The term structured packing refers to a range of specially designed materials for use in
absorption
Absorption may refer to:
Chemistry and biology
* Absorption (biology), digestion
**Absorption (small intestine)
*Absorption (chemistry), diffusion of particles of gas or liquid into liquid or solid materials
*Absorption (skin), a route by which ...
and
distillation columns and
chemical reactors. Structured packings typically consist of thin corrugated metal plates or gauzes arranged in a way that force
fluid
In physics, a fluid is a liquid, gas, or other material that continuously deforms (''flows'') under an applied shear stress, or external force. They have zero shear modulus, or, in simpler terms, are substances which cannot resist any shear ...
s to take complicated paths through the column, thereby creating a large surface area for contact between different
phases.
Structured packing is formed from corrugated sheets of perforated embossed metal, plastic (including
PTFE
Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemour ...
) or wire gauze. The result is a very open honeycomb structure with inclined flow channels giving a relatively high surface area but with very low resistance to gas flow. The surface enhancements have been chosen to maximize liquid spreading. These characteristics tend to show significant performance benefits in low pressure and low irrigation rate applications.
History
Structured packings have been established for several decades. The first generation of structured packing arose in the early 1940s. In 1953, a
patented packing appeared named Panapak, made of a wavy-form expanded metal sheet. The packing was not successful, due to maldistribution and lack of good marketing. The second generation appeared at the end of the 1950s, with highly efficient wire mesh packings, such as Goodloe, Hyperfil and Koch-Sulzer. Until the 1970s, due to their low pressure drop per
theoretical stage, those packings were the most widely used in vacuum distillation. However, high cost, low capacity and high sensitivity to solids have prevented wider utilization of wire mesh packings.
Corrugated structured packings, introduced by
Sulzer by the end of the 1970s, marked the third generation of structured packed columns. These packings offer high capacity, lower cost, and less sensitivity to solids, while keeping a high performance. Popularity of the packings grew in the 1980s, particularly for revamps in oil and
petrochemical plants. These structured packings, made of corrugated metal sheets, had their surfaces treated, chemically or mechanically, in order to enhance their wettability. Consequently, the packings' wetted area increased, improving performance. In 1994, a new geometry was developed, and called Optiflow. Later, in 1999, an improved structure of corrugated sheet packings, the MellapackPlus, was developed based on
CFD simulations and experiment. This new structure, compared with conventional Mellapak, has a lowered pressure drop and maximum useful capacity could be extended up to 50%.
Varieties
Structured packing is manufactured in a wide range of sizes by varying the crimp altitude. Packing surface ranges from (lowest efficiency, highest capacity) to (highest efficiency, lowest capacity).
Applications
Typical applications include vacuum and atmospheric crude oil fractionators, FCC main fractionators and TEG contactors. The separation of
mono-,
di-
Numeral or number prefixes are prefixes derived from numerals or occasionally other numbers. In English and many other languages, they are used to coin numerous series of words. For example:
* unicycle, bicycle, tricycle (1-cycle, 2-cycle, 3-cyc ...
and
triethanolamine, conducted under vacuum, may also utilize structured packing, owing to its relatively low pressure drop.
Tall oil fractionation, the process of separating fatty acids from rosin acids and pitch obtained as a by-product of the
Kraft process
The kraft process (also known as kraft pulping or sulfate process) is a process for conversion of wood into wood pulp, which consists of almost pure cellulose fibres, the main component of paper. The kraft process involves treatment of wood chip ...
of wood pulp manufacture, also utilizes structured packing. The packing additionally finds use in the manufacture of
styrene monomer and the dehydration of
glycol in natural gas processing.
Structured packing also finds use in the equipment/processes below:
*
Air separation
An air separation plant separates atmospheric air into its primary components, typically nitrogen and oxygen, and sometimes also argon and other rare inert gases.
The most common method for air separation is fractional distillation. Cryogenic air ...
*
Cyclohexanone
Cyclohexanone is the organic compound with the formula (CH2)5CO. The molecule consists of six-carbon cyclic molecule with a ketone functional group. This colorless oily liquid has an odor reminiscent of acetone. Over time, samples of cyclohexan ...
/
Cyclohexanol separation
*
Xylene splitters
*
CO2 absorbers
*
H2S absorbers
*
Ethylene oxide absorbers
*
Acrylonitrile absorbers
*
Oleo Chemicalsbr>
*
Fine Chemicalsbr>
Advantages
Structured packing offers the following advantages as compared to the use of random packing and
Continuous distillation#Plates or trays, trays:
* Lower
pressure drop
* Higher efficiency (given the same tower height)
* Higher capacity
* Reduced liquid hold-up
Disadvantages
Structured packing offers the following disadvantages as compared to the use of random packing and trays:
* Cost
* Greater sensitivity to maldistribution
See also
*
Packed bed
In chemical processing, a packed bed is a hollow tube, pipe, or other vessel that is filled with a packing material. The packing can be randomly filled with small objects like Raschig rings or else it can be a specifically designed structured ...
*
Raschig ring
*
Dixon rings
*
Random column packing
References
{{Reflist
Distillation