
Starlite is an
intumescent
An intumescent is a substance that swells as a result of heat exposure, leading to an increase in volume and decrease in density. Intumescent materials are typically used in passive fire protection and require listing, approval, and compliance in ...
material said to be able to withstand and
insulate from extreme heat. It was invented by British hairdresser and amateur chemist
Maurice Ward (1933–2011) during the 1970s and 1980s, and received significant publicity after coverage of the material aired in 1990 on the BBC science and technology show ''
Tomorrow's World''. The name Starlite was coined by Ward's granddaughter Kimberly.
The American company Thermashield, LLC said it acquired the rights to Starlite in 2013 and replicated it.
It is the only company to have itself publicly demonstrated the technology and have samples tested by third parties. Thermashield's Starlite has successfully passed
femtosecond
A femtosecond is a unit of time in the International System of Units (SI) equal to 10 or of a second; that is, one quadrillionth, or one millionth of one billionth, of a second. For context, a femtosecond is to a second as a second is to about 3 ...
laser testing at the
Georgia Institute of Technology
The Georgia Institute of Technology, commonly referred to as Georgia Tech or, in the state of Georgia, as Tech or The Institute, is a public research university and institute of technology in Atlanta, Georgia. Established in 1885, it is part of ...
and ASTM D635-15 Standard Testing.
Properties
Live demonstrations on ''
Tomorrow's World'' and
BBC Radio 4
BBC Radio 4 is a British national radio station owned and operated by the BBC that replaced the BBC Home Service in 1967. It broadcasts a wide variety of Talk radio, spoken-word programmes, including news, drama, comedy, science and history fro ...
showed that an egg coated in Starlite could remain raw, and cold enough to be picked up with a bare hand, even after five minutes in the flame of an
oxyacetylene
Principle of burn cutting
Oxy-fuel welding (commonly called oxyacetylene welding, oxy welding, or gas welding in the United States) and oxy-fuel cutting are processes that use fuel gases (or liquid fuels such as gasoline or petrol, diesel, ...
blowtorch
A blowtorch, also referred to as a blowlamp, is an ambient air fuel-burning gas lamp used for applying flame and heat to various applications, usually metalworking.
Early blowtorches used liquid fuel, carried in a refillable reservoir attache ...
. It would also prevent a blowtorch from damaging a human hand.
When heat is applied, the material
chars
Chars () is a commune in the Val-d'Oise department in Île-de-France in northern France. It is located in the .
Education
Chars has a single preschool, école maternelle des Tournesols, and a single elementary school, ecole elementaire de chars. ...
, which creates an expanding low density carbon foam which is very
thermally resistant.
Even the application of a
plasma torch
A plasma torch (also known as a plasma arc, plasma gun, plasma cutter, or plasmatron) is a device for generating a directed flow of plasma.
The plasma jet can be used for applications including plasma cutting, plasma arc welding, plasma spra ...
, capable of cutting eighteen-inch thick steel plate, has little impact on Starlite. It was reported that it took nine seconds to heat a warhead to 900 °C, but a thin layer of the compound prevented the temperature from rising above 40 °C.
Starlite was also claimed to have been able to withstand a laser beam that could produce a temperature of 10,000 °C.
Starlite reacts more efficiently as more heat is applied. The
MOD's report, as published in
Jane's
Jane's Information Group, now styled Janes, is a global open-source intelligence company specialising in military, national security, aerospace and transport topics, whose name derives from British author Fred T. Jane.
History
Jane's Informat ...
International Defence Review 4/1993, speculated this was due to particle scatter of an ablative layer, thereby increasing the reflective properties of the compound. Testing continues for
thermal conductivity
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by k, \lambda, or \kappa.
Heat transfer occurs at a lower rate in materials of low thermal conductivity than in materials of high thermal ...
and
capacity under different conditions. Contamination with dust residue may occur, and so show degradation with use. Keith Lewis, a retired MOD officer, noted that the material only guards against thermal damage and not the physical damage caused by an
explosion
An explosion is a rapid expansion in volume associated with an extreme outward release of energy, usually with the generation of high temperatures and release of high-pressure gases. Supersonic explosions created by high explosives are kno ...
, which can destroy the insulating layer.
