Stretched Exponential
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The stretched exponential function f_\beta (t) = e^ is obtained by inserting a fractional
power law In statistics, a power law is a Function (mathematics), functional relationship between two quantities, where a Relative change and difference, relative change in one quantity results in a relative change in the other quantity proportional to the ...
into the exponential function. In most applications, it is meaningful only for arguments between 0 and +∞. With , the usual exponential function is recovered. With a ''stretching exponent'' ''β'' between 0 and 1, the graph of log ''f'' versus ''t'' is characteristically ''stretched'', hence the name of the function. The compressed exponential function (with ) has less practical importance, with the notable exceptions of , which gives the
normal distribution In probability theory and statistics, a normal distribution or Gaussian distribution is a type of continuous probability distribution for a real-valued random variable. The general form of its probability density function is f(x) = \frac ...
, and of compressed exponential relaxation in the dynamics of
amorphous solids In condensed matter physics and materials science, an amorphous solid (or non-crystalline solid) is a solid that lacks the long-range order that is a characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymo ...
. In mathematics, the stretched exponential is also known as the complementary cumulative
Weibull distribution In probability theory and statistics, the Weibull distribution is a continuous probability distribution. It models a broad range of random variables, largely in the nature of a time to failure or time between events. Examples are maximum on ...
. The stretched exponential is also the
characteristic function In mathematics, the term "characteristic function" can refer to any of several distinct concepts: * The indicator function of a subset, that is the function \mathbf_A\colon X \to \, which for a given subset ''A'' of ''X'', has value 1 at points ...
, basically the
Fourier transform In mathematics, the Fourier transform (FT) is an integral transform that takes a function as input then outputs another function that describes the extent to which various frequencies are present in the original function. The output of the tr ...
, of the Lévy symmetric alpha-stable distribution. In physics, the stretched exponential function is often used as a phenomenological description of relaxation in disordered systems. It was first introduced by
Rudolf Kohlrausch Rudolf Hermann Arndt Kohlrausch (November 6, 1809 in Göttingen – March 8, 1858 in Erlangen) was a German physicist. Biography He was a native of Göttingen, the son of the Royal Hanovarian director general of schools Friedrich Kohlrausch. He ...
in 1854 to describe the discharge of a capacitor; thus it is also known as the Kohlrausch function. In 1970, G. Williams and D.C. Watts used the
Fourier transform In mathematics, the Fourier transform (FT) is an integral transform that takes a function as input then outputs another function that describes the extent to which various frequencies are present in the original function. The output of the tr ...
of the stretched exponential to describe dielectric spectra of polymers; in this context, the stretched exponential or its Fourier transform are also called the Kohlrausch–Williams–Watts (KWW) function. The Kohlrausch–Williams–Watts (KWW) function corresponds to the time domain charge response of the main dielectric models, such as the
Cole–Cole equation The Cole–Cole equation is a relaxation model that is often used to describe dielectric relaxation in polymers. It is given by the equation : \varepsilon^*(\omega) = \varepsilon_\infty + \frac where \varepsilon^* is the complex dielectric co ...
, the Cole–Davidson equation, and the Havriliak–Negami relaxation, for small time arguments. In phenomenological applications, it is often not clear whether the stretched exponential function should be used to describe the differential or the integral distribution function—or neither. In each case, one gets the same asymptotic decay, but a different power law prefactor, which makes fits more ambiguous than for simple exponentials. In a few cases, it can be shown that the asymptotic decay is a stretched exponential, but the prefactor is usually an unrelated power.


Mathematical properties


Moments

Following the usual physical interpretation, we interpret the function argument ''t'' as time, and ''f''β(''t'') is the differential distribution. The area under the curve can thus be interpreted as a ''mean relaxation time''. One finds \langle\tau\rangle \equiv \int_0^\infty dt\, e^ = \Gamma where is the
gamma function In mathematics, the gamma function (represented by Γ, capital Greek alphabet, Greek letter gamma) is the most common extension of the factorial function to complex numbers. Derived by Daniel Bernoulli, the gamma function \Gamma(z) is defined ...
. For
exponential decay A quantity is subject to exponential decay if it decreases at a rate proportional to its current value. Symbolically, this process can be expressed by the following differential equation, where is the quantity and (lambda Lambda (; uppe ...
, is recovered. The higher moments of the stretched exponential function are \langle\tau^n\rangle \equiv \int_0^\infty dt\, t^\, e^ = \Gamma .


