Strontium carbide (also more precisely known as strontium acetylide or strontium dicarbide) is a

salt In common usage, salt is a mineral composed primarily of sodium chloride (NaCl). When used in food, especially in granulated form, it is more formally called table salt. In the form of a natural crystalline mineral, salt is also known as r ...

with chemical formula . It was first synthesized by Moissan in 1894. It consists of

strontium Strontium is a chemical element; it has symbol Sr and atomic number 38. An alkaline earth metal, it is a soft silver-white yellowish metallic element that is highly chemically reactive. The metal forms a dark oxide layer when it is exposed to ...

cations An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

and

acetylide In chemistry, an acetylide is a compound that can be viewed as the result of replacing one or both hydrogen atoms of acetylene (ethyne) by metallic or other cations. Calcium carbide is an important industrial compound, which has long been used ...

anions An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by convent ...

. Strontium carbide can be formed in an

electric arc furnace An electric arc furnace (EAF) is a Industrial furnace, furnace that heats material by means of an electric arc. Industrial arc furnaces range in size from small units of approximately one-tonne capacity (used in foundry, foundries for producin ...

from

strontium carbonate Strontium carbonate (SrCO3) is the carbonate salt of strontium that has the appearance of a white or grey powder. It occurs in nature as the mineral strontianite. Chemical properties Strontium carbonate is a white, odorless, tasteless powder ...

and a reductant, such as a

reducing sugar A reducing sugar is any sugar that is capable of acting as a reducing agent. In an alkaline solution, a reducing sugar forms some aldehyde or ketone, which allows it to act as a reducing agent, for example in Benedict's reagent. In such a react ...

magnesium Magnesium is a chemical element; it has Symbol (chemistry), symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 ...

metal. Alternatively,

carbothermal reduction Carbothermic reactions involve the reduction of substances, often metal oxides (O2-), using carbon (C) as the reducing agent. The reduction is usually conducted in the electric arc furnace or reverberatory furnace, depending on the metal ore. Thes ...

strontium oxide Strontium oxide or strontia, SrO, is formed when strontium reacts with oxygen. Burning strontium in air results in a mixture of strontium oxide and strontium nitride. It also forms from the decomposition of strontium carbonate SrCO3. It is a st ...

with graphite begins around 150 °C and is

catalyzed Catalysis () is the increase in rate of a chemical reaction due to an added substance known as a catalyst (). Catalysts are not consumed by the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recycles quick ...

calcium oxide Calcium oxide (formula: Ca O), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term '' lime'' connotes calcium-containing ...

. Classical

organic chemistry Organic chemistry is a subdiscipline within chemistry involving the science, scientific study of the structure, properties, and reactions of organic compounds and organic matter, organic materials, i.e., matter in its various forms that contain ...

syntheses include

transmetallation Transmetalation (alt. spelling: transmetallation) is a type of organometallic reaction that involves the transfer of ligands from one metal to another. It has the general form: :M1–R + M2–R′ → M1–R′ + M2–R where R and R′ can be, but ...

from

mercury acetylide Mercury most commonly refers to: * Mercury (planet), the closest planet to the Sun * Mercury (element), a chemical element * Mercury (mythology), a Roman deity Mercury or The Mercury may also refer to: Companies * Mercury (toy manufacturer), ...

or an acid-base reaction between di

benzyl In organic chemistry, benzyl is the substituent or molecular fragment possessing the structure . Benzyl features a benzene ring () attached to a methylene group (). Nomenclature In IUPAC nomenclature, the prefix benzyl refers to a substituent ...

strontium and

acetylene Acetylene (Chemical nomenclature, systematic name: ethyne) is a chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is u ...

, although these techniques often produce complexes with the solvent. Direct formation from the elements has a notional

enthalpy Enthalpy () is the sum of a thermodynamic system's internal energy and the product of its pressure and volume. It is a state function in thermodynamics used in many measurements in chemical, biological, and physical systems at a constant extern ...

of −20 kcal/mol. Nevertheless, strontium carbide may be only

metastable In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is onl ...

when encapsulated in a fullerene. It slowly

hydrolyze Hydrolysis (; ) is any chemical reaction in which a molecule of water breaks one or more chemical bonds. The term is used broadly for substitution, elimination, and solvation reactions in which water is the nucleophile. Biological hydrolysis ...

s in air to

. The material is polymorphic, forming a

monoclinic crystal structure In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic sys ...

akin to

calcium carbide Calcium carbide, also known as calcium acetylide, is a chemical compound with the chemical formula of . Its main use industrially is in the production of acetylene and calcium cyanamide. The pure material is colorless, while pieces of technica ...

