UPt₃ is an inorganic binary

intermetallic An intermetallic (also called intermetallic compound, intermetallic alloy, ordered intermetallic alloy, long-range-ordered alloy) is a type of metallic alloy that forms an ordered solid-state compound between two or more metallic elements. Inte ...

crystalline A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macrosc ...

compound of

platinum Platinum is a chemical element; it has Symbol (chemistry), symbol Pt and atomic number 78. It is a density, dense, malleable, ductility, ductile, highly unreactive, precious metal, precious, silverish-white transition metal. Its name origina ...

and

uranium Uranium is a chemical element; it has chemical symbol, symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Ura ...

Production

It can be synthesised in the following ways: * as an intermetallic compound, by direct fusion of pure components according to

stoichiometric Stoichiometry () is the relationships between the masses of reactants and products before, during, and following chemical reactions. Stoichiometry is based on the law of conservation of mass; the total mass of reactants must equal the total m ...

calculations: ::

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* by reduction of

uranium dioxide Uranium dioxide or uranium(IV) oxide (), also known as urania or uranous oxide, is an oxide of uranium, and is a black, radioactive, crystalline powder that naturally occurs in the mineral uraninite. It is used in nuclear fuel rods in nuclear reac ...

with

hydrogen Hydrogen is a chemical element; it has chemical symbol, symbol H and atomic number 1. It is the lightest and abundance of the chemical elements, most abundant chemical element in the universe, constituting about 75% of all baryon, normal matter ...

in the presence of platinum: ::

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Physical properties

UPt₃ forms crystals of hexagonal symmetry (some studies hypothesize a trigonal structure instead),

space group In mathematics, physics and chemistry, a space group is the symmetry group of a repeating pattern in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of the pattern that ...

P6₃/mmc, cell parameters ''a'' = 0.5766 nm and ''c'' = 0.4898 nm (''c'' should be understood as distance from planes), with a structure similar to nisnite (Ni₃Sn) and MgCd₃. The compound congruently melts at 1700 °C. The

enthalpy of formation In chemistry and thermodynamics, the standard enthalpy of formation or standard heat of formation of a compound is the change of enthalpy during the formation of 1 mole of the substance from its constituent elements in their reference state, wi ...

of the compound is -111 kJ/mol. At temperatures below 1 K it becomes

superconducting Superconductivity is a set of physical properties observed in superconductors: materials where electrical resistance vanishes and magnetic fields are expelled from the material. Unlike an ordinary metallic conductor, whose resistance decreases g ...

, thought to be due to the presence of heavy fermions (the uranium atoms).

References

{{Uranium compounds Platinum compounds Uranium compounds Intermetallics