Succinite
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Baltic amber or succinite is
amber Amber is fossilized tree resin. Examples of it have been appreciated for its color and natural beauty since the Neolithic times, and worked as a gemstone since antiquity."Amber" (2004). In Maxine N. Lurie and Marc Mappen (eds.) ''Encyclopedia ...
from the
Baltic region The Baltic Sea Region, alternatively the Baltic Rim countries (or simply the Baltic Rim), and the Baltic Sea countries/states, refers to the general area surrounding the Baltic Sea, including parts of Northern, Central and Eastern Europe. Un ...
, home of its largest known deposits. It was produced sometime during the
Eocene The Eocene ( ) is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (Ma). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene'' comes ...
epoch, but exactly when is controversial. It has been estimated that this forested region provided the
resin A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Commo ...
for more than 100,000 tons of amber. Today, more than 90% of the world's amber comes from
Kaliningrad Oblast Kaliningrad Oblast () is the westernmost federal subjects of Russia, federal subject of the Russian Federation. It is a Enclave and exclave, semi-exclave on the Baltic Sea within the Baltic region of Prussia (region), Prussia, surrounded by Pola ...
of
Russia Russia, or the Russian Federation, is a country spanning Eastern Europe and North Asia. It is the list of countries and dependencies by area, largest country in the world, and extends across Time in Russia, eleven time zones, sharing Borders ...
. It is a major source of income for the region; the local Kaliningrad Amber Combine extracted 250 tonnes of it in 2014 and 400 tonnes in 2015. Baltic amber is also found in
Poland Poland, officially the Republic of Poland, is a country in Central Europe. It extends from the Baltic Sea in the north to the Sudetes and Carpathian Mountains in the south, bordered by Lithuania and Russia to the northeast, Belarus and Ukrai ...
, as well as the
Baltic states The Baltic states or the Baltic countries is a geopolitical term encompassing Estonia, Latvia, and Lithuania. All three countries are members of NATO, the European Union, the Eurozone, and the OECD. The three sovereign states on the eastern co ...
. Bitterfeld amber from the
brown coal Lignite (derived from Latin ''lignum'' meaning 'wood'), often referred to as brown coal, is a soft, brown, Combustion, combustible sedimentary rock formed from naturally compressed peat. It has a carbon content around 25–35% and is considered ...
mines near
Bitterfeld Bitterfeld () is a town in the district of Anhalt-Bitterfeld, Saxony-Anhalt, Germany. Since 1 July 2007 it has been part of the town of Bitterfeld-Wolfen. It is situated approximately 25 km south of Dessau, and 30 km northeast of Hall ...
in Germany was previously thought to be redeposited Baltic amber, but is now known to be chemically distinct, though like with Ukrainian
Rovno amber Rovno amber, occasionally called Ukrainian amber, is amber found in the Rivne Oblast and surrounding regions of Ukraine and Belarus. The amber is dated between Late Eocene and Early Oligocene, and suggested to be contemporaneous to Baltic amber ...
, it is thought to have been deposited around the same time as Baltic amber. Because Baltic amber contains from 3 to 8%
succinic acid Succinic acid () is a dicarboxylic acid with the chemical formula (CH2)2(CO2H)2. In living organisms, succinic acid takes the form of an anion, succinate, which has multiple biological roles as a metabolic intermediate being converted into fum ...
, it is also termed succinite.


