
Electromagnetic radiation can be affected in several ways by the medium in which it propagates. It can be
scattered,
absorbed, and
reflected and refracted at discontinuities in the medium. This page is an overview of the last 3. The transmittance of a material and any surfaces is its effectiveness in transmitting
radiant energy
In physics, and in particular as measured by radiometry, radiant energy is the energy of electromagnetic radiation, electromagnetic and gravitational radiation. As energy, its SI unit is the joule (J). The quantity of radiant energy may be calcul ...
; the fraction of the initial (incident) radiation which propagates to a location of interest (often an observation location). This may be described by the
transmission coefficient
The transmission coefficient is used in physics and electrical engineering when wave propagation in a medium containing discontinuities is considered. A transmission coefficient describes the amplitude, intensity, or total power of a transmitt ...
.
Surface Transmittance
Hemispherical transmittance
Hemispherical transmittance of a surface, denoted ''T'', is defined as
:
where
*Φ
et is the
radiant flux
In radiometry, radiant flux or radiant power is the radiant energy emitted, reflected, transmitted, or received per unit time, and spectral flux or spectral power is the radiant flux per unit frequency or wavelength, depending on whether the ...
''transmitted'' by that surface into the hemisphere on the opposite side from the incident radiation;
*Φ
ei is the radiant flux received by that surface.
Hemispheric transmittance may be calculated as an integral over the directional transmittance described below.
Spectral hemispherical transmittance
Spectral hemispherical transmittance in frequency and spectral hemispherical transmittance in wavelength of a surface, denoted ''T''
ν and ''T''
λ respectively, are defined as
:
:
where
*Φ
e,νt is the
spectral radiant flux in frequency ''transmitted'' by that surface into the hemisphere on the opposite side from the incident radiation;
*Φ
e,νi is the spectral radiant flux in frequency received by that surface;
*Φ
e,λt is the
spectral radiant flux in wavelength ''transmitted'' by that surface into the hemisphere on the opposite side from the incident radiation;
*Φ
e,λi is the spectral radiant flux in wavelength received by that surface.
Directional transmittance
Directional transmittance of a surface, denoted ''T''
Ω, is defined as
:
where
*''L''
e,Ωt is the
radiance
In radiometry, radiance is the radiant flux emitted, reflected, transmitted or received by a given surface, per unit solid angle per unit projected area. Radiance is used to characterize diffuse emission and reflection of electromagnetic radiati ...
''transmitted'' by that surface into the
solid angle
In geometry, a solid angle (symbol: ) is a measure of the amount of the field of view from some particular point that a given object covers. That is, it is a measure of how large the object appears to an observer looking from that point.
The poin ...
Ω;
*''L''
e,Ωi is the radiance received by that surface.
Spectral directional transmittance
Spectral directional transmittance in frequency and spectral directional transmittance in wavelength of a surface, denoted ''T''
ν,Ω and ''T''
λ,Ω respectively, are defined as
:
:
where
*''L''
e,Ω,νt is the
spectral radiance in frequency ''transmitted'' by that surface;
*''L''
e,Ω,νi is the spectral radiance received by that surface;
*''L''
e,Ω,λt is the
spectral radiance in wavelength ''transmitted'' by that surface;
*''L''
e,Ω,λi is the spectral radiance in wavelength received by that surface.
Luminous transmittance
In the field of
photometry (optics)
Photometry is a branch of optics that deals with measuring light
Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectr ...
, the luminous transmittance of a filter is a measure of the amount of luminous flux or intensity transmitted by an
optical filter
An optical filter is a device that selectively transmits light of different wavelengths, usually implemented as a glass plane or plastic device in the optical path, which are either dyed in the bulk or have interference coatings. The optic ...
. It is generally defined in terms of a
standard illuminant
A standard illuminant is a theoretical source of visible light with a spectral power distribution that is published. Standard illuminants provide a basis for comparing images or colors recorded under different lighting.
CIE illuminants
The Inte ...
