ) is a coarse-grained (phanerite, phaneritic) intrusive rock, intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly coo ...
,
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic c ...
and
monzonite Monzonite is an igneous intrusive rock, formed by slow cooling of underground magma that has a moderate silica content and is enriched in alkali metal oxides. Monzonite is composed mostly of plagioclase and alkali feldspar. Syenodiorite is an ...
s. Major world deposits include Rossing (
Namibia Namibia, officially the Republic of Namibia, is a country on the west coast of Southern Africa. Its borders include the Atlantic Ocean to the west, Angola and Zambia to the north, Botswana to the east and South Africa to the south; in the no ...
), Ilimaussaq intrusive complex (
Greenland Greenland is an autonomous territory in the Danish Realm, Kingdom of Denmark. It is by far the largest geographically of three constituent parts of the kingdom; the other two are metropolitan Denmark and the Faroe Islands. Citizens of Greenlan ...
) and Palabora (
South Africa South Africa, officially the Republic of South Africa (RSA), is the Southern Africa, southernmost country in Africa. Its Provinces of South Africa, nine provinces are bounded to the south by of coastline that stretches along the Atlantic O ...
).


Phosphorite deposits

Marine sedimentary
phosphorite Phosphorite, phosphate rock or rock phosphate is a non-detrital sedimentary rock that contains high amounts of phosphate minerals. The phosphate content of phosphorite (or grade of phosphate rock) varies greatly, from 4% to 20% phosphorus pentoxi ...
deposits can contain low grade concentrations of uranium, up to 0.01–0.015% U3O8, within
fluorite Fluorite (also called fluorspar) is the mineral form of calcium fluoride, CaF2. It belongs to the halide minerals. It crystallizes in isometric cubic habit, although octahedral and more complex isometric forms are not uncommon. The Mohs scal ...
or
apatite Apatite is a group of phosphate minerals, usually hydroxyapatite, fluorapatite and chlorapatite, with high concentrations of Hydroxide, OH−, Fluoride, F− and Chloride, Cl− ion, respectively, in the crystal. The formula of the admixture of ...
. These deposits can have a significant tonnage. Very large phosphorite deposits occur in
Florida Florida ( ; ) is a U.S. state, state in the Southeastern United States, Southeastern region of the United States. It borders the Gulf of Mexico to the west, Alabama to the northwest, Georgia (U.S. state), Georgia to the north, the Atlantic ...
,
Idaho Idaho ( ) is a landlocked U.S. state, state in the Pacific Northwest and Mountain states, Mountain West subregions of the Western United States. It borders Montana and Wyoming to the east, Nevada and Utah to the south, and Washington (state), ...
,
Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...
, and some middle eastern countries.


Collapse breccia pipe deposits

Collapse breccia pipe deposits occur within vertical, circular solution collapse structures, formed by the dissolution of
limestone Limestone is a type of carbonate rock, carbonate sedimentary rock which is the main source of the material Lime (material), lime. It is composed mostly of the minerals calcite and aragonite, which are different Polymorphism (materials science) ...
by groundwater. Pipes are typically filled with down-dropped coarse fragments of limestone and overlying sediments and can be from wide and up to deep. Primary ore minerals are
uraninite Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the uranium c ...
and
pitchblende Uraninite, also known as pitchblende, is a radioactive, uranium-rich mineral and ore with a chemical composition that is largely UO2 but because of oxidation typically contains variable proportions of U3O8. Radioactive decay of the urani ...
, which occur as cavity fills and coatings on
quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
grains within permeable sandstone breccias within the pipe. Resources within individual pipes can range up to 2500
tonnes The tonne ( or ; symbol: t) is a unit of mass equal to 1,000  kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton in the United States to distinguish it from the non-metric units of the s ...
U3O8 at an average grade of between 0.3 and 1.0% U3O8. The best known examples of this deposit type are in the Arizona breccia pipe uranium mineralization in the US, where several of these deposits have been mined.