Geologic context

''In situ'' Baltic amber is derived from the sediments of the
geological formation A geological formation, or simply formation, is a body of rock having a consistent set of physical characteristics (lithology) that distinguishes it from adjacent bodies of rock, and which occupies a particular position in the layers of rock expo ...
termed the Prussian Formation, formerly called the "Amber Formation", with the main amber bearing horizon being referred to as "Blue Earth", so named due to its
glauconite Glauconite is an iron potassium phyllosilicate ( mica group) mineral of characteristic green color which is very friable and has very low weathering resistance. It crystallizes with a monoclinic geometry. Its name is derived from the Greek ...
content. The formation is exposed in the northern part of the
Sambia Peninsula Sambia () or Samland () or Kaliningrad Peninsula (official name, , ''Kaliningradsky poluostrov'') is a peninsula in the Kaliningrad Oblast of Russia, on the southeastern shore of the Baltic Sea. The peninsula is bounded by the Curonian Lagoon to ...
in Kaliningrad. Much of the Baltic amber has been secondarily redeposited in
Pleistocene The Pleistocene ( ; referred to colloquially as the ''ice age, Ice Age'') is the geological epoch (geology), epoch that lasted from to 11,700 years ago, spanning the Earth's most recent period of repeated glaciations. Before a change was fin ...
glacial till image:Geschiebemergel.JPG, Closeup of glacial till. Note that the larger grains (pebbles and gravel) in the till are completely surrounded by the matrix of finer material (silt and sand), and this characteristic, known as ''matrix support'', is d ...
deposits across the
North European Plain The North European Plain ( – North German Plain; ; – Central European Plain; and ; French: ''Plaine d'Europe du Nord'') is a geomorphological region in Europe that covers all or parts of Belgium, the Netherlands (i.e. the Low Countries), ...
. It has been proposed that the amber is secondarily redeposited in coastal lagoonal conditions after a
marine transgression A marine transgression is a geologic event where sea level rises relative to the land and the shoreline moves toward higher ground, resulting in flooding. Transgressions can be caused by the land sinking or by the ocean basins filling with water ...
of the amber forest. The age of the amber is controversial, though it is generally interpreted as having been produced during the
Eocene The Eocene ( ) is a geological epoch (geology), epoch that lasted from about 56 to 33.9 million years ago (Ma). It is the second epoch of the Paleogene Period (geology), Period in the modern Cenozoic Era (geology), Era. The name ''Eocene'' comes ...
epoch (56-34 million years ago). Different authors have given estimates of 40-47 million years ago and 35-43 million years ago as the age of the amber. Dating the amber precisely is difficult due to its redeposited context. While the Bitterfeld amber found near
Bitterfeld Bitterfeld () is a town in the district of Anhalt-Bitterfeld, Saxony-Anhalt, Germany. Since 1 July 2007 it has been part of the town of Bitterfeld-Wolfen. It is situated approximately 25 km south of Dessau, and 30 km northeast of Hall ...
in
Saxony-Anhalt Saxony-Anhalt ( ; ) is a States of Germany, state of Germany, bordering the states of Brandenburg, Saxony, Thuringia and Lower Saxony. It covers an area of and has a population of 2.17 million inhabitants, making it the List of German states ...
, Germany, was historically considered redeposited Baltic amber, it has been found to be chemically distinct.


Baltic amber tree

It was thought since the 1850s that the
resin A resin is a solid or highly viscous liquid that can be converted into a polymer. Resins may be biological or synthetic in origin, but are typically harvested from plants. Resins are mixtures of organic compounds, predominantly terpenes. Commo ...
that became amber was produced by the tree '' Pinites succinifer'', but research in the 1980s concluded that the resin originates from several species. More recently, it has been proposed, on the evidence of
Fourier-transform infrared spectroscopy Fourier transform infrared spectroscopy (FTIR) is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. An FTIR spectrometer simultaneously collects high-resolution spectral data over a wide spectr ...
analysis of amber and resin from living trees, that conifers of the family Sciadopityaceae were responsible. The only extant representative of this family is the Japanese umbrella pine, ''
Sciadopitys verticillata ''Sciadopitys verticillata'', the or Japanese umbrella-pine, is a unique conifer Endemism, endemic to Japan, Sakhalin, and the Kuril Islands. It is the sole living member of the family Sciadopityaceae and genus ''Sciadopitys'', a living fossil ...
''.


Structure

The structure of Baltic amber (succinite) is complex. It is not a
polymer A polymer () is a chemical substance, substance or material that consists of very large molecules, or macromolecules, that are constituted by many repeat unit, repeating subunits derived from one or more species of monomers. Due to their br ...
, because it is not composed of a repeating pattern of
mers Middle East respiratory syndrome (MERS) is a viral respiratory infection caused by '' Middle East respiratory syndrome–related coronavirus'' (MERS-CoV). Symptoms may range from none, to mild, to severe depending on age and risk level. Typi ...
of the same type. Rather it has a
macromolecular A macromolecule is a "molecule of high relative molecular mass, the structure of which essentially comprises the multiple repetition of units derived, actually or conceptually, from molecules of low relative molecular mass." Polymers are physi ...
structure arranged in a crosslinked network, in which the pores (free spaces) are filled by components of molecular structure (e.g. by
mono- Numeral or number prefixes are prefixes derived from numerals or occasionally other numbers. In English and many other languages, they are used to coin numerous series of words. For example: * triangle, quadrilateral, pentagon, hexagon, oc ...
and
sesquiterpene Sesquiterpenes are a class of terpenes that consist of three isoprene units and often have the molecular formula C15H24. Like monoterpenes, sesquiterpenes may be cyclic or contain rings, including many combinations. Biochemical modifications s ...
s). Thus the chemical structure of the amber may be described as a supramolecule. The structure makes the amber denser, harder and more resistant to external factors. It also makes possible good preservation of plant and animal inclusions.


