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An asterism () is a
star-shaped In geometry, a set S in the Euclidean space \R^n is called a star domain (or star-convex set, star-shaped set or radially convex set) if there exists an s_0 \in S such that for all s \in S, the line segment from s_0 to s lies in S. This defini ...
concentration of
light Light, visible light, or visible radiation is electromagnetic radiation that can be visual perception, perceived by the human eye. Visible light spans the visible spectrum and is usually defined as having wavelengths in the range of 400– ...
reflected Reflection is the change in direction of a wavefront at an interface between two different media so that the wavefront returns into the medium from which it originated. Common examples include the reflection of light, sound and water waves. The ...
or
refracted In physics, refraction is the redirection of a wave as it passes from one medium to another. The redirection can be caused by the wave's change in speed or by a change in the medium. Refraction of light is the most commonly observed phenome ...
from a
gemstone A gemstone (also called a fine gem, jewel, precious stone, semiprecious stone, or simply gem) is a piece of mineral crystal which, when cut or polished, is used to make jewellery, jewelry or other adornments. Certain Rock (geology), rocks (such ...
. It can appear when a suitable stone is cut ''en
cabochon A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...
'' (i.e. shaped and polished, not faceted). A gemstone that exhibits this effect is called a star stone or asteria. The best known is star sapphire, but many other minerals can also be asteria, usually due to impurities in the crystal structure.


Archetype

The archetypal asteria is the star sapphire, generally
corundum Corundum is a crystalline form of aluminium oxide () typically containing traces of iron, titanium, vanadium, and chromium. It is a rock (geology), rock-forming mineral. It is a naturally transparency and translucency, transparent material, but ...
with near uniform impurities which is bluish-grey and milky or opalescent, which when lit has a star of six rays. In the red instance stellate reflection is rarer; the star-
ruby Ruby is a pinkish-red-to-blood-red-colored gemstone, a variety of the mineral corundum ( aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapph ...
occasionally found with the star-sapphire in
Sri Lanka Sri Lanka, officially the Democratic Socialist Republic of Sri Lanka, also known historically as Ceylon, is an island country in South Asia. It lies in the Indian Ocean, southwest of the Bay of Bengal, separated from the Indian subcontinent, ...
is among the most valued of "fancy stones". Other examples are star-
topaz Topaz is a silicate mineral made of aluminium, aluminum and fluorine with the chemical formula aluminium, Alsilicon, Sioxygen, O(fluorine, F, hydroxide, OH). It is used as a gemstone in jewelry and other adornments. Common topaz in its natural ...
(8 rays) and star
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
(4 rays); star
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
s may display four-rayed or six-rayed asterisms.


Description

Asterism is generated by reflections of light from twin-
lamellae Lamella (: lamellae) means a small plate or flake in Latin, and in English may refer to: Biology * Lamella (mycology), a papery rib beneath a mushroom cap * Lamella (botany) * Lamella (surface anatomy), a plate-like structure in an animal * Lame ...
or from extremely fine needle-shaped acicular inclusions within the stone's crystal structure. A common cause is oriented sub-microscopic crystals of
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at vis ...
within the gem mineral. It occurs in
rubies Ruby is a pinkish-red-to-blood-red-colored gemstone, a variety of the mineral corundum (aluminium oxide). Ruby is one of the most popular traditional jewelry gems and is very durable. Other varieties of gem-quality corundum are called sapphi ...
,
sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name ''sapphire ...
s,
garnet Garnets () are a group of silicate minerals that have been used since the Bronze Age as gemstones and abrasives. Garnet minerals, while sharing similar physical and crystallographic properties, exhibit a wide range of chemical compositions, de ...
,
diopside Diopside is a monoclinic pyroxene mineral with composition . It forms complete solid solution series with hedenbergite () and augite, and partial solid solutions with orthopyroxene and pigeonite. It forms variably colored, but typically dull ...
, and
spinel Spinel () is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula in the cubic crystal system. Its name comes from the Latin word , a diminutive form of ''spine,'' in reference to its pointed crystals. Prop ...
when a
cabochon A cabochon (; ) is a gemstone that has been shaped and polished, as opposed to faceted. The resulting form is usually a convex (rounded) obverse with a flat reverse. Cabochon was the default method of preparing gemstones before gemstone cuttin ...
is cut from a suitable stone.
Star sapphires Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, cobalt, lead, chromium, vanadium, magnesium, boron, and silicon. The name ''sapphire ...
and rubies display the property from
titanium dioxide Titanium dioxide, also known as titanium(IV) oxide or titania , is the inorganic compound derived from titanium with the chemical formula . When used as a pigment, it is called titanium white, Pigment White 6 (PW6), or Colour Index Internationa ...
impurities (
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at vis ...
) present in them. The star-effect or "asterism" is caused by the difference in refractive index between the host material and that of the dense inclusions of tiny fibers of rutile (also known as "silk"). Rutile causes the relative bright relief of a star in a host material such as corundum, which has a refractive index between 1.760 and 1.778, much lower than that of rutile. The stars are caused by the light reflecting from needle-like inclusions of rutile aligned perpendicularly to the rays of the star. The star-effect may be also caused by the inclusions of
hematite Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
. In black star sapphire hematite needles formed parallel to the faces of the second order prism produce asterism. Some star sapphires from Thailand contain both hematite and rutile needles forming a 12-ray star. Star-stones were formerly regarded with much superstition.
Pliny the Elder Gaius Plinius Secundus (AD 23/24 79), known in English as Pliny the Elder ( ), was a Roman Empire, Roman author, Natural history, naturalist, and naval and army commander of the early Roman Empire, and a friend of the Roman emperor, emperor Vesp ...
's example is consistent with a moonstone; he described it as a colourless stone from
India India, officially the Republic of India, is a country in South Asia. It is the List of countries and dependencies by area, seventh-largest country by area; the List of countries by population (United Nations), most populous country since ...
within which was the appearance of a star shining with the light of the moon. However, since rutile is present in most common star gemstones, these are almost never completely transparent. A distinction can be made between two types of asterism: * Epiasterism, such as that seen in sapphire and most other gems, is the result of a reflection of light on parallel arranged inclusions inside the gemstone. * Diasterism, such as that seen in
rose quartz Quartz is a hard, crystalline mineral composed of silica (silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon–oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical f ...
, is the result of light transmitted through the stone. In order to see this effect, the stone must be illuminated from behind. Rose quartz also exhibits epiasterism.


See also

*
Isomorphism (crystallography) In chemistry, isomorphism has meanings both at the level of crystallography and at a molecular level. In crystallography, crystals are isomorphous if they have identical symmetry and if the atomic positions can be described with a set of paramet ...
*
Chatoyancy In gemology, chatoyancy ( ), also called chatoyance or the cat's eye effect, is an optical phenomenon, optical reflectance effect seen in certain gemstones. (Historically, the term has applied specifically to gems; in woods and other materials ...


References

* D. S. Phillips, T. E. Mitchell and A. H. Heuer,"Precipitation in Star Sapphire I: Identification of the Precipitates, Phil. Mag. A, 1980, v. 42, N0. 3, pp 385–404 {{Authority control Gemology Optical phenomena