Titanium-44
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Naturally occurring
titanium Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in ...
(22Ti) is composed of five stable
isotope Isotopes are distinct nuclear species (or ''nuclides'') of the same chemical element. They have the same atomic number (number of protons in their Atomic nucleus, nuclei) and position in the periodic table (and hence belong to the same chemica ...
s; 46Ti, 47Ti, 48Ti, 49Ti and 50Ti with 48Ti being the most abundant (73.8%
natural abundance In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the ato ...
). Twenty-one
radioisotope A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess numbers of either neutrons or protons, giving it excess nuclear energy, and making it unstable. This excess energy can be used in one of three ...
s have been characterized, with the most stable being 44Ti with a
half-life Half-life is a mathematical and scientific description of exponential or gradual decay. Half-life, half life or halflife may also refer to: Film * Half-Life (film), ''Half-Life'' (film), a 2008 independent film by Jennifer Phang * ''Half Life: ...
of 60 years, 45Ti with a half-life of 184.8 minutes, 51Ti with a half-life of 5.76 minutes, and 52Ti with a half-life of 1.7 minutes. All of the remaining
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
isotopes have half-lives that are less than 33 seconds, and the majority of these have half-lives that are less than half a second. The isotopes of titanium range in
atomic mass Atomic mass ( or ) is the mass of a single atom. The atomic mass mostly comes from the combined mass of the protons and neutrons in the nucleus, with minor contributions from the electrons and nuclear binding energy. The atomic mass of atoms, ...
from 39.00  Da (39Ti) to 64.00 Da (64Ti). The primary
decay mode Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is conside ...
for isotopes lighter than the stable isotopes (lighter than 46Ti) is β+ and the primary mode for the heavier ones (heavier than 50Ti) is β; their respective
decay product In nuclear physics, a decay product (also known as a daughter product, daughter isotope, radio-daughter, or daughter nuclide) is the remaining nuclide left over from radioactive decay. Radioactive decay often proceeds via a sequence of steps ( d ...
s are scandium isotopes and the primary products after are vanadium isotopes. Two
stable isotopes The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundan ...
of titanium (47Ti and 49Ti) have non-zero
nuclear spin Nuclear may refer to: Physics Relating to the nucleus of the atom: * Nuclear engineering * Nuclear physics * Nuclear power * Nuclear reactor * Nuclear weapon * Nuclear medicine *Radiation therapy *Nuclear warfare Mathematics * Nuclear space * ...
of 5/2− and 7/2−, respectively, and thus are
NMR Nuclear magnetic resonance (NMR) is a physical phenomenon in which atomic nucleus, nuclei in a strong constant magnetic field are disturbed by a weak oscillating magnetic field (in the near and far field, near field) and respond by producing ...
-active.


