Taconite () is a variety of
banded iron formation
Banded iron formations (BIFs; also called banded ironstone formations) are distinctive units of sedimentary rock consisting of alternating layers of iron oxides and iron-poor chert. They can be up to several hundred meters in thickness and e ...
, an
iron
Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...
-bearing (over 15% iron)
sedimentary rock
Sedimentary rocks are types of rock (geology), rock formed by the cementation (geology), cementation of sediments—i.e. particles made of minerals (geological detritus) or organic matter (biological detritus)—that have been accumulated or de ...
, in which the iron minerals are interlayered with
quartz
Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The Atom, atoms are linked in a continuous framework of SiO4 silicon–oxygen Tetrahedral molecular geometry, tetrahedra, with each oxygen being shared between two tet ...
,
chert
Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a prec ...
, or
carbonate
A carbonate is a salt of carbonic acid, (), characterized by the presence of the carbonate ion, a polyatomic ion with the formula . The word "carbonate" may also refer to a carbonate ester, an organic compound containing the carbonate group ...
. The name ''taconyte'' was coined by Horace Vaughn Winchell (1865–1923) – son of
Newton Horace Winchell, the
Minnesota
Minnesota ( ) is a U.S. state, state in the Upper Midwestern region of the United States. It is bordered by the Canadian provinces of Manitoba and Ontario to the north and east and by the U.S. states of Wisconsin to the east, Iowa to the so ...
state geologist – during their pioneering investigations of the
Precambrian
The Precambrian ( ; or pre-Cambrian, sometimes abbreviated pC, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of t ...
Biwabik Iron Formation of northeastern Minnesota. He believed the sedimentary rock sequence hosting the iron-formation was correlative with the
Taconic orogeny
The Taconic orogeny was a mountain building period that ended 440 million years ago (Ma) and affected most of modern-day New England. A great mountain chain formed from eastern Canada down through what is now the Piedmont of the east coast of the ...
of New England, and referred to the unfamiliar and as-yet-unnamed iron-bearing rock as the 'taconic rock' or ''taconyte''.
Following development of high grade direct shipping
iron ore
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the f ...
deposits on the
Mesabi Range
The Mesabi Iron Range is a mining district and mountain range in northeastern Minnesota following an elongate trend containing large deposits of iron ore. It is the largest of four major iron ranges in the region collectively known as the Iro ...
, containing up to 65% iron and as little as 1.25%
silica
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , commonly found in nature as quartz. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant f ...
, miners termed the unaltered iron-formation wall rock taconite. The iron content of taconite is generally 30% to 35%, and the silica content generally around 45%. Iron in taconite is commonly present as magnetite, iron silicates, and iron-bearing carbonates, and locally martite (hematite) formed by oxidation of magnetite. Horizons containing magnetite as the dominant mineral have been extensively mined since 1955 to produce iron ore pellets; the term 'taconite' has consequently been colloquially adapted to describe the magnetite iron-formation ores (''taconite iron ore''), the mining, milling, magnetic separation, and agglomerating process (''taconite process''), and the product iron ore pellets (''taconite pellets'').
History
In the late 19th and early 20th centuries, the United States was mining such an abundance of
iron ore
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the f ...
of high quality that taconite was considered an uneconomic waste product. By the end of
World War II
World War II or the Second World War (1 September 1939 – 2 September 1945) was a World war, global conflict between two coalitions: the Allies of World War II, Allies and the Axis powers. World War II by country, Nearly all of the wo ...
much of the high-grade iron ore in the
United States
The United States of America (USA), also known as the United States (U.S.) or America, is a country primarily located in North America. It is a federal republic of 50 U.S. state, states and a federal capital district, Washington, D.C. The 48 ...
had been exhausted, so taconite became valued as a new source of the metal.
Production
To process taconite, the ore is ground into a fine powder, the magnetite is separated from the
gangue
Gangue () is the commercially worthless material that surrounds, or is closely mixed with, a wanted mineral in an ore deposit. It is thus distinct from overburden, which is the waste rock or materials overlying an ore or mineral body that are di ...
by strong magnets, and the powdered iron concentrate is combined with a binder such as
bentonite
Bentonite ( ) is an Absorption (chemistry), absorbent swelling clay consisting mostly of montmorillonite (a type of smectite) which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelli ...
clay and limestone as a
flux
Flux describes any effect that appears to pass or travel (whether it actually moves or not) through a surface or substance. Flux is a concept in applied mathematics and vector calculus which has many applications in physics. For transport phe ...
. As a last step, it is rolled into pellets about 10 millimeters in diameter that contain about 65% iron. The pellets are fired at a very high temperature to harden them and make them durable. This is to ensure that the
blast furnace
A blast furnace is a type of metallurgical furnace used for smelting to produce industrial metals, generally pig iron, but also others such as lead or copper. ''Blast'' refers to the combustion air being supplied above atmospheric pressure.
