Thulium(III) Acetate
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Thulium(III) acetate is the
acetate An acetate is a salt formed by the combination of acetic acid with a base (e.g. alkaline, earthy, metallic, nonmetallic, or radical base). "Acetate" also describes the conjugate base or ion (specifically, the negatively charged ion called ...
salt of thulium, with the
chemical formula A chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbols, such as pare ...
of Tm(CH3COO)3. It can exist in the tetra
hydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
or the anhydrous form.


Properties

Thulium(III) acetate reacts with iron acetylacetonate at 300 °C, which can form the hexagonal crystal TmFeO3. Reacting thulium(III) acetate with
trifluoroacetic acid Trifluoroacetic acid (TFA) is a synthetic organofluorine compound with the chemical formula CF3CO2H. It belongs to the subclass of per- and polyfluoroalkyl substances (PFASs) known as ultrashort-chain perfluoroalkyl acids (PFAAs). TFA is not ...
will produce thulium trifluoroacetate: : Tm(CH3COO)3 + 3 CF3COOH → Tm(CF3COO)3 + 3 CH3COOH


References


External reading

* Mondry, A., & Bukietyńska, K. (2003). The power and limits of the Judd—Ofelt theory: a case of Pr3+ and Tm3+ acetates and dipicolinates. Molecular Physics, 101(7), 923-934. {{Acetates Thulium compounds Acetates