List of isotopes

, -id=Titanium-39 , rowspan=3, 39Ti , rowspan=3 style="text-align:right" , 22 , rowspan=3 style="text-align:right" , 17 , rowspan=3, 39.00268(22)# , rowspan=3, 28.5(9) ms , β+, p (93.7%) , 38Ca , rowspan=3, 3/2+# , rowspan=3, , rowspan=3, , - , β+ (~6.3%) , 39Sc , - , β+, 2p (?%) , 37K , -id=Titanium-40 , rowspan=2, 40Ti , rowspan=2 style="text-align:right" , 22 , rowspan=2 style="text-align:right" , 18 , rowspan=2, 39.990345(73) , rowspan=2, 52.4(3) ms , β+, p (95.8%) , 39Ca , rowspan=2, 0+ , rowspan=2, , rowspan=2, , - , β+ (4.2%) , 40Sc , -id=Titanium-41 , rowspan=2, 41Ti , rowspan=2 style="text-align:right" , 22 , rowspan=2 style="text-align:right" , 19 , rowspan=2, 40.983148(30) , rowspan=2, 81.9(5) ms , β+, p (91.1%) , 40Ca , rowspan=2, 3/2+ , rowspan=2, , rowspan=2, , - , β+ (8.9%) , 41Sc , -id=Titanium-42 , 42Ti , style="text-align:right" , 22 , style="text-align:right" , 20 , 41.97304937(29) , 208.3(4) ms , β+ , 42Sc , 0+ , , , -id=Titanium-43 , 43Ti , style="text-align:right" , 22 , style="text-align:right" , 21 , 42.9685284(61) , 509(5) ms , β+ , 43Sc , 7/2− , , , -id=Titanium-43m1 , style="text-indent:1em" , 43m1Ti , colspan="3" style="text-indent:2em" , 313.0(10) keV , 11.9(3) μs , IT , 43Ti , (3/2+) , , , -id=Titanium-43m2 , style="text-indent:1em" , 43m2Ti , colspan="3" style="text-indent:2em" , 3066.4(10) keV , 556(6) ns , IT , 43Ti , (19/2−) , , , - , 44Ti , style="text-align:right" , 22 , style="text-align:right" , 22 , 43.95968994(75) , 59.1(3) y , EC , 44Sc , 0+ , , , -id=Titanium-45 , 45Ti , style="text-align:right" , 22 , style="text-align:right" , 23 , 44.95812076(90) , 184.8(5) min , β+ , 45Sc , 7/2− , , , -id=Titanium-45m , style="text-indent:1em" , 45mTi , colspan="3" style="text-indent:2em" , 36.53(15) keV , 3.0(2) μs , IT , 45Ti , 3/2− , , , -id=Titanium-46 , 46Ti , style="text-align:right" , 22 , style="text-align:right" , 24 , 45.952626356(97) , colspan=3 align=center, Stable , 0+ , 0.0825(3) , , -id=Titanium-47 , 47Ti , style="text-align:right" , 22 , style="text-align:right" , 25 , 46.951757491(85) , colspan=3 align=center, Stable , 5/2− , 0.0744(2) , , -id=Titanium-48 , 48Ti , style="text-align:right" , 22 , style="text-align:right" , 26 , 47.947940677(79) , colspan=3 align=center, Stable , 0+ , 0.7372(3) , , -id=Titanium-49 , 49Ti , style="text-align:right" , 22 , style="text-align:right" , 27 , 48.947864391(84) , colspan=3 align=center, Stable , 7/2− , 0.0541(2) , , -id=Titanium-50 , 50Ti , style="text-align:right" , 22 , style="text-align:right" , 28 , 49.944785622(88) , colspan=3 align=center, Stable , 0+ , 0.0518(2) , , -id=Titanium-51 , 51Ti , style="text-align:right" , 22 , style="text-align:right" , 29 , 50.94660947(52) , 5.76(1) min , β , 51V , 3/2− , , , -id=Titanium-52 , 52Ti , style="text-align:right" , 22 , style="text-align:right" , 30 , 51.9468835(29) , 1.7(1) min , β , 52V , 0+ , , , -id=Titanium-53 , 53Ti , style="text-align:right" , 22 , style="text-align:right" , 31 , 52.9496707(31) , 32.7(9) s , β , 53V , (3/2)− , , , -id=Titanium-54 , 54Ti , style="text-align:right" , 22 , style="text-align:right" , 32 , 53.950892(17) , 2.1(10) s , β , 54V , 0+ , , , -id=Titanium-55 , 55Ti , style="text-align:right" , 22 , style="text-align:right" , 33 , 54.955091(31) , 1.3(1) s , β , 55V , (1/2)− , , , -id=Titanium-56 , 56Ti , style="text-align:right" , 22 , style="text-align:right" , 34 , 55.95768(11) , 200(5) ms , β , 56V , 0+ , , , -id=Titanium-57 , 57Ti , style="text-align:right" , 22 , style="text-align:right" , 35 , 56.96307(22) , 95(8) ms , β , 57V , 5/2−# , , , -id=Titanium-58 , 58Ti , style="text-align:right" , 22 , style="text-align:right" , 36 , 57.96681(20) , 55(6) ms , β , 58V , 0+ , , , -id=Titanium-59 , 59Ti , style="text-align:right" , 22 , style="text-align:right" , 37 , 58.97222(32)# , 28.5(19) ms , β , 59V , 5/2−# , , , -id=Titanium-59m , style="text-indent:1em" , 59mTi , colspan="3" style="text-indent:2em" , 108.5(5) keV , 615(11) ns , IT , 59Ti , 1/2−# , , , -id=Titanium-60 , 60Ti , style="text-align:right" , 22 , style="text-align:right" , 38 , 59.97628(26) , 22.2(16) ms , β , 60V , 0+ , , , -id=Titanium-61 , 61Ti , style="text-align:right" , 22 , style="text-align:right" , 39 , 60.98243(32)# , 15(4) ms , β , 61V , 1/2−# , , , -id=Titanium-61m1 , style="text-indent:1em" , 61m1Ti , colspan="3" style="text-indent:2em" , 125.0(5) keV , 200(28) ns , IT , 61Ti , 5/2−# , , , -id=Titanium-61m2 , style="text-indent:1em" , 61m2Ti , colspan="3" style="text-indent:2em" , 700.1(7) keV , 354(69) ns , IT , 61Ti , 9/2+# , , , -id=Titanium-62 , 62Ti , style="text-align:right" , 22 , style="text-align:right" , 40 , 61.98690(43)# , 9# ms
620 ns, , , 0+ , , , -id=Titanium-63 , 63Ti , style="text-align:right" , 22 , style="text-align:right" , 41 , 62.99371(54)# , 10# ms
620 ns, , , 1/2−# , , , -id=Titanium-64 , 64Ti , style="text-align:right" , 22 , style="text-align:right" , 42 , 63.99841(64)# , 5# ms
620 ns, , , 0+ , ,


