Sulfur Trifluoride
   HOME

TheInfoList



OR:

Sulfur trifluoride is the
inorganic chemical compound An inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds⁠that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemistry''. Inorgan ...
with the formula SF3. It is a
radical Radical (from Latin: ', root) may refer to: Politics and ideology Politics *Classical radicalism, the Radical Movement that began in late 18th century Britain and spread to continental Europe and Latin America in the 19th century *Radical politics ...
.


Structure and synthesis

Sulfur trifluoride is predicted to be pyramidal. is generated by irradiation of crystals of trifluorosulfonium tetrafluoroborate with
gamma ray A gamma ray, also known as gamma radiation (symbol ), is a penetrating form of electromagnetic radiation arising from high energy interactions like the radioactive decay of atomic nuclei or astronomical events like solar flares. It consists o ...
s.


A derivative formally derived from is the
coordination complex A coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the ''coordination centre'', and a surrounding array of chemical bond, bound molecules or ions, that are in turn known as ' ...
Ir(Cl)(CO)(F)(SF3)(Et3P)2 obtained by
oxidative addition Oxidative addition and reductive elimination are two important and related classes of reactions in organometallic chemistry. Oxidative addition is a process that increases both the oxidation state and coordination number of a metal centre. Oxidat ...
of
sulfur tetrafluoride Sulfur tetrafluoride is a chemical compound with the formula S F4. It is a colorless corrosive gas that releases dangerous hydrogen fluoride gas upon exposure to water or moisture. Sulfur tetrafluoride is a useful reagent for the preparation o ...
to Ir(Cl)(CO)(PEt3)2 (Et = C2H5).


References

{{Fluorides Sulfur fluorides Free radicals