Spinor Spherical Harmonics
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In
quantum mechanics Quantum mechanics is the fundamental physical Scientific theory, theory that describes the behavior of matter and of light; its unusual characteristics typically occur at and below the scale of atoms. Reprinted, Addison-Wesley, 1989, It is ...
, the spinor spherical harmonics (also known as spin spherical harmonics, spinor harmonics and Pauli spinors) are
special functions Special functions are particular mathematical functions that have more or less established names and notations due to their importance in mathematical analysis, functional analysis, geometry, physics, or other applications. The term is defined by ...
defined over the sphere. The spinor spherical harmonics are the natural spinor analog of the
vector spherical harmonics In mathematics, vector spherical harmonics (VSH) are an extension of the scalar spherical harmonics for use with vector fields. The components of the VSH are complex-valued functions expressed in the spherical coordinate basis vectors. Definitio ...
. While the standard
spherical harmonics In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. The table of spherical harmonics co ...
are a basis for the
angular momentum operator In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum pro ...
, the spinor spherical harmonics are a basis for the total angular momentum operator (angular momentum plus
spin Spin or spinning most often refers to: * Spin (physics) or particle spin, a fundamental property of elementary particles * Spin quantum number, a number which defines the value of a particle's spin * Spinning (textiles), the creation of yarn or thr ...
). These functions are used in analytical solutions to
Dirac equation In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin-1/2 massive particles, called "Dirac ...
in a radial potential. The spinor spherical harmonics are sometimes called Pauli central field spinors, in honor of
Wolfgang Pauli Wolfgang Ernst Pauli ( ; ; 25 April 1900 – 15 December 1958) was an Austrian theoretical physicist and a pioneer of quantum mechanics. In 1945, after having been nominated by Albert Einstein, Pauli received the Nobel Prize in Physics "for the ...
who employed them in the solution of the
hydrogen atom A hydrogen atom is an atom of the chemical element hydrogen. The electrically neutral hydrogen atom contains a single positively charged proton in the nucleus, and a single negatively charged electron bound to the nucleus by the Coulomb for ...
with
spin–orbit interaction In quantum mechanics, the spin–orbit interaction (also called spin–orbit effect or spin–orbit coupling) is a relativistic interaction of a particle's spin with its motion inside a potential. A key example of this phenomenon is the spin– ...
.


Properties

The spinor spherical harmonics are the
spinor In geometry and physics, spinors (pronounced "spinner" IPA ) are elements of a complex numbers, complex vector space that can be associated with Euclidean space. A spinor transforms linearly when the Euclidean space is subjected to a slight (infi ...
s
eigenstate In quantum physics, a quantum state is a mathematical entity that embodies the knowledge of a quantum system. Quantum mechanics specifies the construction, evolution, and measurement of a quantum state. The result is a prediction for the system re ...
s of the total
angular momentum operator In quantum mechanics, the angular momentum operator is one of several related operators analogous to classical angular momentum. The angular momentum operator plays a central role in the theory of atomic and molecular physics and other quantum pro ...
squared: : \begin \mathbf j^2 Y_ &= j (j + 1) Y_ \\ \mathrm j_ Y_ &= m Y_\;;\;m=-j,-(j-1),\cdots,j-1,j\\ \mathbf l^2 Y_ &= l (l + 1) Y_\\ \mathbf s^2 Y_ &= s (s + 1) Y_ \end where , where , , and are the (dimensionless) total, orbital and spin angular momentum operators, ''j'' is the total
azimuthal quantum number In quantum mechanics, the azimuthal quantum number is a quantum number for an atomic orbital that determines its angular momentum operator, orbital angular momentum and describes aspects of the angular shape of the orbital. The azimuthal quantum ...
and ''m'' is the total
magnetic quantum number In atomic physics, a magnetic quantum number is a quantum number used to distinguish quantum states of an electron or other particle according to its angular momentum along a given axis in space. The orbital magnetic quantum number ( or ) disting ...
. Under a parity operation, we have : P Y_ = (-1)^Y_. For
spin-1/2 In quantum mechanics, spin is an intrinsic property of all elementary particles. All known fermions, the particles that constitute ordinary matter, have a spin of . The spin number describes how many symmetrical facets a particle has in one f ...
systems, they are given in matrix form by : Y_ = \frac \begin \pm \sqrt Y_^ \\ \sqrt Y_^ \end. where Y_^ are the usual
spherical harmonics In mathematics and physical science, spherical harmonics are special functions defined on the surface of a sphere. They are often employed in solving partial differential equations in many scientific fields. The table of spherical harmonics co ...
.


References

Spinors Rotational symmetry Special functions {{quantum-stub