Ultrafine particles (UFPs) are
particulate matter
Particulate matter (PM) or particulates are microscopic particles of solid or liquid matter suspended in the air. An ''aerosol'' is a mixture of particulates and air, as opposed to the particulate matter alone, though it is sometimes defin ...
of
nanoscale size (less than 0.1
μm or 100
nm in diameter).
[
] Regulations do not exist for this size class of ambient
air pollution
Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
particles, which are far smaller than the regulated
PM10 and
PM2.5 particle classes and are believed to have several more aggressive health implications than those classes of larger particulates.
Although they remain largely unregulated, the
World Health Organization
The World Health Organization (WHO) is a list of specialized agencies of the United Nations, specialized agency of the United Nations which coordinates responses to international public health issues and emergencies. It is headquartered in Gen ...
has published good practice statements regarding measuring UFPs.
There are two main divisions that categorize types of UFPs. UFPs can either be carbon-based or metallic, and then can be further subdivided by their magnetic properties.
Electron microscopy
An electron microscope is a microscope that uses a beam of electrons as a source of illumination. It uses electron optics that are analogous to the glass lenses of an optical light microscope to control the electron beam, for instance focusing i ...
and special physical lab conditions allow scientists to observe UFP morphology.
Airborne UFPs can be measured using a
condensation particle counter, in which particles are mixed with alcohol vapor and then cooled, allowing the vapor to condense around them, after which they are counted using a light scanner.
[
] UFPs are both manufactured and naturally occurring. UFPs are the main constituent of airborne particulate matter. Owing to their large quantity and ability to penetrate deep within the lung, UFPs are a major concern for respiratory exposure and health.
Sources and applications
UFPs are both manufactured and naturally occurring. Hot
volcanic lava, ocean
spray, and
smoke
Smoke is an aerosol (a suspension of airborne particulates and gases) emitted when a material undergoes combustion or pyrolysis, together with the quantity of air that is entrained or otherwise mixed into the mass. It is commonly an unwante ...
are common natural UFPs sources. UFPs can be intentionally fabricated as
fine particles to serve a vast range of applications in both medicine and technology. Other UFPs are byproducts, like emissions, from specific processes, combustion reactions, or equipment such as
printer toner and
automobile exhaust. Anthropogenic sources of UFPs include combustion of gas, coal or hydrocarbons,
biomass burning Non-methane volatile organic compounds (NMVOCs) are a set of organic compounds that are typically Photochemical Reaction, photochemically reactive in the atmosphere—marked by the exclusion of methane. NMVOCs include a large variety of chemically d ...
(i.e. agricultural burning, forest fires and waste disposal), vehicular traffic and industrial emissions, tire wear and tear from car brakes, air traffic, seaport, maritime transportation, construction, demolition, restoration and
concrete processing, domestic wood stoves,
outdoor burning, kitchen, and cigarette smoke. In 2014, an
air quality
Air pollution is the presence of substances in the Atmosphere of Earth, air that are harmful to humans, other living beings or the environment. Pollutants can be Gas, gases like Ground-level ozone, ozone or nitrogen oxides or small particles li ...
study found harmful ultrafine particles from the takeoffs and landings at
Los Angeles International Airport
Los Angeles International Airport is the primary international airport serving Los Angeles and its Greater Los Angeles, surrounding metropolitan area, in the U.S. state of California. LAX is located in the Westchester, Los Angeles, Westcheste ...
to be of much greater magnitude than previously thought. There are a multitude of indoor sources that include but are not limited to
laser printers,
fax machines
Fax (short for facsimile), sometimes called telecopying or telefax (short for telefacsimile), is the telephone, telephonic transmission of scanned printed material (both text and images), normally to a telephone number connected to a printer or ...
,
photocopiers, the peeling of
citrus fruits,
cooking
Cooking, also known as cookery or professionally as the culinary arts, is the art, science and craft of using heat to make food more palatable, digestible, nutritious, or Food safety, safe. Cooking techniques and ingredients vary widely, from ...
