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Tonstein (from the
German German(s) may refer to: * Germany (of or related to) **Germania (historical use) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizens of Germany, see also German nationality law **Ger ...
"Ton", meaning clay, plus "Stein", meaning rock) is a hard, compact
sedimentary rock Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particle ...
that is composed mainly of
kaolinite Kaolinite ( ) is a clay mineral, with the chemical composition Al2 Si2 O5( OH)4. It is an important industrial mineral. It is a layered silicate mineral, with one tetrahedral sheet of silica () linked through oxygen atoms to one octahed ...
or, less commonly, other
clay mineral Clay minerals are hydrous aluminium phyllosilicates (e.g. kaolin, Al2 Si2 O5( OH)4), sometimes with variable amounts of iron, magnesium, alkali metals, alkaline earths, and other cations found on or near some planetary surfaces. Clay mineral ...
s such as
montmorillonite Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group ...
and
illite Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina ...
. The clays often are cemented by
iron oxide Iron oxides are chemical compounds composed of iron and oxygen. Several iron oxides are recognized. All are black magnetic solids. Often they are non-stoichiometric. Oxyhydroxides are a related class of compounds, perhaps the best known of w ...
minerals,
carbon Carbon () is a chemical element with the symbol C and atomic number 6. It is nonmetallic and tetravalent—its atom making four electrons available to form covalent chemical bonds. It belongs to group 14 of the periodic table. Carbon makes ...
aceous matter, or
chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chl ...
. Tonsteins form from
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer ...
deposited in swamps. Tonsteins occur as distinctive, thin, and laterally extensive layers in
coal Coal is a combustible black or brownish-black sedimentary rock, formed as stratum, rock strata called coal seams. Coal is mostly carbon with variable amounts of other Chemical element, elements, chiefly hydrogen, sulfur, oxygen, and nitrogen ...
seams throughout the world. They are often used as
key bed Marker horizons (also referred to as chronohorizons, key beds or marker beds) are stratigraphic units of the same age and of such distinctive composition and appearance, that, despite their presence in separate geographic locations, there is no do ...
s to correlate the
strata In geology and related fields, a stratum ( : strata) is a layer of rock or sediment characterized by certain lithologic properties or attributes that distinguish it from adjacent layers from which it is separated by visible surfaces known as e ...
in which they are found. The regional persistence of tonsteins and relict
phenocryst 300px, Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter 2.3 cm) for scale. A phenocryst is an early forming, relati ...
s indicate that they formed as the result of the diagenetic alteration of
volcanic ash Volcanic ash consists of fragments of rock, mineral crystals, and volcanic glass, created during volcanic eruptions and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer ...
falls in an acidic (low pH) and low-
salinity Salinity () is the saltiness or amount of salt dissolved in a body of water, called saline water (see also soil salinity). It is usually measured in g/L or g/kg (grams of salt per liter/kilogram of water; the latter is dimensionless and equal ...
environment, consistent with a freshwater swamp.Potter, P. E., J. B. Maynard, and P. J. Depetris (2005) ''Mud and Mudstones'' Springer-Verlag, Heidelberg, Berlin. 297 pp. . pp. 141–142.Bohor, B. F., and D. M. Triplehorn (1993) ''Tonsteins: altered volcanic ash layers in coal-bearing sequences'' Special Paper 285. Geological Society of America, Boulder, Colorado, 44 pp. In contrast, the alteration of a volcanic ashfall deposit in a marine environment typically produces a
bentonite Bentonite () is an absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-m ...
layer. The
induration A skin condition, also known as cutaneous condition, is any medical condition that affects the integumentary system—the organ system that encloses the body and includes skin, nails, and related muscle and glands. The major function of thi ...
of tonsteins is in contrast to kaolin
claystone Mudrocks are a class of fine-grained siliciclastic sedimentary rocks. The varying types of mudrocks include siltstone, claystone, mudstone, slate, and shale. Most of the particles of which the stone is composed are less than and are too sm ...
s that can be mined for kaolin clay, such as the
ball clay Ball clays are kaolinitic sedimentary clays that commonly consist of 20–80% kaolinite, 10–25% mica, 6–65% quartz. Localized seams in the same deposit have variations in composition, including the quantity of the major minerals, accessor ...
s found at
Bovey Tracey Bovey Tracey () is a small town and civil parish in Devon, England, on the edge of Dartmoor, its proximity to which gives rise to the "slogan" used on the town's boundary signs, "The Gateway to the Moor". It is often known locally as "Bovey". It ...
which formed by the erosion of a nearby kaolinised
granite Granite () is a coarse-grained ( phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies und ...
. These deposits are generally softer, white, and plastic.


See also

* * * * *


References


External links

* R. A. Batchelor
Bentonite & Tonstein Bibliography
St. Andrews University Sedimentary rocks Claystone {{petrology-stub