Volcanic deposits

Volcanic deposits occur in
felsic In geology, felsic is a grammatical modifier, modifier describing igneous rocks that are relatively rich in elements that form feldspar and quartz.Marshak, Stephen, 2009, ''Essentials of Geology,'' W. W. Norton & Company, 3rd ed. It is contrasted ...
to intermediate
volcanic A volcano is commonly defined as a vent or fissure in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often fo ...
to volcaniclastic rocks and associated
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcanic eruption. An eruption that ejects large volumes of magma over a short period of time can cause significant detriment to the str ...
subsidence structures, comagmatic intrusions, ring dykes and diatremes. Mineralization occurs either as structurally controlled veins and breccias discordant to the stratigraphy and less commonly as stratabound mineralization either in extrusive rocks or permeable sedimentary facies. Mineralization may be primary, that is magmatic-related or as secondary mineralization due to leaching, remobilization and re-precipitation. The principal uranium mineral in volcanic deposits is pitchblende, which is usually associated with molybdenite and minor amounts of lead, tin and tungsten mineralization. Volcanic hosted uranium deposits occur in host rocks spanning the Precambrian to the Cenozoic, but because of the shallow levels at which they form, preservation favors younger age deposits. Some of the more important deposits or districts are Streltsovskoye, Russia; Dornod, Mongolia; and McDermitt, Nevada. The average deposit size is rather small with grades of 0.02% to 0.2% U3O8. These deposits make up only a small proportion of the world's uranium resources. The only volcanic hosted deposits currently being exploited are those of the Streltsovkoye district of eastern
Siberia Siberia ( ; , ) is an extensive geographical region comprising all of North Asia, from the Ural Mountains in the west to the Pacific Ocean in the east. It has formed a part of the sovereign territory of Russia and its predecessor states ...
. This is in fact not a single stand-alone deposit, but 18 individual deposits occurring within the Streltsovsk caldera complex. Nevertheless, the average size of these deposits is far greater than the average volcanic type.


Surficial deposits (calcretes)

Surficial deposits are broadly defined as
Tertiary Tertiary (from Latin, meaning 'third' or 'of the third degree/order..') may refer to: * Tertiary period, an obsolete geologic period spanning from 66 to 2.6 million years ago * Tertiary (chemistry), a term describing bonding patterns in organic ch ...
to
Holocene The Holocene () is the current geologic time scale, geological epoch, beginning approximately 11,700 years ago. It follows the Last Glacial Period, which concluded with the Holocene glacial retreat. The Holocene and the preceding Pleistocene to ...
near-surface uranium concentrations in sediments or soils. Mineralization in calcrete (
calcium Calcium is a chemical element; it has symbol Ca and atomic number 20. As an alkaline earth metal, calcium is a reactive metal that forms a dark oxide-nitride layer when exposed to air. Its physical and chemical properties are most similar to it ...
and magnesium carbonates) are the largest of the surficial deposits. They are interbedded with Tertiary sand and clay, which are usually cemented by calcium and magnesium carbonates. Surficial deposits also occur in
peat bog A bog or bogland is a wetland that accumulates peat as a deposit of dead plant materials often mosses, typically sphagnum moss. It is one of the four main types of wetlands. Other names for bogs include mire, mosses, quagmire, and muske ...
s,
karst Karst () is a topography formed from the dissolution of soluble carbonate rocks such as limestone and Dolomite (rock), dolomite. It is characterized by features like poljes above and drainage systems with sinkholes and caves underground. Ther ...
caverns and soils. Surficial deposits account for approximately 4% of world uranium resources. The Yeelirrie deposit is by far the world's largest surficial deposit, averaging 0.15% U3O8. Langer Heinrich in
Namibia Namibia, officially the Republic of Namibia, is a country on the west coast of Southern Africa. Its borders include the Atlantic Ocean to the west, Angola and Zambia to the north, Botswana to the east and South Africa to the south; in the no ...
is another significant surficial deposit.


Metasomatite deposits

Metasomatite deposits consist of disseminated uranium minerals within structurally deformed rocks that have been affected by intense
sodium Sodium is a chemical element; it has Symbol (chemistry), symbol Na (from Neo-Latin ) and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 element, group 1 of the peri ...
metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is traditionally defined as metamorphism which involves a change in the chemical com ...
. Ore minerals are uraninite and brannerite. Th/U ratio in the ores is mostly less than 0.1. Metasomatites are typically small in size and generally contain less than 1000 t U3O8. Giant (up to 100 thousands t U) U deposits in sodium metasomatites (albitites) are known in Central Ukraine and Brazil. Two subtypes are defined based on host lithologies: *''metasomatized granite''; ex. Ross Adams deposit in
Alaska Alaska ( ) is a non-contiguous U.S. state on the northwest extremity of North America. Part of the Western United States region, it is one of the two non-contiguous U.S. states, alongside Hawaii. Alaska is also considered to be the north ...
; Novokostantynivka deposit in Kirovogradska oblast, Ukraine. *''metasomatised metasediment''; Zhovta River and Pervomayske deposits in Dnipropetrovska oblast, Ukraine and Valhalla deposit in northwestern Queensland, Australia.


Metamorphic deposits

Metamorphic deposits those that occur in metasediments or metavolcanic rocks where there is no direct evidence for mineralization post-dating metamorphism. These deposits were formed during regional metamorphism of uranium bearing or mineralized sediments or volcanic precursors. The most prominent deposits of this type are Mary Kathleen, Queensland, Australia, and Forstau, Austria.