Materials scientist Mark Miodownik described Starlite as a type of
intumescent paint, and one of the materials he would most like to see for himself.
He also admitted some doubt about the commercial potential of Starlite.
Its main use appears to be as a
flame retardant
The term flame retardants subsumes a diverse group of chemicals that are added to manufactured materials, such as plastics and textiles, and surface finishes and coatings. Flame retardants are activated by the presence of an ignition source a ...
. Testing of modern
composite materials
A composite material (also called a composition material or shortened to composite, which is the common name) is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or ...
enhanced with Starlite could expand the range of potential uses and applications of this substance.
Composition
Starlite's composition is a closely guarded secret. "The actual composition of Starlite is known only to Maurice and one or two members of his family," former
Chief Scientific Adviser to the Ministry of Defence The Chief Scientific Adviser to the UK's Ministry of Defence is responsible for providing strategic management of science and technology issues in the MOD, most directly through the MOD research budget of well over £1 billion, and sits as a full me ...
Sir Ronald Mason averred.
It is said to contain a variety of
organic polymer
A polymer (; Greek ''poly-'', "many" + ''-mer'', "part")
is a substance or material consisting of very large molecules called macromolecules, composed of many repeating subunits. Due to their broad spectrum of properties, both synthetic and ...
s and
co-polymer
In polymer chemistry, a copolymer is a polymer derived from more than one species of monomer. The polymerization of monomers into copolymers is called copolymerization. Copolymers obtained from the copolymerization of two monomer species are ...
s with both organic and inorganic additives, including
borate
A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name a ...
s and small quantities of
ceramic
A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelai ...
s and other special barrier ingredients—up to 21 in all.
Perhaps uniquely for a material said to be thermal proof, it is said to be not entirely
inorganic
In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as ''inorganic chemis ...
but up to 90 percent
organic.
Nicola McDermott, Ward's youngest daughter, stated that Starlite is 'natural' and
edible, and that it has been fed to dogs and horses without ill effects.
The American company Thermashield, LLC, which owns the Starlite formula, stated in a radio interview that Starlite is not made from household ingredients and there is no
PVA glue
Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue, PVA glue, white glue, carpenter's glue, school glue, or Elmer's glue in the US, is a widely available adhesive used for porous materials like wood, paper, and ...
,
baking soda
Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation ( Na+) and a bicarbonate anion ( HCO3� ...
or
baking powder
Baking powder is a dry chemical leavening agent, a mixture of a carbonate or bicarbonate and a weak acid. The base and acid are prevented from reacting prematurely by the inclusion of a buffer such as cornstarch. Baking powder is used to incre ...
in it.
Commercialisation
Ward allowed various organisations such as the
Atomic Weapons Establishment
The Atomic Weapons Establishment (AWE) is a United Kingdom Ministry of Defence research facility responsible for the design, manufacture and support of warheads for the UK's nuclear weapons. It is the successor to the Atomic Weapons Research E ...
and
ICI to conduct tests on samples, but did not permit them to retain samples for fear of
reverse engineering
Reverse engineering (also known as backwards engineering or back engineering) is a process or method through which one attempts to understand through deductive reasoning how a previously made device, process, system, or piece of software accompli ...
. Ward maintained that his invention was worth billions.
Sir Ronald Mason told a reporter in 1993, "I started this path with Maurice very sceptical. I’m totally convinced of the reality of the claims." He further states, "We don't still quite understand ''how'' it works, but that it works is undoubtedly the case."
NASA
The National Aeronautics and Space Administration (NASA ) is an independent agency of the US federal government responsible for the civil space program, aeronautics research, and space research.
NASA was established in 1958, succeedi ...
became involved in Starlite in 1994, and NASA engineer Rosendo 'Rudy' Naranjo talked about its potential in a ''
Dateline NBC
''Dateline NBC'' is a weekly American television news magazine/reality legal show that is broadcast on NBC. It was previously the network's flagship general interest news magazine, but now focuses mainly on true crime stories with only occasio ...
'' report. The ''Dateline'' reporter stated that Starlite could perhaps help with the fragile
Space Shuttle
The Space Shuttle is a retired, partially reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program na ...
heat shield.
Naranjo said of their discussions with Ward, "We have done a lot of evaluation and … we know all the tremendous possibilities that this material has."