History of use

Baltic amber has been traded since the
Neolithic The Neolithic or New Stone Age (from Ancient Greek, Greek 'new' and 'stone') is an archaeological period, the final division of the Stone Age in Mesopotamia, Asia, Europe and Africa (c. 10,000 BCE to c. 2,000 BCE). It saw the Neolithic Revo ...
period in Europe, with Baltic amber being found as trade goods from 3634–3363 BC in Spain, with Baltic amber being traded to China by the time of the
Han Dynasty The Han dynasty was an Dynasties of China, imperial dynasty of China (202 BC9 AD, 25–220 AD) established by Liu Bang and ruled by the House of Liu. The dynasty was preceded by the short-lived Qin dynasty (221–206 BC ...
. Initially Baltic amber was extracted from redeposited amber in
Holocene The Holocene () is the current geologic time scale, geological epoch, beginning approximately 11,700 years ago. It follows the Last Glacial Period, which concluded with the Holocene glacial retreat. The Holocene and the preceding Pleistocene to ...
deposits, like sandbars, with large scale industrial extraction beginning in the 19th century.


Paleobiology

Numerous extinct genera and species of plants and animals have been discovered and scientifically described from inclusions in Baltic amber. Inclusions of insects make up over 98% of the animals preserved in the amber, while all other
arthropod Arthropods ( ) are invertebrates in the phylum Arthropoda. They possess an arthropod exoskeleton, exoskeleton with a cuticle made of chitin, often Mineralization (biology), mineralised with calcium carbonate, a body with differentiated (Metam ...
s,
annelid The annelids (), also known as the segmented worms, are animals that comprise the phylum Annelida (; ). The phylum contains over 22,000 extant species, including ragworms, earthworms, and leeches. The species exist in and have adapted to vario ...
s,
mollusc Mollusca is a phylum of protostome, protostomic invertebrate animals, whose members are known as molluscs or mollusks (). Around 76,000 extant taxon, extant species of molluscs are recognized, making it the second-largest animal phylum ...
s,
nematode The nematodes ( or ; ; ), roundworms or eelworms constitute the phylum Nematoda. Species in the phylum inhabit a broad range of environments. Most species are free-living, feeding on microorganisms, but many are parasitic. Parasitic worms (h ...
s,
protozoa Protozoa (: protozoan or protozoon; alternative plural: protozoans) are a polyphyletic group of single-celled eukaryotes, either free-living or parasitic, that feed on organic matter such as other microorganisms or organic debris. Historically ...
ns contribute less than 0.5% of the animals. Vertebrates are another 0.5% of the animals included and mostly are represented by mammal fur, feathers, and reptiles.


Flora


Fauna

Image:Baltic beach sand containing amber.jpg, Typical beach sand on the Baltic Sea where amber is often washed up Image:Amber Fisher.jpg, Fishing for amber at the seacoast, Mikoszewo, close to
Gdańsk Gdańsk is a city on the Baltic Sea, Baltic coast of northern Poland, and the capital of the Pomeranian Voivodeship. With a population of 486,492, Data for territorial unit 2261000. it is Poland's sixth-largest city and principal seaport. Gdań ...
, Poland Image:Colours of Baltic Amber.jpg, Different colours of Baltic amber File:Baltic amber Coleoptera Brentidae Apion 3.JPG, Fossil brentid beetle


See also

* Amber Coast *
Dominican amber Dominican amber is amber from the Dominican Republic derived from resin of the extinct tree '' Hymenaea protera''. Dominican amber differentiates itself from Baltic amber by being nearly always transparent, and it has a higher number of fossil in ...
* Japanese amber *
Rovno amber Rovno amber, occasionally called Ukrainian amber, is amber found in the Rivne Oblast and surrounding regions of Ukraine and Belarus. The amber is dated between Late Eocene and Early Oligocene, and suggested to be contemporaneous to Baltic amber ...
amber from Ukraine deposited at around the same time * Bitterfeld amber amber from Germany deposited at around the same time *
Burmese amber Burmese amber, also known as Burmite or Kachin amber, is amber from the Hukawng Valley in northern Myanmar. The amber is dated to around 100 million years ago, during the latest Albian to earliest Cenomanian ages of the mid-Cretaceous period. Th ...


References


Bibliography

* {{Commons category, Baltic amber Eocene Paleontological sites of Europe Geology of Lithuania Oligocene geology