II and a

black Black is a color that results from the absence or complete absorption of visible light. It is an achromatic color, without chroma, like white and grey. It is often used symbolically or figuratively to represent darkness.Eva Heller, ''P ...

tetragonal In crystallography, the tetragonal crystal system is one of the 7 crystal systems. Tetragonal crystal lattices result from stretching a cubic lattice along one of its lattice vectors, so that the Cube (geometry), cube becomes a rectangular Pri ...

phase. Heated to 370 °C, it reversibly converts to a

face-centered cubic In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties o ...

(fcc) lattice. Yttrium carbide retains the fcc lattice down to

room temperature Room temperature, colloquially, denotes the range of air temperatures most people find comfortable indoors while dressed in typical clothing. Comfortable temperatures can be extended beyond this range depending on humidity, air circulation, and ...

; the difference is a 3''e_g'' orbital that strontium lacks the electrons to fill.

Cyanamide Cyanamide is an organic compound with the formula C N2 H2. This white solid is widely used in agriculture and the production of pharmaceuticals and other organic compounds. It is also used as an alcohol-deterrent drug. The molecule features a ...

impurities stabilize one other strontium carbide polymorph, just as they do for calcium carbide. The stabilized calcium carbide polymorph is

triclinic class=skin-invert-image, 180px, Triclinic (a ≠ b ≠ c ≠ a and α, β, γ, 90° pairwise different) In crystallography, the triclinic (or anorthic) crystal system is one of the seven crystal systems. A crystal system is described by three b ...

, and the strontium carbide polymorph is believed to be so as well. At roughly 1800 °C, strontium carbide melts. It forms a

solid solution A solid solution, a term popularly used for metals, is a homogeneous mixture of two compounds in solid state and having a single crystal structure. Many examples can be found in metallurgy, geology, and solid-state chemistry. The word "solutio ...

with europium carbide, as has an almost identical

ionic radius Ionic radius, ''r''ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cati ...

to . Strontium carbide is a

chemical intermediate In chemistry, a reaction intermediate, or intermediate, is a molecular entity arising within the sequence of a stepwise chemical reaction. It is formed as the reaction product of an elementary step, from the reactants and/or preceding intermedi ...

in an archaic

carbon-14 dating Radiocarbon dating (also referred to as carbon dating or carbon-14 dating) is a method for Chronological dating, determining the age of an object containing organic material by using the properties of carbon-14, radiocarbon, a radioactive Isotop ...

technique: burning the material to be dated releases

carbon dioxide Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...

, trapped as

. Magnesium then reduces the carbonate to strontium carbide and hydrolysis releases acetylene. The radioactive decay of the acetylene can then be observed directly or heating to 600 °C polymerizes the acetylene to

benzene Benzene is an Organic compound, organic chemical compound with the Chemical formula#Molecular formula, molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar hexagonal Ring (chemistry), ring with one hyd ...

for a liquid scintillator. Solid state metathesis of strontium carbide and a (complex) metal

oxide An oxide () is a chemical compound containing at least one oxygen atom and one other element in its chemical formula. "Oxide" itself is the dianion (anion bearing a net charge of −2) of oxygen, an O2− ion with oxygen in the oxidation st ...

gives the corresponding metal

carbide In chemistry, a carbide usually describes a compound composed of carbon and a metal. In metallurgy, carbiding or carburizing is the process for producing carbide coatings on a metal piece. Interstitial / Metallic carbides The carbides of th ...

and strontium oxide. The latter washes away easily in pure water.

References

{{cite journal, first1=V. P., last1=Zhukov, first2=D. L., last2=Novikov, first3=N. I., last3=Medvedeva, first4=V. A., last4=Gubanov, doi=10.1007/BF00751445, title=Electronic structure and chemical bonding in yttrium dicarbide and strontium dicarbide, id=UDC 541.19, journal=Zhurnal Strukturnoi Khimii, volume=30, issue=4, pages=27–32, date=July–August 1989, orig-date=25 December 1987, publication-date=1990, publisher=Plenum, bibcode=1989JStCh..30..553Z Strontium compounds Acetylides