Tantalum(V) Iodide
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Tantalum(V) iodide is the
inorganic compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
with the formula Ta2I10. Its name comes from the compound's
empirical formula In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms present in a compound. A simple example of this concept is that the empirical formula of sulfur monoxide, or SO, is simply SO, as is the empir ...
, TaI5. It is a diamagnetic, black solid that hydrolyses readily. The compound adopts an edge-shared bioctahedral structure, which means that two TaI5 units are joined by a pair of iodide bridges. There is no bond between the Ta centres.
Niobium(V) chloride Niobium(V) chloride, also known as niobium pentachloride, is a yellow crystalline solid. It hydrolyzes in air, and samples are often contaminated with small amounts of Niobium oxychloride, NbOCl3. It is often used as a precursor to other compound ...
, niobium(V) bromide, niobium(V) iodide, tantalum(V) chloride, and tantalum(V) bromide all share this structural motif.


Synthesis and structure

Tantalum pentaiodide forms from the reaction of tantalum pentoxide with aluminium triiodide: :


References

{{Iodides Iodides Tantalum(V) compounds Metal halides