
In
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
,
spin is an intrinsic property of all
elementary particle
In particle physics, an elementary particle or fundamental particle is a subatomic particle that is not composed of other particles. Particles currently thought to be elementary include electrons, the fundamental fermions (quarks, leptons, antiq ...
s. All known
fermion
In particle physics, a fermion is a particle that follows Fermi–Dirac statistics. Generally, it has a half-odd-integer spin: spin , spin , etc. In addition, these particles obey the Pauli exclusion principle. Fermions include all quarks and ...
s, the particles that constitute ordinary matter, have a spin of .
The spin number describes how many symmetrical facets a particle has in one full rotation; a spin of means that the particle must be rotated by two full
turn
Turn may refer to:
Arts and entertainment
Dance and sports
* Turn (dance and gymnastics), rotation of the body
* Turn (swimming), reversing direction at the end of a pool
* Turn (professional wrestling), a transition between face and heel
* Turn, ...
s (through 720°) before it has the same configuration as when it started.
Particles having net spin include the
proton,
neutron
The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behav ...
,
electron
The electron (, or in nuclear reactions) is a subatomic particle with a negative one elementary electric charge. Electrons belong to the first generation of the lepton particle family,
and are generally thought to be elementary partic ...
,
neutrino
A neutrino ( ; denoted by the Greek letter ) is a fermion (an elementary particle with spin of ) that interacts only via the weak interaction and gravity. The neutrino is so named because it is electrically neutral and because its rest mass ...
, and
quarks. The dynamics of spin- objects cannot be accurately described using
classical physics; they are among the simplest systems which require
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
to describe them. As such, the study of the behavior of spin- systems forms a central part of
quantum mechanics
Quantum mechanics is a fundamental theory in physics that provides a description of the physical properties of nature at the scale of atoms and subatomic particles. It is the foundation of all quantum physics including quantum chemistry, q ...
.
Stern–Gerlach experiment
The necessity of introducing half-integer
spin goes back experimentally to the results of the
Stern–Gerlach experiment. A beam of atoms is run through a strong
heterogeneous magnetic field, which then splits into N parts depending on the intrinsic angular momentum of the atoms. It was found that for silver atoms, the beam was split in two—the
ground state therefore could not be an integer, because even if the intrinsic angular momentum of the atoms were the smallest (non-zero) integer possible, 1, the beam would be split into 3 parts, corresponding to atoms with ''L
z'' = −1, +1, and 0, with 0 simply being the value known to come between -1 and +1 while also being a whole-integer itself, and thus a valid quantized spin number in this case. The existence of this hypothetical "extra step" between the two polarized quantum states would necessitate a third quantum state; a third beam, which is not observed in the experiment. The conclusion was that silver atoms had net intrinsic angular momentum of .
General properties

Spin- objects are all
fermions (a fact explained by the
spin–statistics theorem) and satisfy the
Pauli exclusion principle. Spin- particles can have a permanent
magnetic moment along the direction of their spin, and this magnetic moment gives rise to
electromagnetic interactions that depend on the spin. One such effect that was important in the discovery of spin is the
Zeeman effect
The Zeeman effect (; ) is the effect of splitting of a spectral line into several components in the presence of a static magnetic field. It is named after the Dutch physicist Pieter Zeeman, who discovered it in 1896 and received a Nobel priz ...
, the splitting of a spectral line into several components in the presence of a static magnetic field.
Unlike in more complicated quantum mechanical systems, the spin of a spin- particle can be expressed as a
linear combination of just two
eigenstates
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in t ...
, or
eigenspinor In quantum mechanics, eigenspinors are thought of as basis vectors representing the general spin state of a particle. Strictly speaking, they are not vectors at all, but in fact spinors. For a single spin 1/2 particle, they can be defined as th ...
s. These are traditionally labeled spin up and spin down. Because of this, the quantum-mechanical spin
operators can be represented as simple 2 × 2
matrices. These matrices are called the
Pauli matrices.
Creation and annihilation operators can be constructed for spin- objects; these obey the same
commutation relations as other
angular momentum operators.
Connection to the uncertainty principle
One consequence of the
generalized uncertainty principle is that the spin projection operators (which measure the spin along a given direction like ''x'', ''y'', or ''z'') cannot be measured simultaneously. Physically, this means that the axis about which a particle is spinning is ill-defined. A measurement of the ''z''-component of spin destroys any information about the ''x''- and ''y''-components that might previously have been obtained.
Mathematical description
A spin- particle is characterized by an
angular momentum quantum number for spin s of . In solutions of the
Schrödinger equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
, angular momentum is quantized according to this number, so that total spin angular momentum
:
However, the observed
fine structure when the electron is observed along one axis, such as the ''z''-axis, is quantized in terms of a
magnetic quantum number, which can be viewed as a quantization of a
vector component
In mathematics, physics, and engineering, a Euclidean vector or simply a vector (sometimes called a geometric vector or spatial vector) is a geometric object that has magnitude (or length) and direction. Vectors can be added to other vectors ...
of this total angular momentum, which can have only the values of .
Note that these values for angular momentum are functions only of the
reduced Planck constant
The Planck constant, or Planck's constant, is a fundamental physical constant of foundational importance in quantum mechanics. The constant gives the relationship between the energy of a photon and its frequency, and by the mass-energy equivalen ...
(the angular momentum of any
photon
A photon () is an elementary particle that is a quantum of the electromagnetic field, including electromagnetic radiation such as light and radio waves, and the force carrier for the electromagnetic force. Photons are Massless particle, massless ...