Distribution function

In physics, attempts have been made to explain stretched exponential behaviour as a linear superposition of simple exponential decays. This requires a nontrivial distribution of relaxation times, ''ρ''(''u''), which is implicitly defined by e^ = \int_0^\infty du\,\rho(u)\, e^. Alternatively, a distribution G = u \rho (u) is used. ''ρ'' can be computed from the series expansion: \rho (u ) = - \sum_^\infty \sin (\pi \beta k)\Gamma (\beta k + 1) u^ For rational values of ''β'', ''ρ''(''u'') can be calculated in terms of elementary functions. But the expression is in general too complex to be useful except for the case where G(u) = u \rho(u) = \sqrt e^ Figure 2 shows the same results plotted in both a
linear In mathematics, the term ''linear'' is used in two distinct senses for two different properties: * linearity of a '' function'' (or '' mapping''); * linearity of a '' polynomial''. An example of a linear function is the function defined by f(x) ...
and a
log Log most often refers to: * Trunk (botany), the stem and main wooden axis of a tree, called logs when cut ** Logging, cutting down trees for logs ** Firewood, logs used for fuel ** Lumber or timber, converted from wood logs * Logarithm, in mathe ...
representation. The curves converge to a
Dirac delta function In mathematical analysis, the Dirac delta function (or distribution), also known as the unit impulse, is a generalized function on the real numbers, whose value is zero everywhere except at zero, and whose integral over the entire real line ...
peaked at as ''β'' approaches 1, corresponding to the simple exponential function. The moments of the original function can be expressed as \langle\tau^n\rangle = \Gamma(n) \int_0^\infty d\tau\, t^n \, \rho(\tau). The first logarithmic moment of the distribution of simple-exponential relaxation times is \langle\ln\tau\rangle = \left( 1 - \right) + \ln \tau_K where Eu is the
Euler constant Euler's constant (sometimes called the Euler–Mascheroni constant) is a mathematical constant, usually denoted by the lowercase Greek letter gamma (), defined as the limiting difference between the harmonic series and the natural logarith ...
.


Fourier transform

To describe results from spectroscopy or inelastic scattering, the sine or cosine Fourier transform of the stretched exponential is needed. It must be calculated either by numeric integration, or from a series expansion. The series here as well as the one for the distribution function are special cases of the
Fox–Wright function In mathematics, the Fox–Wright function (also known as Fox–Wright Psi function, not to be confused with Wright Omega function) is a generalisation of the generalised hypergeometric function ''p'F'q''(''z'') based on ideas of and : _p\ ...
. For practical purposes, the Fourier transform may be approximated by the Havriliak–Negami function, though nowadays the numeric computation can be done so efficiently that there is no longer any reason not to use the Kohlrausch–Williams–Watts function in the frequency domain.


