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Tetrachloroiodic acid is an inorganic compound, a polyhalide acid with the formula HICl4. In addition to an
anhydrous A substance is anhydrous if it contains no water. Many processes in chemistry can be impeded by the presence of water; therefore, it is important that water-free reagents and techniques are used. In practice, however, it is very difficult to achie ...
form, an orange crystalline
tetrahydrate In chemistry, a hydrate is a substance that contains water or its constituent elements. The chemical state of the water varies widely between different classes of hydrates, some of which were so labeled before their chemical structure was understo ...
is known. It is unstable in air.Tetrachloroiodic (3) acid HICl4x4H2O
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Synthesis

Tetrachloroiodic acid may be formed by dissolution of
iodine trichloride Iodine trichloride is an interhalogen compound of iodine and chlorine. It is bright yellow but upon time and exposure to light it turns red due to the presence of elemental iodine. In the solid state is present as a planar dimer I2Cl6, with two ...
in concentrated
hydrochloric acid Hydrochloric acid, also known as muriatic acid or spirits of salt, is an aqueous solution of hydrogen chloride (HCl). It is a colorless solution with a distinctive pungency, pungent smell. It is classified as a acid strength, strong acid. It is ...
: : Tetrachloroiodic acid may also be made by passing
chlorine Chlorine is a chemical element; it has Symbol (chemistry), symbol Cl and atomic number 17. The second-lightest of the halogens, it appears between fluorine and bromine in the periodic table and its properties are mostly intermediate between ...
through a solution of
iodine Iodine is a chemical element; it has symbol I and atomic number 53. The heaviest of the stable halogens, it exists at standard conditions as a semi-lustrous, non-metallic solid that melts to form a deep violet liquid at , and boils to a vi ...
in concentrated hydrochloric acid : :


Physical properties

Tetrachloroiodic acid forms a crystal hydrate which has orange crystals that are unstable in air and melt by dissolving in their own water of crystallization at 19 °C.


See also

*
Iodine trichloride Iodine trichloride is an interhalogen compound of iodine and chlorine. It is bright yellow but upon time and exposure to light it turns red due to the presence of elemental iodine. In the solid state is present as a planar dimer I2Cl6, with two ...


References

Iodine compounds Chlorine compounds {{Inorganic-compound-stub