Starting fluid is a
volatile,
flammable liquid
A flammable liquid is a liquid which can be easily ignited in air at ambient temperatures, i.e. it has a flash point at or below nominal threshold temperatures defined by a number of national and international standards organisations.
The Occup ...
which is used to aid the starting of
internal combustion engine
An internal combustion engine (ICE or IC engine) is a heat engine in which the combustion of a fuel occurs with an oxidizer (usually air) in a combustion chamber that is an integral part of the working fluid flow circuit. In an internal comb ...
s, especially during cold weather or in engines that are difficult to start using conventional starting procedures. It is typically available in an
aerosol spray
Aerosol spray is a type of dispensing system which creates an aerosol mist of liquid particles. It comprises a can or bottle that contains a payload, and a propellant under pressure. When the container's valve is opened, the payload is forced out ...
can, and may sometimes be used for starting direct injected diesel engines or
lean burn
Lean-burn refers to the burning of fuel with an excess of air in an internal combustion engine. In lean-burn engines the air–fuel ratio may be as lean as 65:1 (by mass). The air:fuel ratio needed to stoichiometry, stoichiometrically combust gas ...
spark engines running on
alcohol fuel
Various alcohols are used as fuel for internal combustion engines. The first four aliphatic alcohols (methanol, ethanol, propanol, and butanol) are of interest as fuels because they can be synthesized chemically or biologically, and they have ...
. Some modern starting fluid products contain mostly volatile
hydrocarbon
In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and Hydrophobe, hydrophobic; their odor is usually fain ...
s such as
heptane
Heptane or ''n''-heptane is the straight-chain alkane with the chemical formula H3C(CH2)5CH3 or C7H16. When used as a test fuel component in anti-knock test engines, a 100% heptane fuel is the zero point of the octane rating scale (the 100 poi ...
(the main component of natural gasoline), with a small portion of
diethyl ether
Diethyl ether, or simply ether, is an organic compound with the chemical formula , sometimes abbreviated as . It is a colourless, highly Volatility (chemistry), volatile, sweet-smelling ("ethereal odour"), extremely flammable liquid. It belongs ...
, and
carbon dioxide
Carbon dioxide is a chemical compound with the chemical formula . It is made up of molecules that each have one carbon atom covalent bond, covalently double bonded to two oxygen atoms. It is found in a gas state at room temperature and at norma ...
(as a propellant). Some formulations contain
butane
Butane () is an alkane with the formula C4H10. Butane exists as two isomers, ''n''-butane with connectivity and iso-butane with the formula . Both isomers are highly flammable, colorless, easily liquefied gases that quickly vaporize at ro ...
or
propane
Propane () is a three-carbon chain alkane with the molecular formula . It is a gas at standard temperature and pressure, but becomes liquid when compressed for transportation and storage. A by-product of natural gas processing and petroleum ref ...
as both propellant and starting fuel. Historically, diethyl ether, with a small amount of oil, a trace amount of a
stabilizer and a hydrocarbon propellant has been used to help start internal combustion engines because of its low
autoignition temperature
The autoignition temperature or self-ignition temperature, often called spontaneous ignition temperature or minimum ignition temperature (or shortly ignition temperature) and formerly also known as kindling point, of a substance is the lowest tem ...
.
Diethyl ether is distinct from
petroleum ether
Petroleum ether is the petroleum fraction consisting of aliphatic hydrocarbons and boiling in the range 35–60 °C, and commonly used as a laboratory solvent. Despite the name, petroleum ether is not an ether; the term is used only figurativ ...
(a crude oil distillate consisting mostly of
pentane
Pentane is an organic compound with the chemical formula, formula C5H12—that is, an alkane with five carbon atoms. The term may refer to any of three structural isomerism, structural isomers, or to a mixture of them: in the IUPAC nomenclature, h ...
and other
alkanes
In organic chemistry, an alkane, or paraffin (a historical trivial name that also has other meanings), is an acyclic saturated hydrocarbon. In other words, an alkane consists of hydrogen and carbon atoms arranged in a tree structure in whi ...
) which has also been used for starting engines.
Usage
Four stroke engines
Starting fluid is sprayed into the engine intake near the air filter, or into the carburetor bore or a spark plug hole of an engine to get added fuel to the combustion cylinder quickly. Using starting fluid to get the engine running faster avoids wear to starters and fatigue to one's arm with pull start engines, especially on rarely used machines. Other uses include cold weather starting, vehicles that run out of fuel and thus require extra time to restore fuel pressure, and sometimes with
flooded engine
A flooded engine is an internal combustion engine that has been fed an excessively rich air-fuel mixture that cannot be ignited. This is caused by the mixture exceeding the upper explosive limit for the particular fuel. An engine in this condition ...
s. Mechanics sometimes use it to diagnose starting problems by determining whether the spark and ignition system of the vehicle is functioning; if the spark is adequate but the fuel delivery system is not, the engine will run until the starting fluid vapors are consumed. It is used more often with
carbureted engines than with
fuel injection
Fuel injection is the introduction of fuel in an internal combustion engine, most commonly automotive engines, by the means of a fuel injector. This article focuses on fuel injection in reciprocating piston and Wankel rotary engines.
All c ...
systems. Caution is required when using starting fluid with
diesel engines that have preheat systems in the intake or glow-plugs installed, as the starting fluid may pre-ignite, leading to engine damage.
Two stroke engines
Starting fluid is not recommended for regular use with some
two-stroke engines
A two-stroke (or two-stroke cycle) engine is a type of internal combustion engine that completes a Thermodynamic power cycle, power cycle with two strokes of the piston, one up and one down, in one revolution of the crankshaft in contrast to a f ...
because it does not possess lubricating qualities by itself.
Lubrication for two-stroke engines is achieved using oil that is either mixed into the fuel by the user or injected automatically into the fuel supply; engines requiring premixed fuel that are run solely on starting fluid do not receive an adequate supply of lubrication to their crankcase and cylinder(s). Engines that haven't been run recently are especially vulnerable to damage from oil starvation; starting fluid, a strong solvent, tends to strip residual oil off of cranks and cylinder walls, further reducing lubrication during the period of fuel starvation.
WD-40
WD-40 (Water Displacement, 40th formula) is an American manufacturer and the trademark of a penetrating oil manufactured by the WD-40 Company based in San Diego, California. Its formula was invented for the Rocket Chemical Company in 1953, ...
was previously recommended for use on two stroke engines because it has lubricating qualities,
but the formulation with non-flammable CO
2 as propellant instead of propane no longer has the same combustible nature, making it useless as starting fluid on any type of engine.
Abuse
Diethyl ether has a long history as a medical
anesthetic
An anesthetic (American English) or anaesthetic (British English; see spelling differences) is a drug used to induce anesthesia — in other words, to result in a temporary loss of sensation or awareness. They may be divided into t ...
; when starting fluid was mostly ether, a similar effect could be obtained using it. Use at the present time directly as an
inhalant includes the effect of the petroleum solvents, which are more toxic as inhalants than diethyl ether.
Sometimes referred to as "passing the shirt," the starting fluid is sprayed on a piece of cloth and held up to one's face for inhalation. This trend has gradually picked up since the turn of the century, as phrases such as "etherized" and "ethervision" have gained popularity. The effects of inhalation vary, but have been known to include lightheadedness, loss of coordination, paranoia, and sometimes hallucinations.
References
{{Reflist
Fuels