(e.g. Illuminant A, Iluminant C, or Illuminant E). The luminous transmittance with respect to the standard illuminant is defined as:
:
where:
*
is the spectral radiant flux or intensity of the standard illuminant (unspecified magnitude).
*
is the spectral transmittance of the filter
*
is the
luminous efficiency function
A luminous efficiency function or luminosity function represents the average spectral sensitivity of human visual perception of light. It is based on subjective judgements of which of a pair of different-colored lights is brighter, to describe re ...
The luminous transmittance is independent of the magnitude of the flux or intensity of the standard illuminant used to measure it, and is a
dimensionless quantity
Dimensionless quantities, or quantities of dimension one, are quantities implicitly defined in a manner that prevents their aggregation into unit of measurement, units of measurement. ISBN 978-92-822-2272-0. Typically expressed as ratios that a ...
.
Internal Transmittance
Optical Depth
By definition, internal transmittance is related to
optical depth
In physics, optical depth or optical thickness is the natural logarithm of the ratio of incident to ''transmitted'' radiant power through a material.
Thus, the larger the optical depth, the smaller the amount of transmitted radiant power throu ...
and to
absorbance
Absorbance is defined as "the logarithm of the ratio of incident to transmitted radiant power through a sample (excluding the effects on cell walls)". Alternatively, for samples which scatter light, absorbance may be defined as "the negative log ...
as
:
where
*''τ'' is the optical depth;
*''A'' is the absorbance.
Beer–Lambert law
The
Beer–Lambert law
The Beer–Bouguer–Lambert (BBL) extinction law is an empirical relationship describing the attenuation in intensity of a radiation beam passing through a macroscopically homogenous medium with which it interacts. Formally, it states that the ...
states that, for ''N'' attenuating species in the material sample,
:
:
where
*''σ''
''i'' is the
attenuation cross section of the attenuating species ''i'' in the material sample;
*''n''
''i'' is the
number density of the attenuating species ''i'' in the material sample;
*''ε''
''i'' is the
molar attenuation coefficient
In chemistry, the molar absorption coefficient or molar attenuation coefficient () is a measurement of how strongly a chemical species absorbs, and thereby attenuates, light at a given wavelength. It is an intrinsic property of the species. The In ...
of the attenuating species ''i'' in the material sample;
*''c''
''i'' is the
amount concentration
Quantity or amount is a property that can exist as a multitude or magnitude, which illustrate discontinuity and continuity. Quantities can be compared in terms of "more", "less", or "equal", or by assigning a numerical value multiple of a un ...
of the attenuating species ''i'' in the material sample;
*''ℓ'' is the path length of the beam of light through the material sample.
Attenuation cross section and molar attenuation coefficient are related by
:
and number density and amount concentration by
:
where N
A is the
Avogadro constant
The Avogadro constant, commonly denoted or , is an SI defining constant with an exact value of when expressed in reciprocal moles.
It defines the ratio of the number of constituent particles to the amount of substance in a sample, where th ...
.
In case of ''uniform'' attenuation, these relations become
:
:
Cases of ''non-uniform'' attenuation occur in
atmospheric science
Atmospheric science is the study of the Atmosphere of Earth, Earth's atmosphere and its various inner-working physical processes. Meteorology includes atmospheric chemistry and atmospheric physics with a major focus on weather forecasting. Clima ...
applications and
radiation shielding theory for instance.
Other radiometric coefficients
See also
*
Opacity (optics)
Opacity is the measure of impenetrability to electromagnetic or other kinds of radiation, especially visible light. In radiative transfer, it describes the absorption and scattering of radiation in a medium, such as a plasma, dielectric, sh ...
*
Photometry (optics)
Photometry is a branch of optics that deals with measuring light
Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectr ...
*
Radiometry
Radiometry is a set of techniques for measurement, measuring electromagnetic radiation, including visible light. Radiometric techniques in optics characterize the distribution of the radiation's power (physics), power in space, as opposed to phot ...
References
{{reflist
Physical quantities
Radiometry
Spectroscopy