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Transformer oil or insulating oil is an oil that is stable at high temperatures and has excellent electrical insulating properties. It is used in oil-filled wet transformers, some types of high-voltage
capacitors In electrical engineering, a capacitor is a device that stores electrical energy by accumulating electric charges on two closely spaced surfaces that are insulated from each other. The capacitor was originally known as the condenser, a term st ...
,
fluorescent Fluorescence is one of two kinds of photoluminescence, the emission of light by a substance that has absorbed light or other electromagnetic radiation. When exposed to ultraviolet radiation, many substances will glow (fluoresce) with color ...
lamp ballasts, and some types of high-voltage switches and circuit breakers. It functions to insulate, suppress
corona discharge A corona discharge is an electrical discharge caused by the ionization of a fluid such as air surrounding a conductor (material), conductor carrying a high voltage. It represents a local region where the air (or other fluid) has undergone ...
and arcing, and serves as a coolant. Most often, transformer oil is based on
mineral oil Mineral oil is any of various colorless, odorless, light mixtures of higher alkanes from a mineral source, particularly a distillate of petroleum, as distinct from usually edible vegetable oils. The name 'mineral oil' by itself is imprecise, ...
, but alternative formulations - with different engineering or environmental properties - are growing in popularity.


Function and properties

Transformer oil's primary functions are to insulate and cool a
transformer In electrical engineering, a transformer is a passive component that transfers electrical energy from one electrical circuit to another circuit, or multiple Electrical network, circuits. A varying current in any coil of the transformer produces ...
. It must therefore have high dielectric strength,
thermal conductivity The thermal conductivity of a material is a measure of its ability to heat conduction, conduct heat. It is commonly denoted by k, \lambda, or \kappa and is measured in W·m−1·K−1. Heat transfer occurs at a lower rate in materials of low ...
, and
chemical stability In chemistry, chemical stability is the thermodynamic stability of a chemical system, in particular a chemical compound or a polymer. Colloquially, it may instead refer to kinetic persistence, the shelf-life of a metastable substance or system; t ...
, and must keep these properties when held at high temperatures for extended periods. Typically, they have a
flash point The flash point of a material is the "lowest liquid temperature at which, under certain standardized conditions, a liquid gives off vapours in a quantity such as to be capable of forming an ignitable vapour/air mixture". The flash point is somet ...
greater than , pour point less than , and a dielectric breakdown at greater than 28 kVRMS. To improve cooling of large power transformers, the oil-filled tank may have external
radiator A radiator is a heat exchanger used to transfer thermal energy from one medium to another for the purpose of cooling and heating. The majority of radiators are constructed to function in cars, buildings, and electronics. A radiator is always a ...
s through which the oil circulates by natural
convection Convection is single or Multiphase flow, multiphase fluid flow that occurs Spontaneous process, spontaneously through the combined effects of material property heterogeneity and body forces on a fluid, most commonly density and gravity (see buoy ...
. Power transformers with capacities of thousands of kilovolt-ampere may also have cooling fans, oil pumps, and even oil-to-water heat exchangers.Kenneth R. Edwards, ''Transformers'', American Technical Publishers Ltd., 1996 pp.138-14 Power transformers undergo prolonged drying processes, using electrical self-heating, the application of a
vacuum A vacuum (: vacuums or vacua) is space devoid of matter. The word is derived from the Latin adjective (neuter ) meaning "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressur ...
, or both to ensure that the transformer is completely free of
water vapor Water vapor, water vapour, or aqueous vapor is the gaseous phase of Properties of water, water. It is one Phase (matter), state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from th ...
before the insulating oil is introduced. This helps prevent corona formation and subsequent
electrical breakdown In electronics, electrical breakdown or dielectric breakdown is a process that occurs when an electrically insulating material (a dielectric), subjected to a high enough voltage, suddenly becomes a conductor and current flows through it. All ...
under load. Oil filled transformers with a conservator oil reservoir may have a gas detector relay like a Buchholz relay. These safety devices detect the buildup of gas inside the transformer due to
corona discharge A corona discharge is an electrical discharge caused by the ionization of a fluid such as air surrounding a conductor (material), conductor carrying a high voltage. It represents a local region where the air (or other fluid) has undergone ...
, overheating, or an internal
electric arc An electric arc (or arc discharge) is an electrical breakdown of a gas that produces a prolonged electrical discharge. The electric current, current through a normally Electrical conductance, nonconductive medium such as air produces a plasma ( ...
. On a slow accumulation of gas, or rapid pressure rise, these devices can trip a protective
circuit breaker A circuit breaker is an electrical safety device designed to protect an Electrical network, electrical circuit from damage caused by current in excess of that which the equipment can safely carry (overcurrent). Its basic function is to interr ...
to remove power from the transformer. Transformers without conservators are usually equipped with sudden pressure relays, which perform a similar function as the Buchholz relay.