), with no dependence on mass or charge.
Complex phase
Mathematically, quantum mechanical spin is not described by a
vector as in classical angular momentum. It is described by a complex-valued vector with two components called a
spinor. There are subtle differences between the behavior of spinors and vectors under
coordinate rotations, stemming from the behavior of a vector space over a complex field.
When a spinor is rotated by 360° (one full turn), it transforms to its negative, and then after a further rotation of 360° it transforms back to its initial value again. This is because in quantum theory the state of a particle or system is represented by a complex
probability amplitude (
wavefunction) ''ψ'', and when the system is measured, the probability of finding the system in the state ''ψ'' equals , the
absolute square (square of the
absolute value) of the amplitude. In mathematical terms, the quantum Hilbert space carries a
projective representation of the rotation group SO(3).
Suppose a detector that can be rotated measures a particle in which the probabilities of detecting some state are affected by the rotation of the detector. When the system is rotated through 360°, the observed output and physics are the same as initially but the amplitudes are changed for a spin- particle by a factor of
−1 or a phase shift of half of 360°. When the probabilities are calculated, the −1 is squared, (−1)
2 = 1, so the predicted physics is the same as in the starting position. Also, in a spin- particle there are only two spin states and the amplitudes for both change by the same −1 factor, so the interference effects are identical, unlike the case for higher spins. The complex probability amplitudes are something of a theoretical construct which cannot be directly observed.
If the probability amplitudes rotated by the same amount as the detector, then they would have changed by a factor of −1 when the equipment was rotated by 180° which when squared would predict the same output as at the start, but experiments show this to be wrong. If the detector is rotated by 180°, the result with spin- particles can be different from what it would be if not rotated, hence the factor of a half is necessary to make the predictions of the theory match the experiments.
In terms of more direct evidence, physical effects of the difference between the rotation of a spin- particle by 360° as compared with 720° have been experimentally observed in classic experiments
in neutron interferometry. In particular, if a beam of spin-oriented spin- particles is split, and just one of the beams is rotated about the axis of its direction of motion and then recombined with the original beam, different interference effects are observed depending on the angle of rotation. In the case of rotation by 360°, cancellation effects are observed, whereas in the case of rotation by 720°, the beams are mutually reinforcing.
NRQM (non-relativistic quantum mechanics)
The
quantum state
In quantum physics, a quantum state is a mathematical entity that provides a probability distribution for the outcomes of each possible measurement on a system. Knowledge of the quantum state together with the rules for the system's evolution in ...
of a spin- particle can be described by a two-component complex-valued vector called a
spinor. Observable states of the particle are then found by the spin operators ''S
x'', ''S
y'', and ''S
z,'' and the total spin operator S.
Observables
When spinors are used to describe the quantum states, the three spin operators (''S
x'', ''S
y'', ''S
z,'') can be described by 2 × 2 matrices called the Pauli matrices whose
eigenvalue
In linear algebra, an eigenvector () or characteristic vector of a linear transformation is a nonzero vector that changes at most by a scalar factor when that linear transformation is applied to it. The corresponding eigenvalue, often denot ...
s are .
For example, the spin projection operator ''S
z'' affects a measurement of the spin in the ''z'' direction.
:
The two eigenvalues of ''S
z'', , then correspond to the following eigenspinors:
:
:
These vectors form a complete basis for the
Hilbert space
In mathematics, Hilbert spaces (named after David Hilbert) allow generalizing the methods of linear algebra and calculus from (finite-dimensional) Euclidean vector spaces to spaces that may be infinite-dimensional. Hilbert spaces arise natu ...
describing the spin- particle. Thus, linear combinations of these two states can represent all possible states of the spin, including in the ''x''- and ''y''-directions.
The
ladder operators are:
:
Since ,
it follows that and . Thus:
:
:
Their normalized eigenspinors can be found in the usual way. For ''S
x'', they are:
:
:
For ''S
y'', they are:
:
:
RQM (relativistic quantum mechanics)
While NRQM defines spin with 2 dimensions in Hilbert space with dynamics that are described in 3-dimensional space and time,
relativistic quantum mechanics defines the spin with 4 dimensions in Hilbert space and dynamics described by 4-dimensional space-time.
Observables
As a consequence of the four-dimensional nature of space-time in relativity, relativistic quantum mechanics uses 4×4 matrices to describe spin operators and observables.
Spin as a consequence of combining quantum theory and special relativity
When physicist
Paul Dirac
Paul Adrien Maurice Dirac (; 8 August 1902 – 20 October 1984) was an English theoretical physicist who is regarded as one of the most significant physicists of the 20th century. He was the Lucasian Professor of Mathematics at the Unive ...
tried to modify the
Schrödinger equation
The Schrödinger equation is a linear partial differential equation that governs the wave function of a quantum-mechanical system. It is a key result in quantum mechanics, and its discovery was a significant landmark in the development of th ...
so that it was consistent with Einstein's
theory of relativity
The theory of relativity usually encompasses two interrelated theories by Albert Einstein: special relativity and general relativity, proposed and published in 1905 and 1915, respectively. Special relativity applies to all physical phenomena in ...
, he found it was only possible by including matrices in the resulting
Dirac equation, implying the wave must have multiple components leading to spin.
See also
*
Projective representation
Notes
Further reading
*
*
External links
*
{{DEFAULTSORT:Spin-1 2
Rotation in three dimensions
Quantum models