Titanium-44

Titanium-44 (44Ti) is a radioactive isotope of titanium that undergoes
electron capture Electron capture (K-electron capture, also K-capture, or L-electron capture, L-capture) is a process in which the proton-rich nucleus of an electrically neutral atom absorbs an inner atomic electron, usually from the K or L electron shells. Th ...
to an
excited state In quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Add ...
of
scandium-44 Scandium-44 (44Sc) is a radioactive isotope of scandium that decays by positron emission to stable 44Ca with a half-life of 4.042 hours. 44Sc can be obtained as a daughter radionuclide of long-lived 44Ti (t1/2 60.4 a) from 44Ti /44Sc generato ...
with a half-life of 60 years, before the ground state of 44Sc and ultimately 44Ca are populated. Because titanium-44 can only decay through electron capture, its half-life increases with its ionization state and it becomes stable in its
fully ionized The degree of ionization (also known as ionization yield in the literature) refers to the proportion of neutral particles, such as those in a gas or aqueous solution, that are ionized. For electrolytes, it could be understood as a capacity of ac ...
state (that is, having a charge of +22). Titanium-44 is produced in relative abundance in the
alpha process The alpha process, also known as alpha capture or the alpha ladder, is one of two classes of nuclear fusion reactions by which stars convert helium into heavier elements. The other class is a cycle of reactions called the triple-alpha process, w ...
in
stellar nucleosynthesis In astrophysics, stellar nucleosynthesis is the creation of chemical elements by nuclear fusion reactions within stars. Stellar nucleosynthesis has occurred since the original creation of hydrogen, helium and lithium during the Big Bang. As a ...
and the early stages of
supernova A supernova (: supernovae or supernovas) is a powerful and luminous explosion of a star. A supernova occurs during the last stellar evolution, evolutionary stages of a massive star, or when a white dwarf is triggered into runaway nuclear fusion ...
explosions. It is produced when
calcium-40 Calcium (Ca) has 26 known isotopes, ranging from Ca to Ca. There are five stable isotopes (Ca, Ca, Ca, Ca and Ca), plus one isotope ( Ca) with such a long half-life that it is for all practical purposes stable. The most abundant isotope, Ca, as ...
fuses with an
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay but may also be produce ...
(
helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and consi ...
nucleus) in a star's high-temperature environment; the resulting 44Ti nucleus can then fuse with another alpha particle to form chromium-48. The age of supernovae may be determined through measurements of
gamma-ray A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists ...
emissions from titanium-44 and its abundance. It was observed in the
Cassiopeia A Cassiopeia A (Cas A) () is a supernova remnant (SNR) in the constellation Cassiopeia and the brightest extrasolar radio source in the sky at frequencies above 1 GHz. The supernova occurred approximately away within the Milky Way; ...
supernova remnant and
SN 1987A SN 1987A was a Type II supernova in the Large Magellanic Cloud, a dwarf satellite galaxy of the Milky Way. It occurred approximately from Earth and was the closest observed supernova since Kepler's Supernova in 1604. Light and neutrinos ...
at a relatively high concentration, a consequence of delayed decay resulting from ionizing conditions.


See also

Daughter products other than titanium *
Isotopes of vanadium Naturally occurring vanadium (23V) is composed of one stable isotope 51V and one radioactive isotope 50V with a half-life of 2.71×1017 years. 24 artificial radioisotopes have been characterized (in the range of mass number between 40 and 65) with ...
*
Isotopes of scandium Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-seven radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a hal ...
*
Isotopes of calcium Calcium (Ca) has 26 known isotopes, ranging from Ca to Ca. There are five stable isotopes (Ca, Ca, Ca, Ca and Ca), plus one isotope ( Ca) with such a long half-life that it is for all practical purposes stable. The most abundant isotope, Ca, as ...
*
Isotopes of potassium Potassium () has 25 known isotopes from to as well as , as well as an unconfirmed report of . Three of those isotopes occur naturally: the two stable forms (93.3%) and (6.7%), and a very long-lived radioisotope (0.012%) Naturally occurring ...


References

* Isotope masses from: ** * Isotopic compositions and standard atomic masses from: ** ** * Half-life, spin, and isomer data selected from the following sources. ** ** ** {{Navbox element isotopes Titanium Titaniun