Mineral oil alternatives

Mineral oil is generally effective as a transformer oil, but it has some disadvantages, one of which is its relatively low flashpoint versus some alternatives. If a transformer leaks mineral oil, it can potentially start a fire.
Fire code Fire safety is the set of practices intended to reduce destruction caused by fire. Fire safety measures include those that are intended to prevent wikt:ignition, the ignition of an uncontrolled fire and those that are used to limit the spread a ...
s often require that transformers inside buildings use a less flammable liquid, or the use of dry-type transformers with no liquid at all. Mineral oil is also an environmental contaminant, and its insulating properties are rapidly degraded by even small amounts of water. Transformers are well equipped to keep water outside the oil for this reason. Pentaerythritol tetra
fatty acid In chemistry, in particular in biochemistry, a fatty acid is a carboxylic acid with an aliphatic chain, which is either saturated and unsaturated compounds#Organic chemistry, saturated or unsaturated. Most naturally occurring fatty acids have an ...
synthetic and natural
esters In chemistry, an ester is a chemical compound, compound derived from an acid (either organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group () of that acid is replaced by an organyl group (R). These compounds c ...
have emerged as an increasingly common mineral oil alternative, especially in high-fire-risk applications such as indoors due to their high fire point, which are over . They are biodegradable, but are more expensive than mineral oil. Natural esters have lower oxidation stability in the 120C oxygen saturated test of approximately 48-hours compared to 500-hours for Mineral oils, and are therefore used in closed transformers. Hermetic seals are important for larger transformers due to thermal expansion and contraction. Mid-size and large power transformers will typically have a conservator and employ a rubber bag with the use of natural ester to reduce oxygen ingress and prevent the natural ester from experiencing a faster oxidation than utilities are accustomed to with mineral oils.
Silicone In Organosilicon chemistry, organosilicon and polymer chemistry, a silicone or polysiloxane is a polymer composed of repeating units of siloxane (, where R = Organyl group, organic group). They are typically colorless oils or elastomer, rubber ...
or
fluorocarbon Fluorocarbons are chemical compounds with carbon-fluorine bonds. Compounds that contain many C-F bonds often have distinctive properties, e.g., enhanced stability, volatility, and hydrophobicity. Several fluorocarbons and their derivatives are ...
-based oils, which are even less flammable, are also used, but they are more expensive than esters. There are over 3 million transformers in service with vegetable-based formulations, using soy or rapeseed based formulations in up to 500 kV transformers so far. However,
coconut oil Coconut oil (or coconut fat) is an edible oil derived from the kernels, meat, and milk of the coconut palm fruit. Coconut oil is a white solid fat below around , and a clear thin liquid oil at higher temperatures. Unrefined varieties have a disti ...
-based formulations are unsuitable for use in cold climates or for voltages over 230 kV. Researchers are also investigating nanofluids for transformer use; these would be used as additives to improve the stability and thermal and electrical properties of the oil.


Polychlorinated biphenyls (PCBs)

Polychlorinated biphenyls Polychlorinated biphenyls (PCBs) are organochlorine compounds with the formula C12 H10−''x'' Cl''x''; they were once widely used in the manufacture of carbonless copy paper, as heat transfer fluids, and as dielectric and coolant fluids f ...
(PCB) are synthetic dielectrics first made over a century ago and found to have desirable properties that led to their widespread use. Polychlorinated biphenyls were formerly used as transformer oil, since they have high dielectric strength and are not flammable. Unfortunately, they are also
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...
,
bioaccumulative Bioaccumulation is the gradual accumulation of substances, such as pesticides or other chemicals, in an organism. Bioaccumulation occurs when an organism absorbs a substance faster than it can be lost or eliminated by catabolism and excretion. ...
, not at all biodegradable, and difficult to dispose of safely. When burned, they form even more toxic products, such as chlorinated dioxins and chlorinated dibenzofurans. Beginning in the 1970s, production and new uses of PCBs were banned in many countries, due to concerns about the accumulation of PCBs and toxicity of their byproducts. For instance, in the USA, production of PCBs was banned in 1979 under the Toxic Substances Control Act. In many countries significant programs are in place to reclaim and safely destroy PCB contaminated equipment. One method that can be used to reclaim PCB contaminated transformer oil is the application of a PCB removal system, also called a PCB dechlorination system. PCB removal systems use an alkali dispersion to strip the chlorine atoms from the other molecules in a chemical reaction. This forms PCB-free transformer oil and a PCB-free sludge. The two can then be separated via a centrifuge. The sludge can be disposed as regular non-PCB industrial waste. The treated transformer oil is fully restored, meeting the required standards, without any detectable PCB content. It can, thus, be used as the insulating fluid in transformers again. PCBs and mineral oil are miscible in all proportions, and sometimes the same equipment (drums, pumps, hoses, and so on) was used for either type of liquid, so PCB contamination of transformer oil continues to be a concern. For instance, under present regulations, concentrations of PCBs exceeding 5 parts per million can cause an oil to be classified as hazardous waste in California.