History and further applications

As said in the introduction, the stretched exponential was introduced by the
German German(s) may refer to: * Germany, the country of the Germans and German things **Germania (Roman era) * Germans, citizens of Germany, people of German ancestry, or native speakers of the German language ** For citizenship in Germany, see also Ge ...
physicist A physicist is a scientist who specializes in the field of physics, which encompasses the interactions of matter and energy at all length and time scales in the physical universe. Physicists generally are interested in the root or ultimate cau ...
Rudolf Kohlrausch Rudolf Hermann Arndt Kohlrausch (November 6, 1809 in Göttingen – March 8, 1858 in Erlangen) was a German physicist. Biography He was a native of Göttingen, the son of the Royal Hanovarian director general of schools Friedrich Kohlrausch. He ...
in 1854 to describe the discharge of a capacitor (
Leyden jar A Leyden jar (or Leiden jar, or archaically, Kleistian jar) is an electrical component that stores a high-voltage electric charge (from an external source) between electrical conductors on the inside and outside of a glass jar. It typically co ...
) that used glass as dielectric medium. The next documented usage is by Friedrich Kohlrausch, son of Rudolf, to describe torsional relaxation. A. Werner used it in 1907 to describe complex luminescence decays;
Theodor Förster Theodor Förster (15 May 1910 – 20 May 1974) was a German Physical chemistry, physical chemist known for theoretical work on light-matter interaction in molecular systems such as fluorescence and Förster resonance energy transfer, resonant ener ...
in 1949 as the fluorescence decay law of electronic energy donors. Outside
condensed matter physics Condensed matter physics is the field of physics that deals with the macroscopic and microscopic physical properties of matter, especially the solid and liquid State of matter, phases, that arise from electromagnetic forces between atoms and elec ...
, the stretched exponential has been used to describe the removal rates of small, stray bodies in the solar system, the diffusion-weighted MRI signal in the brain, and the production from unconventional gas wells.


In probability

If the integrated distribution is a stretched exponential, the normalized
probability density function In probability theory, a probability density function (PDF), density function, or density of an absolutely continuous random variable, is a Function (mathematics), function whose value at any given sample (or point) in the sample space (the s ...
is given by p(\tau \mid \lambda, \beta)~d\tau = \frac ~ e^ ~ d\tau Note that confusingly some authors have been known to use the name "stretched exponential" to refer to the
Weibull distribution In probability theory and statistics, the Weibull distribution is a continuous probability distribution. It models a broad range of random variables, largely in the nature of a time to failure or time between events. Examples are maximum on ...
.


Modified functions

A modified stretched exponential function f_\beta (t) = e^ with a slowly ''t''-dependent exponent ''β'' has been used for biological survival curves.


Wireless Communications

In wireless communications, a scaled version of the stretched exponential function has been shown to appear in the Laplace Transform for the interference power I when the transmitters' locations are modeled as a 2D
Poisson Point Process In probability theory, statistics and related fields, a Poisson point process (also known as: Poisson random measure, Poisson random point field and Poisson point field) is a type of mathematical object that consists of points randomly located ...
with no exclusion region around the receiver. The
Laplace transform In mathematics, the Laplace transform, named after Pierre-Simon Laplace (), is an integral transform that converts a Function (mathematics), function of a Real number, real Variable (mathematics), variable (usually t, in the ''time domain'') to a f ...
can be written for arbitrary
fading In wireless communications, fading is the variation of signal attenuation over variables like time, geographical position, and radio frequency. Fading is often modeled as a random process. In wireless systems, fading may either be due to mul ...
distribution as follows: L_I(s) = \exp\left(-\pi \lambda \mathbb \Gamma s^\frac\right) = \exp\left(- t s^\beta \right) where g is the power of the fading, \eta is the path loss exponent, \lambda is the density of the 2D Poisson Point Process, \Gamma(\cdot) is the Gamma function, and \mathbb /math> is the expectation of the variable x. The same reference also shows how to obtain the inverse Laplace Transform for the stretched exponential \exp\left(-s^\beta \right) for higher order integer \beta = \beta_q \beta_b from lower order integers \beta_a and \beta_b.


Internet Streaming

The stretched exponential has been used to characterize Internet media accessing patterns, such as YouTube and other stable
streaming media Streaming media refers to multimedia delivered through a Computer network, network for playback using a Media player (disambiguation), media player. Media is transferred in a ''stream'' of Network packet, packets from a Server (computing), ...
sites. The commonly agreed power-law accessing patterns of Web workloads mainly reflect text-based content Web workloads, such as daily updated news sites.


References


External links

* J. Wuttke
libkww
C library to compute the Fourier transform of the stretched exponential function {{DEFAULTSORT:Stretched Exponential Function Exponentials