,
tobacco smoke, penetration of contaminated outdoor air,
chimney
A chimney is an architectural ventilation structure made of masonry, clay or metal that isolates hot toxic exhaust gases or smoke produced by a boiler, stove, furnace, incinerator, or fireplace from human living areas. Chimneys are typical ...
cracks and
vacuum cleaners
A vacuum cleaner, also known simply as a vacuum, is a device that uses suction, and often agitation, in order to remove dirt and other debris from carpets, hard floors, and other surfaces.
The dirt is collected into a dust bag or a plastic bin ...
.
[
UFPs have a variety of applications in the medical and technology fields. They are used in diagnostic imagining, and novel drug delivery systems that include targeting the circulatory system, and or passage of the blood brain barrier to name just a few. Certain UFPs like silver based nanostructures have antimicrobial properties that are exploited in wound healing and internal instrumental coatings among other uses, in order to prevent infections. In the area of technology, carbon based UFPs have a plethora of applications in computers. This includes the use of ]graphene
Graphene () is a carbon allotrope consisting of a Single-layer materials, single layer of atoms arranged in a hexagonal lattice, honeycomb planar nanostructure. The name "graphene" is derived from "graphite" and the suffix -ene, indicating ...
and carbon nanotubes
A carbon nanotube (CNT) is a tube made of carbon with a diameter in the nanometre range (nanoscale). They are one of the allotropes of carbon. Two broad classes of carbon nanotubes are recognized:
* ''Single-walled carbon nanotubes'' (''SWC ...
in electronic as well as other computer and circuitry components. Some UFPs have characteristics similar to gas or liquid and are useful in powders or lubricants
A lubricant (sometimes shortened to lube) is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces ...
.
Exposure, risk, and health effects
The main exposure to UFPs is through inhalation. Owing to their size, UFPs are considered to be respirable particles. Contrary to the behaviour of inhaled PM10 and PM2.5, ultrafine particles are deposited in the lungs, where they have the ability to penetrate tissue and undergo interstitialization, or to be absorbed directly into the bloodstream—and therefore are not easily removed from the body and may have immediate effect. Exposure to UFPs, even if components are not very toxic, may cause oxidative stress
Oxidative stress reflects an imbalance between the systemic manifestation of reactive oxygen species and a biological system's ability to readily detoxify the reactive intermediates or to repair the resulting damage. Disturbances in the normal ...
, inflammatory mediator release, and could induce heart disease, lung disease, and other systemic effects.
The exact mechanism through which UFP exposure leads to health effects remains to be elucidated, but effects on blood pressure
Blood pressure (BP) is the pressure of Circulatory system, circulating blood against the walls of blood vessels. Most of this pressure results from the heart pumping blood through the circulatory system. When used without qualification, the term ...
may play a role. It has recently been reported that UFP is associated with an increase in blood pressure in schoolchildren with the smallest particles inducing the largest effect. According to research, infants whose mothers were exposed to higher levels of UFPs during pregnancy are much more likely to develop asthma.
There is a range of potential human exposures that include occupational, due to the direct manufacturing process or a byproduct from an industrial or office
An office is a space where the employees of an organization perform Business administration, administrative Work (human activity), work in order to support and realize the various goals of the organization. The word "office" may also denote a po ...
environment, as well as incidental, from contaminated outdoor air and other byproduct emissions. In order to quantify exposure and risk, both ''in vivo'' and ''in vitro'' studies of various UFP species are currently being done using a variety of animal models including mouse, rat, and fish.[
] These studies aim to establish toxicological profiles necessary for risk assessment, risk management, and potential regulation and legislation.
Some sizes of UFPs may be filtered from the air using ULPA filters.
Regulation and legislation
As the nanotechnology
Nanotechnology is the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). At this scale, commonly known as the nanoscale, surface area and quantum mechanical effects become important in describing propertie ...
industry has grown, nanoparticle
A nanoparticle or ultrafine particle is a particle of matter 1 to 100 nanometres (nm) in diameter. The term is sometimes used for larger particles, up to 500 nm, or fibers and tubes that are less than 100 nm in only two directions. At ...
s have brought UFPs more public and regulatory attention. UFP risk assessment research is still in the very early stages. There are continuing debates about whether to regulate UFPs and how to research and manage the health risks they may pose.[
][
] As of March 19, 2008, the EPA does not yet regulate ultrafine particle emissions.
The EPA does require notification of the intentional manufacture of nanoparticles.