Testing and oil quality

Transformer oils are subject to electrical and mechanical stresses while a transformer is in operation. In addition there is contamination caused by chemical interactions with windings and other solid insulation, catalyzed by high
operating temperature An operating temperature is the allowable temperature range of the local ambient environment at which an electrical or mechanical device operates. The device will operate effectively within a specified temperature range which varies based on the de ...
. The original chemical properties of transformer oil change gradually, rendering it ineffective for its intended purpose after many years. Oil in large transformers and electrical apparatus is periodically tested for its electrical and chemical properties, to make sure it is suitable for further use. Sometimes oil condition can be improved by filtration and treatment. Tests can be divided into: # Dissolved gas analysis # Furan analysis # PCB analysis # General electrical & physical tests: #* Color & Appearance #* Breakdown Voltage #* Water Content #* Acidity (Neutralization Value) #* Dielectric Dissipation Factor #* Resistivity #* Sediments & Sludge #* Flash Point #* Pour Point #* Density #* Kinematic Viscosity The details of conducting these tests are available in standards released by
International Electrotechnical Commission The International Electrotechnical Commission (IEC; ) is an international standards organization that prepares and publishes international standards for all electrical, electronics, electronic and related technologies. IEC standards cover a va ...
,
ASTM International ASTM International, formerly known as American Society for Testing and Materials, is a standards organization that develops and publishes voluntary consensus technical international standards for a wide range of materials, products, systems and s ...
,
International standard An international standard is a technical standard developed by one or more international standards organizations. International standards are available for consideration and use worldwide. The most prominent such organization is the International O ...
, British Standards, and testing can be done by any of the methods. The Furan and DGA tests are specifically not for determining the quality of transformer oil, but for determining any abnormalities in the internal windings of the transformer or the paper insulation of the transformer, which cannot be otherwise detected without a complete overhaul of the transformer. Suggested intervals for these test are: * General and physical tests - bi-yearly * Dissolved gas analysis - yearly * Furan testing - once every 2 years, subject to the transformer being in operation for min 5 years.


On-site testing

Some transformer oil tests can be carried out in the field, using portable test apparatus. Other tests, such as dissolved gas, normally require a sample to be sent to a laboratory. Electronic on-line dissolved gas detectors can be connected to important or distressed transformers to continually monitor gas generation trends. To determine the insulating property of the dielectric oil, an oil sample is taken from the device under test, and its
breakdown voltage The breakdown voltage of an insulator (electrical), insulator is the minimum voltage that causes a portion of an insulator to experience electrical breakdown and become electrically Conductor (material), conductive. For diodes, the breakdown vo ...
is measured on-site according to the following test sequence: * In the vessel, two standard-compliant test electrodes with a typical clearance of 2.5 mm are surrounded by the insulating oil. * During the test, a test voltage is applied to the electrodes. The test voltage is continuously increased up to the breakdown voltage with a constant slew rate of e.g. 2 kV/s. * Breakdown occurs in an electric arc, leading to a collapse of the test voltage. * Immediately after ignition of the arc, the test voltage is switched off automatically. * Ultra fast switch off is crucial, as the energy that is brought into the oil and is burning it during the breakdown, must be limited to keep the additional pollution by carbonisation as low as possible. *The
root mean square In mathematics, the root mean square (abbrev. RMS, or rms) of a set of values is the square root of the set's mean square. Given a set x_i, its RMS is denoted as either x_\mathrm or \mathrm_x. The RMS is also known as the quadratic mean (denote ...
value of the test voltage is measured at the very instant of the breakdown and is reported as the breakdown voltage. * After the test is completed, the insulating oil is stirred automatically and the test sequence is performed repeatedly. * The resulting breakdown voltage is calculated as mean value of the individual measurements.


See also

* Heat-transfer oil


References

* Less and nonflammable liquid-insulated transformers, approval standard class Number 3990, Factory Mutual Research Corporation, 1997. * McShane C.P. (2001) Relative properties of the new combustion-resistant vegetable oil-based dielectric coolants for distribution and power transformers. IEEE Trans. on Industry Applications, Vol.37, No.4, July/August 2001, pp. 1132–1139, No. 0093-9994/01, 2001 IEEE. * "The Environmental technology verification program", U.S. Environmental Protection Agency, Washington, DC, VS-R-02-02, June 2002

* IEEE Guide for loading mineral-oil-immersed transformers, IEEE Standard C57.91-1995, 1996.


External links

{{Electric transformers Oils Electric transformers Liquid dielectrics