In a ...
charge remains porous enough to allow heated gas to pass through and react with the pelletized ore. Firing the pellet
oxidize
Redox ( , , reduction–oxidation or oxidation–reduction) is a type of chemical reaction in which the oxidation states of the reactants change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is ...
s the magnetite (Fe
3O
4) to
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
(Fe
2O
3), an
exothermic
In thermodynamics, an exothermic process () is a thermodynamic process or reaction that releases energy from the system to its surroundings, usually in the form of heat, but also in a form of light (e.g. a spark, flame, or flash), electricity (e ...
reaction that reduces the cost of pelletizing the concentrate.
E. W. Davis of the
University of Minnesota
The University of Minnesota Twin Cities (historically known as University of Minnesota) is a public university, public Land-grant university, land-grant research university in the Minneapolis–Saint Paul, Twin Cities of Minneapolis and Saint ...
Mines Experiment Station is credited with developing the pelletizing process. Since the commercial development of this process in the
Lake Superior
Lake Superior is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. Lake Michigan–Huron has a larger combined surface area than Superior, but is normally considered tw ...
region in the 1950s, the term "taconite" has been used globally to refer to iron ores amenable to upgrading by similar processes.
Major producers of iron ore pellets from taconite in North America include
Iron Ore Company of Canada
Iron Ore Company of Canada (often abbreviated to IOC) () is a Canadian-based producer of iron ore. The company was founded in 1949 from a partnership of Canadian and American firms, the largest being the M.A. Hanna Company. It is now owned by a c ...
,
Cliffs Natural Resources, Inc.,
U.S. Steel, and
ArcelorMittal
ArcelorMittal S.A. is a Luxembourg-based multinational steel manufacturing corporation, headquartered in Luxembourg City. It is ranked second on the list of steel producers behind Baowu, and had an annual crude steel production of 58 millio ...
. These processed taconite-ore pellets are also referred to as "taconite". Because this is the form that is typically transported by rail and ship, and cargo of these is often discussed, this usage of the term is very common.
The
Mesabi Iron Range region of the American state of Minnesota is a major production area. The taconite iron ore pellets are hauled by
railroad
Rail transport (also known as train transport) is a means of transport using wheeled vehicles running in railway track, tracks, which usually consist of two parallel steel railway track, rails. Rail transport is one of the two primary means of ...
to the ports of
Silver Bay,
Two Harbors and the
Twin Ports
The Duluth MN–WI Metropolitan Area, commonly called the Twin Ports, is a small metropolitan area centered around the cities of Duluth, Minnesota and Superior, Wisconsin. The Twin Ports are located at the western part of Lake Superior (the we ...
of
Duluth, Minnesota
Duluth ( ) is a Port, port city in the U.S. state of Minnesota and the county seat of St. Louis County, Minnesota, St. Louis County. Located on Lake Superior in Minnesota's Arrowhead Region, the city is a hub for cargo shipping. The population ...
, and
Superior, Wisconsin
Superior (; ) is a city in Douglas County, Wisconsin, United States, and its county seat. The population was 26,751 at the 2020 United States census, 2020 census. Located at the western end of Lake Superior in northwestern Wisconsin, the city l ...
, all on
Lake Superior
Lake Superior is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. Lake Michigan–Huron has a larger combined surface area than Superior, but is normally considered tw ...
. The docks at
Escanaba, Michigan
Escanaba ( ), commonly shortened to Esky, is a port city and the county seat of Delta County in the U.S. state of Michigan, located on Little Bay de Noc in the state's Upper Peninsula. The population was 12,450 at the 2020 census, making it the ...
, on Lake Michigan, also ship taconite from the Marquette iron range in Michigan, and occasionally ore from Minnesota is hauled by rail there.
Marquette, Michigan
Marquette ( ) is the county seat of Marquette County, Michigan, Marquette County and the largest city in the Upper Peninsula of Michigan, United States. Located on the shores of Lake Superior, Marquette is a major port known primarily for shippin ...
, also has a taconite dock that loads bulk freighters with ore from the Marquette iron range. The ore is generally shipped by
lake freighter
Lake freighters, or lakers, are bulk carriers operating on the Great Lakes of North America. These vessels are traditionally called boats, although classified as ships. Freighters typically have a long, narrow hull, a raised pilothouse, and the ...
s to locations on the lower
Great Lakes
The Great Lakes, also called the Great Lakes of North America, are a series of large interconnected freshwater lakes spanning the Canada–United States border. The five lakes are Lake Superior, Superior, Lake Michigan, Michigan, Lake Huron, H ...