In 2008, the EPA drafted a Nanomaterial Research Strategy. There is also debate about how the European Union
The European Union (EU) is a supranational union, supranational political union, political and economic union of Member state of the European Union, member states that are Geography of the European Union, located primarily in Europe. The u ...
(EU) should regulate UFPs.
Political disputes
There is political dispute between China
China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
and South Korea
South Korea, officially the Republic of Korea (ROK), is a country in East Asia. It constitutes the southern half of the Korea, Korean Peninsula and borders North Korea along the Korean Demilitarized Zone, with the Yellow Sea to the west and t ...
on ultrafine dust. South Korea claims that about 80% of ultrafine dust comes from China, and China and South Korea should cooperate to reduce the level of fine dust. China, however, argues that the Chinese government has already implemented its policy regarding ecological environment. According to China's government, its quality of air has been improved more than 40% since 2013. However, the air pollution in South Korea got worse. Therefore, the dispute between China and South Korea has become political. In March 2019, Seoul Research Institute of Public Health and Environment said that 50% to 70% of the fine dust is from China, therefore China is responsible for the air pollution in South Korea. This dispute provokes dispute among citizens as well.
In July 2014, China
China, officially the People's Republic of China (PRC), is a country in East Asia. With population of China, a population exceeding 1.4 billion, it is the list of countries by population (United Nations), second-most populous country after ...
's paramount leader
Paramount leader () is an informal term for the most important Supreme leader, political figure in the China, People's Republic of China (PRC). The paramount leader typically controls the Chinese Communist Party (CCP) and the People's Liberatio ...
Xi Jinping
Xi Jinping, pronounced (born 15 June 1953) is a Chinese politician who has been the general secretary of the Chinese Communist Party (CCP) and Chairman of the Central Military Commission (China), chairman of the Central Military Commission ...
and the South Korean government agreed to enforce Korea-China Cooperative Project, regarding Sharing of observation data on air pollutions, joint research on an air pollution forecast model and air pollution source identification, and human resources exchanges, etc. Followed by this agreement, in 2018, China and South Korea signed China-Korea Environmental Cooperation Plan to resolute environmental issues. China Research Academy of Environmental Studies (CRAES) in Beijing is developing a building for China-Korea Environmental Cooperation Center including office building and laboratory building. Based on this cooperation, South Korea already sent 10 experts on environments to China for research, and China will also send more experts for long-term research. By this bilateral relations, China and Republic of Korea are seeking resolution on air pollution in North East Asia region, and seeks international security.
See also
* Diesel particulate matter
* Health and safety hazards of nanomaterials
*Metal fume fever
Metal fume fever, also known as brass founders' ague, brass shakes, zinc shakes, galvie flu, galvo poisoning, metal dust fever, welding shivers, or Monday morning fever, is an illness primarily caused by exposure to chemicals such as zinc oxide (Zn ...
* Metal working
*Microplastics
Microplastics are "synthetic solid particles or polymeric matrices, with regular or irregular shape and with size ranging from 1 μm to 5 mm, of either primary or secondary manufacturing origin, which are insoluble in water." Microplastics a ...
* Nanostructures
* Open burning of waste
*Power tool
A power tool is a tool that is actuator, actuated by an additional engine, power source and mechanism (engineering), mechanism other than the solely manual labour, manual labor used with hand tools. The most common types of power tools use electric ...
* Renovation
*Welding
Welding is a fabrication (metal), fabrication process that joins materials, usually metals or thermoplastics, primarily by using high temperature to melting, melt the parts together and allow them to cool, causing Fusion welding, fusion. Co ...
*Wildfire
A wildfire, forest fire, or a bushfire is an unplanned and uncontrolled fire in an area of Combustibility and flammability, combustible vegetation. Depending on the type of vegetation present, a wildfire may be more specifically identified as a ...
*Fumed silica
Fumed silica (CAS_Registry_Number, CAS number 7631-86-9, also 112945-52-5), also known as pyrogenic silica because it is produced in a flame, consists of microscopic droplets of amorphous silica fused into branched, chainlike, three-dimensional ...
References
Further reading
*
*
External links
Current global map of PM{{sub, 1 distribution
Particulates
*