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The Stefan–Boltzmann constant (also Stefan's constant), a
physical constant A physical constant, sometimes fundamental physical constant or universal constant, is a physical quantity that is generally believed to be both universal in nature and have constant value in time. It is contrasted with a mathematical constant, ...
denoted by the Greek letter ''σ'' (sigma), is the constant of proportionality in the Stefan–Boltzmann law: "the total intensity radiated over all wavelengths increases as the temperature increases", of a
black body A black body or blackbody is an idealized physical object, physical body that absorption (electromagnetic radiation), absorbs all incident electromagnetic radiation, regardless of frequency or angle of incidence (optics), angle of incidence. T ...
which is proportional to the fourth power of the
thermodynamic temperature Thermodynamic temperature is a quantity defined in thermodynamics as distinct from kinetic theory or statistical mechanics. Historically, thermodynamic temperature was defined by Kelvin in terms of a macroscopic relation between thermodynamic ...
. The theory of
thermal radiation Thermal radiation is electromagnetic radiation generated by the thermal motion of particles in matter. Thermal radiation is generated when heat from the movement of charges in the material (electrons and protons in common forms of matter) is ...
lays down the theory of
quantum mechanics Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
, by using physics to relate to molecular, atomic and sub-atomic levels. Slovenian physicist Josef Stefan formulated the constant in 1879; it was formally derived in 1884 by his former student and collaborator, the Austrian physicist Ludwig Boltzmann. The equation can also be derived from
Planck's law In physics, Planck's law describes the spectral density of electromagnetic radiation emitted by a black body in thermal equilibrium at a given temperature , when there is no net flow of matter or energy between the body and its environment. A ...
, by integrating over all wavelengths at a given temperature, which will represent a small flat black body box. "The amount of thermal radiation emitted increases quickly and the principal frequency of the radiation becomes higher with increasing temperatures". The Stefan–Boltzmann constant can be used to measure the amount of heat that is emitted by a black body, which absorbs all of the radiant energy that hits it, and will emit all the radiant energy. Furthermore, the Stefan–Boltzmann constant allows for temperature (K) to be converted to units for intensity (W⋅m−2), which is power per unit area.


Value

Since the
2019 redefinition of the SI base units In 2019, four of the seven SI base units specified in the International System of Quantities were redefined in terms of natural physical constants, rather than human artifacts such as the standard kilogram. Effective 20 May 2019, the 144th ...
, the Stefan–Boltzmann constant is given exactly rather than in experimental values. The value is given in
SI units The International System of Units, known by the international abbreviation SI in all languages and sometimes pleonastically as the SI system, is the modern form of the metric system and the world's most widely used system of measurement. E ...
by In cgs units the Stefan–Boltzmann constant is In
thermochemistry Thermochemistry is the study of the heat energy which is associated with chemical reactions and/or phase changes such as melting and boiling. A reaction may release or absorb energy, and a phase change may do the same. Thermochemistry focuses on ...
the Stefan–Boltzmann constant is often expressed in
cal Cal or CAL may refer to: Arts and entertainment * ''Cal'' (novel), a 1983 novel by Bernard MacLaverty * "Cal" (short story), a science fiction short story by Isaac Asimov * ''Cal'' (1984 film), an Irish drama starring John Lynch and Helen Mir ...
cm−2
day A day is the time period of a full rotation of the Earth with respect to the Sun. On average, this is 24 hours, 1440 minutes, or 86,400 seconds. In everyday life, the word "day" often refers to a solar day, which is the length between two so ...
−1K−4: In US customary units the Stefan–Boltzmann constant is The Stefan–Boltzmann constant is defined in terms of other fundamental constants as \sigma = \frac = \frac\,, where *''k''B is the
Boltzmann constant The Boltzmann constant ( or ) is the proportionality factor that relates the average relative kinetic energy of particles in a gas with the thermodynamic temperature of the gas. It occurs in the definitions of the kelvin and the gas consta ...
, *''h'' is the
Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
, *''ħ'' is the
reduced Planck constant The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
, and *''c'' is the
speed of light The speed of light in vacuum, commonly denoted , is a universal physical constant that is important in many areas of physics. The speed of light is exactly equal to ). According to the special theory of relativity, is the upper limit fo ...
in vacuum, giving :\sigma = \frac\, \mathrm\cdot\mathrm^\cdot\mathrm^\cdot\mathrm^ The
CODATA The Committee on Data of the International Science Council (CODATA) was established in 1966 as the Committee on Data for Science and Technology, originally part of the International Council of Scientific Unions, now part of the International ...
recommended value prior to 20 May 2019 (2018 CODATA) was calculated from the measured value of the
gas constant The molar gas constant (also known as the gas constant, universal gas constant, or ideal gas constant) is denoted by the symbol or . It is the molar equivalent to the Boltzmann constant, expressed in units of energy per temperature increment p ...
: \sigma = \frac = \frac , where *''R'' is the universal gas constant *''N''A is the Avogadro constant *''R'' is the
Rydberg constant In spectroscopy, the Rydberg constant, symbol R_\infty for heavy atoms or R_\text for hydrogen, named after the Swedish physicist Johannes Rydberg, is a physical constant relating to the electromagnetic spectra of an atom. The constant first a ...
*''A''r(e) is the "
relative atomic mass Relative atomic mass (symbol: ''A''; sometimes abbreviated RAM or r.a.m.), also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a give ...
" of the
electron The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family, and are generally thought to be elementary partic ...
*''M''u is the molar mass constant (1 g/mol by definition) *''α'' is the fine-structure constant. Dimensional formula: M1T−3Θ−4 A related constant is the radiation constant (or radiation density constant) a, which is given byRadiation constant
from ScienceWorld a = \frac = 7.5657 \times 10^ \mathrm = 7.5657 \times 10^ \mathrm.


References


External links

* {{DEFAULTSORT:Stefan-Boltzmann constant Physical constants Thermodynamics Ludwig Boltzmann de:Stefan-Boltzmann-Gesetz