Trichlorogermanate
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Trichlorogermanate is the inorganic anion with the formula . It is the
chloride The term chloride refers to a compound or molecule that contains either a chlorine anion (), which is a negatively charged chlorine atom, or a non-charged chlorine atom covalently bonded to the rest of the molecule by a single bond (). The pr ...
adduct of
germanium dichloride Germanium dichloride is a chemical compound of germanium and chlorine with the formula . It is a yellow solid. Germanium dichloride is an example of a compound featuring germanium in the +2 oxidation state. Preparation Solid germanium dichloride ...
: : The anion can be isolated as a
quaternary ammonium salt In organic chemistry, quaternary ammonium cations, also known as quats, are positively-charged polyatomic ions of the structure , where R is an alkyl group, an aryl group or organyl group. Unlike the ammonium ion () and the primary, secondary, ...
. The anion is similar to
trichlorostannate Trichlorostannate is the inorganic anion with the formula . It is the chloride adduct of stannous chloride: : The trichlorostannate anion is pyramidal in shape, being similar to trichlorogermanate () and antimony trichloride. The anion can be ...
(). The anion is pyramidal according to
X-ray crystallography X-ray crystallography is the experimental science of determining the atomic and molecular structure of a crystal, in which the crystalline structure causes a beam of incident X-rays to Diffraction, diffract in specific directions. By measuring th ...
with Cl-Ge-Cl angle of about 95° and Ge-Cl distance of 232 pm.


References

{{DEFAULTSORT:Trichlorogermanate Metal halides Chlorides Germanium(II) compounds Chlorometallates