Boeing
The Boeing Company () is an American multinational corporation that designs, manufactures, and sells airplanes, rotorcraft, rockets, satellites, telecommunications equipment, and missiles worldwide. The company also provides leasing and ...
, which was the main contractor for the Space Shuttles in 1994, became interested in the potential of Starlite to eliminate flammable materials in their jets.
By the time of Ward's death in 2011 there appeared to have been no commercialisation of Starlite, and the formulation of the material had not been released to the public.
*According to a 2016 broadcast of the BBC programme ''
The Naked Scientists
''The Naked Scientists'' is a one-hour audience-interactive science radio talk show broadcast live by the BBC in the East of England, nationally by BBC Radio 5 Live and internationally on ABC Radio National, Australia; it is also distributed ...
'', Ward took his secrets with him when he died.
*According to a 2020 ''
BBC Online
BBC Online, formerly known as BBCi, is the BBC's online service. It is a large network of websites including such high-profile sites as BBC News and Sport, the on-demand video and radio services branded BBC iPlayer and BBC Sounds, the childr ...
'' release in the BBC Reel category, Thermashield, LLC had purchased all of Ward's notes, equipment and other related materials and is working towards a viable commercial product.
Replication
A
YouTube
YouTube is a global online video sharing and social media platform headquartered in San Bruno, California. It was launched on February 14, 2005, by Steve Chen, Chad Hurley, and Jawed Karim. It is owned by Google, and is the second most ...
user, NightHawkInLight, attempted in 2018 to create materials that replicated the properties of Starlite. Observing that the mechanism that generates an expanding carbon foam in Starlite is similar to
black snake fireworks, NightHawkInLight concocted a formula using
cornstarch
Corn starch, maize starch, or cornflour (British English) is the starch derived from corn (maize) grain. The starch is obtained from the endosperm of the kernel. Corn starch is a common food ingredient, often used to thicken sauces or soups, ...
,
baking soda
Sodium bicarbonate ( IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation ( Na+) and a bicarbonate anion ( HCO3� ...
, and
PVA glue
Polyvinyl acetate (PVA, PVAc, poly(ethenyl ethanoate)), commonly known as wood glue, PVA glue, white glue, carpenter's glue, school glue, or Elmer's glue in the US, is a widely available adhesive used for porous materials like wood, paper, and ...
. After drying, the hardened material creates a thin layer of carbon foam on the surface when exposed to high heat, insulating the material from further heat transfer. He later improved it by taking out the PVA glue and baking soda, and adding in flour, sugar and borax. Using borax and flour makes it less expensive,
mold
A mold () or mould () is one of the structures certain fungi can form. The dust-like, colored appearance of molds is due to the formation of spores containing fungal secondary metabolites. The spores are the dispersal units of the fungi. Not ...
and
insect
Insects (from Latin ') are pancrustacean hexapod invertebrates of the class Insecta. They are the largest group within the arthropod phylum. Insects have a chitinous exoskeleton, a three-part body (head, thorax and abdomen), three pairs ...
resistant, and allows it to work when dry.
Several experiments testing the replication and variant recipes show that they can handle lasers,
thermite
Thermite () is a pyrotechnic composition of metal powder and metal oxide. When ignited by heat or chemical reaction, thermite undergoes an exothermic reduction-oxidation (redox) reaction. Most varieties are not explosive, but can create br ...
, torches, etc. But the replication recipe failed when it was used to make a
crucible
A crucible is a ceramic or metal container in which metals or other substances may be melted or subjected to very high temperatures. While crucibles were historically usually made from clay, they can be made from any material that withstands te ...
for an
induction furnace.
See also
*
Lost inventions
*
Firepaste
Troy James Hurtubise (November 23, 1963 – June 17, 2018) was a Canadian inventor and conservationist, noted for self-testing his often bizarre creations. These inventions included various ray generators, firepaste (an ablative heatproofing ma ...
References
External links
* .
* .
* . (Wayback Machine; March 9, 2020)
*
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* {{Skeptoid , id=4684 , number= 684 , title=Starlight, the Magical Mystery Material , date=16 July 2019
Organic polymers
Biomaterials
Brand name materials
Lost inventions
Firestops