Lignite

Lignite deposits (soft brown coal) can contain significant uranium mineralization. Mineralization can also be found in clay and sandstone immediately adjacent to lignite deposits. Uranium has been adsorbed onto carbonaceous matter and as a result no discrete uranium minerals have formed. Deposits of this type are known from the Serres Basin, in
Greece Greece, officially the Hellenic Republic, is a country in Southeast Europe. Located on the southern tip of the Balkan peninsula, it shares land borders with Albania to the northwest, North Macedonia and Bulgaria to the north, and Turkey to th ...
, and in
North North is one of the four compass points or cardinal directions. It is the opposite of south and is perpendicular to east and west. ''North'' is a noun, adjective, or adverb indicating Direction (geometry), direction or geography. Etymology T ...
and
South Dakota South Dakota (; Sioux language, Sioux: , ) is a U.S. state, state in the West North Central states, North Central region of the United States. It is also part of the Great Plains. South Dakota is named after the Dakota people, Dakota Sioux ...
. The uranium content in these deposits is very low, on average less than 0.005% U3O8, and does not currently warrant commercial extraction. When burned (e.g. in coal-fired power plants) the coal fly ash or
bottom ash Bottom ash is part of the non- combustible residue of combustion in a power plant, boiler, furnace, or incinerator. In an industrial context, it has traditionally referred to coal combustion and comprises traces of combustibles embedded in for ...
may contain a mass fraction of uranium high enough to be a concern as hazardous waste or to be potentially lucrative for extraction and sale. This is because the combustion process removes the carbon content as well as volatile elements, leaving non-volatile oxides behind.


Black shale deposits

Black shale mineralisations are large low-grade resources of uranium. They form in submarine environments under oxygen-free conditions. Organic matter in clay-rich sediments will not be converted to CO2 by biological processes in this environment and it can reduce and immobilise uranium dissolved in seawater. Average uranium grades of black shales are 50 to 250 ppm. The largest explored resource is Ranstad in Sweden containing 254,000 t of uranium. However, there are estimates for black shales in the US and Brazil assuming a uranium content of over 1 million tonnes, but at grades below 100 ppm uranium. Chattanooga Shale in the
southeastern United States The Southeastern United States, also known as the American Southeast or simply the Southeast, is a geographical List of regions in the United States, region of the United States located in the eastern portion of the Southern United States and t ...
is estimated to contain 4 to 5 million tonnes at an average grade of 54 ppm. Only the Ronneburg deposit in eastern Thuringia, Germany, has produced significant amounts of uranium. The
Ordovician The Ordovician ( ) is a geologic period and System (geology), system, the second of six periods of the Paleozoic Era (geology), Era, and the second of twelve periods of the Phanerozoic Eon (geology), Eon. The Ordovician spans 41.6 million years f ...
and
Silurian The Silurian ( ) is a geologic period and system spanning 23.5 million years from the end of the Ordovician Period, at million years ago ( Mya), to the beginning of the Devonian Period, Mya. The Silurian is the third and shortest period of t ...
black shales have a background uranium content of 40 to 60 ppm. However, hydrothermal and supergene processes caused remobilsation and enrichment of the uranium. The production between 1950 and 1990 was about 100,000 t of uranium at average grades of 700 to 1,000 ppm. Measured and inferred resources containing 87,000 t uranium at grades between 200 and 900 ppm are left.


Other types of deposits

*There are uranium deposits of other types in the Todilto Formation in the Grants District,
New Mexico New Mexico is a state in the Southwestern United States, Southwestern region of the United States. It is one of the Mountain States of the southern Rocky Mountains, sharing the Four Corners region with Utah, Colorado, and Arizona. It also ...
. *The Freital/Dresden-Gittersee deposit in eastern Germany produced about 3.700 t of uranium from
Permian The Permian ( ) is a geologic period and System (stratigraphy), stratigraphic system which spans 47 million years, from the end of the Carboniferous Period million years ago (Mya), to the beginning of the Triassic Period 251.902 Mya. It is the s ...
hard coal and its host rocks. The average ore grade was 0.11%. The deposit formed in a combination of syngenetic and diagenetic processes. *In some countries, for example China, trials are underway to extract uranium from
fly ash Coal combustion products (CCPs), also called coal combustion wastes (CCWs) or coal combustion residuals (CCRs), are byproducts of burning coal. They are categorized in four groups, each based on physical and chemical forms derived from coal combust ...
.


See also

* List of countries by uranium reserves * List of uranium mines *
Nuclear fuel cycle The nuclear fuel cycle, also known as the nuclear fuel chain, describes the series of stages that nuclear fuel undergoes during its production, use, and recycling or disposal. It consists of steps in the ''front end'', which are the preparation o ...
*
Ore genesis Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: sour ...
*
Uranium mining Uranium mining is the process of extraction of uranium ore from the earth. Over 50,000 tons of uranium were produced in 2019. Kazakhstan, Canada, and Australia were the top three uranium producers, respectively, and together account for 68% of w ...


References


Further reading

* * * *{{cite web , url = http://www.wise-uranium.org/uod.html , title = Uranium Ore Deposits , publisher = WISE Uranium Project , access-date = 2008-09-20 Economic geology Ore deposits Uranium