. Many steelmaking centers are near
Lake Erie
Lake Erie ( ) is the fourth-largest lake by surface area of the five Great Lakes in North America and the eleventh-largest globally. It is the southernmost, shallowest, and smallest by volume of the Great Lakes and also has the shortest avera ...
. Due to increased international demand, taconite is shipped to Mexico and China.
Future Work
The SS ''
Edmund Fitzgerald,'' which sank in
Lake Superior
Lake Superior is the largest freshwater lake in the world by surface areaThe Caspian Sea is the largest lake, but is saline, not freshwater. Lake Michigan–Huron has a larger combined surface area than Superior, but is normally considered tw ...
on November 10, 1975, was carrying about 26,116
long tons of taconite pellets.
Taconite and human health
Beginning in 1955, Reserve Mining Company discharged crushed waste rock (tailings) from their
Silver Bay, Minnesota processing plant into Lake Superior. The tailings contained 40% of the
amphibole
Amphibole ( ) is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is ...
group mineral series
cummingtonite-
grunerite, which may form asbestiform particles. A small fraction of the fine-grained tailings were shown to widely disperse along the western shore of Lake Superior, the source of drinking water for a number of cities; for example, tests of Duluth, Minnesota's water supply showed 100 billion fibers per liter of water. There was no epidemiological proof whether these particles caused cancer or were safe. On April 20, 1974, the U.S. District Court judge Miles Lord ruled that the drinking water and Lake Superior must be protected from the asbestos-like particles. The Reserve Mine was forced to begin disposing of tailing wastes on the land, and to implement air pollution control equipment, instead of discharging them directly to Lake Superior. This became one of the costliest pollution prevention cases in U.S. history. Government-funded studies have found no adverse health effects from drinking Lake Superior water.
A 2003 study of taconite miners concluded that the most likely cause of 14 of the 17 cases of
mesothelioma
Mesothelioma is a type of cancer that develops from the thin layer of tissue that covers many of the internal organs (known as the mesothelium). The area most commonly affected is the lining of the lungs and chest wall. Less commonly the lini ...
among miners on the iron range was contact with
asbestos
Asbestos ( ) is a group of naturally occurring, Toxicity, toxic, carcinogenic and fibrous silicate minerals. There are six types, all of which are composed of long and thin fibrous Crystal habit, crystals, each fibre (particulate with length su ...
. Since that study was concluded, 35 more Iron Range miners have been diagnosed with the disease. Mesothelioma occurs at twice the expected rate among the population of the northeastern region of Minnesota, including the
Iron Range.
[ ] Spurred by the 2003 study, the Minnesota Department of Health (MDH) studied the relationship of fibrous minerals in taconite and taconite dust, and lung conditions similar to
asbestosis
Asbestosis is long-term inflammation and pulmonary fibrosis, scarring of the human lung, lungs due to asbestos fibers. Symptoms may include shortness of breath, cough, wheezing, and chest pain, chest tightness. Complications may include lung canc ...
, pleural mesothelioma and other
pleural
The pleural cavity, or pleural space (or sometimes intrapleural space), is the potential space between the pulmonary pleurae, pleurae of the pleural sac that surrounds each lung. A small amount of serous fluid, serous pleural fluid is maintained ...
conditions which occur following asbestos exposure. Because these conditions can be triggered by industrial asbestos, which was used in taconite mining and processing, as well as other industrial facilities in northeastern Minnesota, the study attempted to determine what, if any, influence naturally occurring fibrous minerals in taconite may have played.
The lengthy epidemiological study of Minnesota iron miners concluded in December 2014 that those working 30 years in the iron mines and living to be 80 years old had a lifetime chance of having a mesothelioma of 3.33 cases per thousand such workers, more than double the background rate of 1.44 cases per thousand people living to 80 years old.
See also
*
* {{annotated link, Banded iron formation
References
Further reading
* Davis, Edward W., ''Pioneering With Taconite''. St. Paul: Minnesota Historical Society Press, 1964.
* Erie Mining Company History Project Team, ''Taconite, New Life for Minnesota's Iron Range: The History of Erie Mining Company''. Duluth: St. Louis County Historical Society, 2019.
* Manuel, Jeffrey T., "Mr. Taconite: Edward W. Davis and the Promotion of Low-Grade Iron Ore, 1913–1955," ''Technology and Culture,'' 54 (April 2013), 317–45.
* Manuel, Jeffrey T., ''Taconite Dreams: The Struggle to Sustain Mining on Minnesota's Iron Range, 1915-2000''. Minneapolis: University of Minnesota Press, 2015.
External links
"Taconite" Minnesota Department of Natural Resources
Geography
Silver Bay, Minnesota Official Website
Economic geology
Geology of Minnesota
Iron(II,III) minerals
Iron mining
Mining in Minnesota
Sedimentary rocks